Activating the Fe(I) State of Iron Porphyrinoid with Second-Sphere Proton Transfer Residues for Selective Reduction of CO2 to HCOOH via Fe(III/II)–COOH Intermediate(s)

Enhancing a Molecular Electrocatalyst’s Activity for CO2 Reduction by Simultaneously Modulating Three Substituent Effects

(2021) Weixuan Nie et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Selective Electrocatalytic CO2 Reduction by [Pt(dmpe)2]2+ through Kinetic and Thermodynamic Control

(2020) Bianca M. Ceballos et al.   ORGANOMETALLICS

Breaking Scaling Relationships in CO2 Electroreduction with Isoelectronic Analogs [Fe4N(CO)12]− and [Fe3MnO(CO)12]−

(2020) Cody R. Carr et al.   ORGANOMETALLICS

Homogeneous Electrochemical Reduction of CO2 to CO by a Cobalt Pyridine Thiolate Complex

(2020) Md Estak Ahmed et al.   INORGANIC CHEMISTRY

Electroreduction of CO 2 to Formate with Low Overpotential using Cobalt Pyridine Thiolate Complexes

(2020) Subal Dey et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Electronically Modified Cobalt Aminopyridine Complexes Reveal an Orthogonal Axis for Catalytic Optimization for CO2 Reduction

(2020) Alon Chapovetsky et al.   INORGANIC CHEMISTRY

Oxygen Reduction by Iron Porphyrins with Covalently Attached Pendent Phenol and Quinol

(2020) Asmita Singha et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Second-Sphere Biomimetic Multipoint Hydrogen-Bonding Patterns to Boost CO2 Reduction of Iron Porphyrins

(2019) Philipp Gotico et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synergistic Effects of Imidazolium-Functionalization on fac-Mn(CO)3 Bipyridine Catalyst Platforms for Electrocatalytic Carbon Dioxide Reduction

(2019) Siyoung Sung et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Unified Benchmarking of Electrocatalysts in Noninnocent Second Coordination Spheres for CO2 Reduction

(2019) Yasuo Matsubara   ACS Energy Letters

Reversible and Selective CO2 to HCO2 − Electrocatalysis near the Thermodynamic Potential

(2019) Drew W. Cunningham et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Secondary Coordination Sphere Design to Modify Transport of Protons and CO2

(2019) Natalia D. Loewen et al.   INORGANIC CHEMISTRY

Tertiary Amine-Assisted Electroreduction of Carbon Dioxide to Formate Catalyzed by Iron Tetraphenylporphyrin

(2019) Charles G. Margarit et al.   ACS Energy Letters

Homogeneously Catalyzed Electroreduction of Carbon Dioxide—Methods, Mechanisms, and Catalysts

(2018) Robert Francke et al.   CHEMICAL REVIEWS

Activation of Co(I) State in a Cobalt-Dithiolato Catalyst for Selective and Efficient CO2 Reduction to CO

(2018) Subal Dey et al.   INORGANIC CHEMISTRY

Electrocatalytic Reduction of CO2 to Formate by an Iron Schiff Base Complex

(2018) Asa W. Nichols et al.   INORGANIC CHEMISTRY

Rational Design of Mononuclear Iron-porphyrins for Facile and Selective 4e-/4H+ O2 Reduction: Activation of O-O Bond by 2nd Sphere Hydrogen Bonding

(2018) Sarmistha Bhunia et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Carbon Dioxide Reduction by Iron Hangman Porphyrins

(2018) Charles G. Margarit et al.   ORGANOMETALLICS

Positional effects of second-sphere amide pendants on electrochemical CO2 reduction catalyzed by iron porphyrins

(2018) Eva M. Nichols et al.   Chemical Science

Hydricity of Transition-Metal Hydrides: Thermodynamic Considerations for CO2 Reduction

(2018) Kate M. Waldie et al.   ACS Catalysis

A Bioinspired Nickel(bis-dithiolene) Complex as a Homogeneous Catalyst for Carbon Dioxide Electroreduction

(2018) Thibault Fogeron et al.   ACS Catalysis

Pendant Hydrogen-Bond Donors in Cobalt Catalysts Independently Enhance CO2 Reduction

