Base metal catalyzed (De)hydrogenative formylation and methylation reactions utilizing carbon dioxide and methanol as C1 sources

CO2-Promoted Reactions: An Emerging Concept for the Synthesis of Fine Chemicals and Pharmaceuticals

(2021) Prakash Kumar Sahoo et al.   ACS Catalysis

Borrowing Hydrogen for Organic Synthesis

(2021) Benjamin G. Reed-Berendt et al.   ACS Central Science

Homogeneously catalyzed acceptorless dehydrogenation of alcohols: A progress report

(2021) Monica Trincado et al.   COORDINATION CHEMISTRY REVIEWS

Recent Progress in the Synthesis of Heterocycles through Base Metal‐Catalyzed Acceptorless Dehydrogenative and Borrowing Hydrogen Approach

(2021) Avijit Mondal et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Manganese-Catalyzed One-Pot Conversion of Nitroarenes into N -Methylarylamines Using Methanol

(2020) Benjamin G. Reed-Berendt et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Formylation of Amines by CO2 Hydrogenation Using Preformed Co(II)/Nickel(II) Complexes

(2020) Mohammad A. Affan et al.   INORGANIC CHEMISTRY

Homogeneous (De)hydrogenative Catalysis for Circular Chemistry – Using Waste as a Resource

(2020) Amit Kumar et al.   ChemCatChem

Circular chemistry to enable a circular economy

(2019) Tom Keijer et al.   Nature Chemistry

Mn-Catalyzed Selective Double and Mono N-Formylation and N- Methylation of Amines Using CO2

(2019) Zijun Huang et al.   ChemSusChem

Iron-Catalyzed Tandem Three-Component Alkylation: Access to α-Methylated Substituted Ketones

(2019) Léo Bettoni et al.   ORGANIC LETTERS

Iron‐Catalyzed Selective N ‐Methylation and N ‐Formylation of Amines with CO 2

(2019) Wen‐Duo Li et al.   ADVANCED SYNTHESIS & CATALYSIS

Iron-Catalyzed Borrowing Hydrogen β-C(sp3)-Methylation of Alcohols

(2019) Kurt Polidano et al.   ACS Catalysis

Manganese(I)-Catalyzed β-Methylation of Alcohols Using Methanol as C1 Source

(2019) Akash Kaithal et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iron-Catalyzed β-Alkylation of Alcohols

(2019) Léo Bettoni et al.   ORGANIC LETTERS

Atom-Economical and Tandem Conversion of Nitriles to N-Methylated Amides Using Methanol and Water

(2019) Bhaskar Paul et al.   ACS Catalysis

Manganese-Catalyzed β-Methylation of Alcohols by Methanol

(2019) Martin Schlagbauer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic (de)hydrogenation promoted by non-precious metals – Co, Fe and Mn: recent advances in an emerging field

(2018) Georgy A. Filonenko et al.   CHEMICAL SOCIETY REVIEWS

Ethanol-Mediated N-Formylation of Amines with CO2/H2 over Cobalt Catalysts

(2018) Zhenghui Liu et al.   NEW JOURNAL OF CHEMISTRY

Iron-catalyzed urea synthesis: dehydrogenative coupling of methanol and amines

(2018) Elizabeth M. Lane et al.   Chemical Science

Selective Iron-Catalyzed N-Formylation of Amines using Dihydrogen and Carbon Dioxide

(2018) Upul Jayarathne et al.   ACS Catalysis

Iron-Catalyzed Methylation Using the Borrowing Hydrogen Approach

(2018) Kurt Polidano et al.   ACS Catalysis

Cobalt Complexes as an Emerging Class of Catalysts for Homogeneous Hydrogenations

(2018) Weiping Liu et al.   ACCOUNTS OF CHEMICAL RESEARCH

Well-Defined Phosphine-Free Iron-Catalyzed N-Ethylation and N-Methylation of Amines with Ethanol and Methanol

(2018) Alexis Lator et al.   ORGANIC LETTERS

Catalytic C1  Alkylation with Methanol and Isotope-Labeled Methanol

(2018) Jan Sklyaruk et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

First-Row Transition Metal (De)Hydrogenation Catalysis Based On Functional Pincer Ligands

