期刊
ACS CATALYSIS
卷 10, 期 15, 页码 8237-8246出版社
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.0c01842
关键词
nickel catalysis; enantioselective; reductive cross-coupling; asymmetric catalysis; cross-electrophile coupling
资金
- National Science Foundation [DGE-1144469]
- NIH [R35GM118191-01]
Nickel-catalyzed reductive cross-coupling reactions have emerged as powerful methods to join two electrophiles. These reactions have proven particularly useful for the coupling of sec-alkyl electrophiles to form stereogenic centers; however, the development of enantioselective variants remains challenging. In this Perspective, we summarize the progress that has been made toward Ni-catalyzed enantioselective reductive cross-coupling reactions.
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