(2018) Alon Chapovetsky et al.   ACS Central Science

Local ionic liquid environment at a modified iron porphyrin catalyst enhances electrocatalytic performance of CO2 to CO reduction in water

(2018) Ally Aukauloo et al.   CHEMICAL COMMUNICATIONS

Unexpected Solvent Effect in Electrocatalytic CO2 to CO Conversion Revealed Using Asymmetric Metalloporphyrins

(2018) Soumalya Sinha et al.   INORGANIC CHEMISTRY

A Thiourea Tether in the Second Coordination Sphere as a Binding Site for CO2 and a Proton Donor Promotes the Electrochemical Reduction of CO2 to CO Catalyzed by a Rhenium Bipyridine-Type Complex

(2018) Eynat Haviv et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Directing the reactivity of metal hydrides for selective CO2 reduction

(2018) Bianca M. Ceballos et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Molecular Cobalt Complexes with Pendant Amines for Selective Electrocatalytic Reduction of Carbon Dioxide to Formic Acid

(2017) Souvik Roy et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Turning on the Protonation-First Pathway for Electrocatalytic CO2 Reduction by Manganese Bipyridyl Tricarbonyl Complexes

(2017) Ken T. Ngo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electrocatalytic CO2 Reduction by Imidazolium-Functionalized Molecular Catalysts

(2017) Siyoung Sung et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Standard Electrode Potentials for the Reduction of CO2 to CO in Acetonitrile–Water Mixtures Determined Using a Generalized Method for Proton-Coupled Electron-Transfer Reactions

(2017) Yasuo Matsubara   ACS Energy Letters

Thermodynamic Hydricity of Transition Metal Hydrides

(2016) Eric S. Wiedner et al.   CHEMICAL REVIEWS

Through-Space Charge Interaction Substituent Effects in Molecular Catalysis Leading to the Design of the Most Efficient Catalyst of CO2-to-CO Electrochemical Conversion

(2016) Iban Azcarate et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Manganese Electrocatalysts with Bulky Bipyridine Ligands: Utilizing Lewis Acids To Promote Carbon Dioxide Reduction at Low Overpotentials

(2016) Matthew D. Sampson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Proton-Assisted Reduction of CO2 by Cobalt Aminopyridine Macrocycles

(2016) Alon Chapovetsky et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A pendant proton shuttle on [Fe4N(CO)12]− alters product selectivity in formate vs. H2 production via the hydride [H–Fe4N(CO)12]−

(2016) Natalia D. Loewen et al.   Chemical Science

Efficient electrocatalytic CO2 reduction with a molecular cofacial iron porphyrin dimer

(2015) Eman A. Mohamed et al.   CHEMICAL COMMUNICATIONS

Enhanced CO2 electroreduction efficiency through secondary coordination effects on a pincer iridium catalyst

(2015) Steven T. Ahn et al.   CHEMICAL COMMUNICATIONS

Tailoring Electrocatalysts for Selective CO2 or H+ Reduction: Iron Carbonyl Clusters as a Case Study

(2015) Atefeh Taheri et al.   INORGANIC CHEMISTRY

Molecular Catalysis of the Electrochemical and Photochemical Reduction of CO2 with Earth-Abundant Metal Complexes. Selective Production of CO vs HCOOH by Switching of the Metal Center

(2015) Lingjing Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Intermediates Involved in the 2e–/2H+ Reduction of CO2 to CO by Iron(0) Porphyrin

(2015) Biswajit Mondal et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The Homogeneous Reduction of CO2 by [Ni(cyclam)]+: Increased Catalytic Rates with the Addition of a CO Scavenger

(2015) Jesse D. Froehlich et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Efficient and selective molecular catalyst for the CO2-to-CO electrochemical conversion in water

(2015) Cyrille Costentin et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

An Iron Electrocatalyst for Selective Reduction of CO2 to Formate in Water: Including Thermochemical Insights

(2015) Atefeh Taheri et al.   ACS Catalysis

A local proton source in a [Mn(bpy-R)(CO)3Br]-type redox catalyst enables CO2 reduction even in the absence of Brønsted acids