(2018) Lukas Alig et al.   CHEMICAL REVIEWS

3d-Metal Catalyzed N- and C-Alkylation Reactions via Borrowing Hydrogen or Hydrogen Autotransfer

(2018) Torsten Irrgang et al.   CHEMICAL REVIEWS

Recent Advances in Methylation: A Guide for Selecting Methylation Reagents

(2018) Yantao Chen   CHEMISTRY-A EUROPEAN JOURNAL

Cobalt-Catalyzed Synthesis of Unsymmetrically N,N-Disubstituted Formamides via Reductive Coupling of Primary Amines and Aldehydes with CO2 and H2

(2018) Zhengang Ke et al.   ORGANIC LETTERS

Cobalt-Catalyzed α-Methoxymethylation and Aminomethylation of Ketones with Methanol as a C1 Source

(2018) Jingya Yang et al.   ORGANIC LETTERS

Homogeneous Catalysis by Cobalt and Manganese Pincer Complexes

(2018) Arup Mukherjee et al.   ACS Catalysis

Synthesis of formamides containing unsaturated groups by N-formylation of amines using CO2 with H2

(2017) Hangyu Liu et al.   GREEN CHEMISTRY

Catalytic Formylation of Primary and Secondary Amines with CO2 and H2 Using Abundant-Metal Catalysts

(2017) Mohammad A. Affan et al.   INORGANIC CHEMISTRY

Mono- N -methylation of anilines with methanol catalyzed by a manganese pincer-complex

(2017) Antoine Bruneau-Voisine et al.   JOURNAL OF CATALYSIS

Manganese-Catalyzed Aminomethylation of Aromatic Compounds with Methanol as a Sustainable C1 Building Block

(2017) Matthias Mastalir et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Methylation of C(sp3)–H/C(sp2)–H Bonds with Methanol Catalyzed by Cobalt System

(2017) Zhenghui Liu et al.   ORGANIC LETTERS

Recent Developments of Manganese Complexes for Catalytic Hydrogenation and Dehydrogenation Reactions

(2017) Biplab Maji et al.   SYNTHESIS-STUTTGART

Selective N-Formylation of Amines with H2 and CO2 Catalyzed by Cobalt Pincer Complexes

(2017) Prosenjit Daw et al.   ACS Catalysis

Utilization of CO2 as a C1 Building Block for Catalytic Methylation Reactions

(2017) Yuehui Li et al.   ACS Catalysis

Bio-Inspired Mn(I) Complexes for the Hydrogenation of CO2 to Formate and Formamide

(2017) Abhishek Dubey et al.   ACS Catalysis

Manganese-Catalyzed Sequential Hydrogenation of CO2 to Methanol via Formamide

(2017) Sayan Kar et al.   ACS Catalysis

N-Formylation of Amines with CO2 and H2 Using Pd–Au Bimetallic Catalysts Supported on Polyaniline-Functionalized Carbon Nanotubes

(2017) Pengpeng Ju et al.   ACS Sustainable Chemistry & Engineering

Selective Catalytic Synthesis Using the Combination of Carbon Dioxide and Hydrogen: Catalytic Chess at the Interface of Energy and Chemistry

(2016) Jürgen Klankermayer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Efficient and selective N-alkylation of amines with alcohols catalysed by manganese pincer complexes

(2016) Saravanakumar Elangovan et al.   Nature Communications

Getting Down to Earth: The Renaissance of Catalysis with Abundant Metals

(2015) Paul Chirik et al.   ACCOUNTS OF CHEMICAL RESEARCH

Recent Advances in Transition Metal-Catalyzed Methylation Reactions

(2015) Guobing Yan et al.   ADVANCED SYNTHESIS & CATALYSIS

Hydrogen Acceptor- and Base-FreeN-Formylation of Nitriles and Amines using Methanol as C1Source

(2015) Byungjoon Kang et al.   ADVANCED SYNTHESIS & CATALYSIS

Highly Efficient Ruthenium-Catalyzed N-Formylation of Amines with H2and CO2

(2015) Lei Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Step into an eco-Compatible Future: Iron- and Cobalt-catalyzed Borrowing Hydrogen Transformation

(2015) Adrien Quintard et al.   ChemSusChem

Reductive functionalization of CO2 with amines: an entry to formamide, formamidine and methylamine derivatives

(2015) Anis Tlili et al.   GREEN CHEMISTRY

Selective N-Methylation of Aliphatic Amines with CO2 and Hydrosilanes Using Nickel-Phosphine Catalysts

(2015) Lucero González-Sebastián et al.   ORGANOMETALLICS

Recent development in catalytic technologies for methanol synthesis from renewable sources: A critical review

(2015) Khozema Ahmed Ali et al.   RENEWABLE & SUSTAINABLE ENERGY REVIEWS

Using carbon dioxide as a building block in organic synthesis

(2015) Qiang Liu et al.   Nature Communications

Catalytic Conversion of Nonfood Woody Biomass Solids to Organic Liquids

(2014) Katalin Barta et al.   ACCOUNTS OF CHEMICAL RESEARCH

Creating Added Value with a Waste: Methylation of Amines with CO2and H2

(2014) Anis Tlili et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Methylation of CH Bonds Using CO2and H2

(2014) Yuehui Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Formylation of Amines

(2014) Ciera Gerack et al.   MOLECULES

Catalytic and Organometallic Chemistry of Earth-Abundant Metals

(2014) Martin Albrecht et al.   ORGANOMETALLICS

Ruthenium-Catalyzed Direct Methylation of Primary and Secondary Aromatic Amines Using Carbon Dioxide and Molecular Hydrogen

(2013) Kassem Beydoun et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Selective Methylation of Amines with Carbon Dioxide and H2

(2013) Yuehui Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Amine formylation via carbon dioxide recycling catalyzed by a simple and efficient heterogeneous palladium catalyst

(2013) Xinjiang Cui et al.   CHEMICAL COMMUNICATIONS

Catalysis for the Valorization of Exhaust Carbon: from CO2 to Chemicals, Materials, and Fuels. Technological Use of CO2

(2013) Michele Aresta et al.   CHEMICAL REVIEWS

N-Formylation of Amines by Methanol Activation

(2013) Nuria Ortega et al.   ORGANIC LETTERS

Applications of Acceptorless Dehydrogenation and Related Transformations in Chemical Synthesis

(2013) C. Gunanathan et al.   SCIENCE

CO2 as a C1-building block for the catalytic methylation of amines

(2013) Olivier Jacquet et al.   Chemical Science

N,N-Dimethylformamide: A Multipurpose Building Block

(2012) Shengtao Ding et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Well-Defined Iron Catalyst for Improved Hydrogenation of Carbon Dioxide and Bicarbonate

(2012) Carolin Ziebart et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron/Amino Acid Catalyzed Direct N-Alkylation of Amines with Alcohols

(2011) Yingsheng Zhao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Transformation of Carbon Dioxide with Homogeneous Transition-Metal Catalysts: A Molecular Solution to a Global Challenge?

(2011) Mirza Cokoja et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Methylation Effect in Medicinal Chemistry

(2011) Eliezer J. Barreiro et al.   CHEMICAL REVIEWS

Transition-metal-catalyzed C–C bond formation through the fixation of carbon dioxide

(2011) Kun Huang et al.   CHEMICAL SOCIETY REVIEWS

Catalytic Hydrogenation of Carbon Dioxide and Bicarbonates with a Well-Defined Cobalt Dihydrogen Complex

(2011) Christopher Federsel et al.   CHEMISTRY-A EUROPEAN JOURNAL

A Well-Defined Iron Catalyst for the Reduction of Bicarbonates and Carbon Dioxide to Formates, Alkyl Formates, and Formamides

(2010) Christopher Federsel et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Renewable Chemical Commodity Feedstocks from Integrated Catalytic Processing of Pyrolysis Oils

(2010) T. P. Vispute et al.   SCIENCE