(2014) Federico Franco et al.   CHEMICAL COMMUNICATIONS

Manganese Catalysts with Bulky Bipyridine Ligands for the Electrocatalytic Reduction of Carbon Dioxide: Eliminating Dimerization and Altering Catalysis

(2014) Matthew D. Sampson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pendant Acid–Base Groups in Molecular Catalysts: H-Bond Promoters or Proton Relays? Mechanisms of the Conversion of CO2 to CO by Electrogenerated Iron(0)Porphyrins Bearing Prepositioned Phenol Functionalities

(2014) Cyrille Costentin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ultraefficient homogeneous catalyst for the CO2-to-CO electrochemical conversion

(2014) Cyrille Costentin et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Electrocatalytic Reduction of Carbon Dioxide: Let the Molecules Do the Work

(2014) Peng Kang et al.   TOPICS IN CATALYSIS

Frontiers, Opportunities, and Challenges in Biochemical and Chemical Catalysis of CO2 Fixation

(2013) Aaron M. Appel et al.   CHEMICAL REVIEWS

Carbon capture and storage update

(2013) Matthew E. Boot-Handford et al.   Energy & Environmental Science

Nickel Pyridinethiolate Complexes as Catalysts for the Light-Driven Production of Hydrogen from Aqueous Solutions in Noble-Metal-Free Systems

(2013) Zhiji Han et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Proton-Coupled Electron Transfer Cleavage of Heavy-Atom Bonds in Electrocatalytic Processes. Cleavage of a C–O Bond in the Catalyzed Electrochemical Reduction of CO2

(2013) Cyrille Costentin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Selective electrocatalytic reduction of carbon dioxide to formate by a water-soluble iridium pincer catalyst

(2013) Peng Kang et al.   Chemical Science

Electrochemical Hydrogen Production in Acidic Water by an Azadithiolate Bridged Synthetic Hydrogenese Mimic: Role of Aqueous Solvation in Lowering Overpotential

(2013) Subal Dey et al.   ACS Catalysis

Electrochemical conversion of CO2 to useful chemicals: current status, remaining challenges, and future opportunities

(2013) Huei-Ru “Molly” Jhong et al.   Current Opinion in Chemical Engineering

Nickel(ii) macrocycles: highly efficient electrocatalysts for the selective reduction of CO2 to CO

(2012) Jacob Schneider et al.   Energy & Environmental Science

Selective Electrocatalytic Reduction of CO2 to Formate by Water-Stable Iridium Dihydride Pincer Complexes

(2012) Peng Kang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Local Proton Source Enhances CO2 Electroreduction to CO by a Molecular Fe Catalyst

(2012) C. Costentin et al.   SCIENCE

[Mn(bipyridyl)(CO)3Br]: An Abundant Metal Carbonyl Complex as Efficient Electrocatalyst for CO2 Reduction

(2011) Marc Bourrez et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Re(bipy-tBu)(CO)3Cl−improved Catalytic Activity for Reduction of Carbon Dioxide: IR-Spectroelectrochemical and Mechanistic Studies

(2010) Jonathan M. Smieja et al.   INORGANIC CHEMISTRY

Prospects of CO2 Utilization via Direct Heterogeneous Electrochemical Reduction

(2010) Devin T. Whipple et al.   Journal of Physical Chemistry Letters

Structure validation in chemical crystallography

(2009) Anthony L. Spek   ACTA CRYSTALLOGRAPHICA SECTION D-BIOLOGICAL CRYSTALLOGRAPHY

Opportunities and prospects in the chemical recycling of carbon dioxide to fuels

(2009) Gabriele Centi et al.   CATALYSIS TODAY

OLEX2: a complete structure solution, refinement and analysis program

(2009) Oleg V. Dolomanov et al.   JOURNAL OF APPLIED CRYSTALLOGRAPHY

Mössbauer, NMR, Geometric, and Electronic Properties inS=3/2Iron Porphyrins

(2009) Yan Ling et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electrocatalytic and homogeneous approaches to conversion of CO2to liquid fuels

(2008) Eric E. Benson et al.   CHEMICAL SOCIETY REVIEWS