A pendant proton shuttle on [Fe4N(CO)12]− alters product selectivity in formate vs. H2 production via the hydride [H–Fe4N(CO)12]−

Diiron Azadithiolates as Models for the [FeFe]-Hydrogenase Active Site and Paradigm for the Role of the Second Coordination Sphere

(2015) Thomas B. Rauchfuss   ACCOUNTS OF CHEMICAL RESEARCH

Tailoring Electrocatalysts for Selective CO2 or H+ Reduction: Iron Carbonyl Clusters as a Case Study

(2015) Atefeh Taheri et al.   INORGANIC CHEMISTRY

Solvation Effects on Transition Metal Hydricity

(2015) Charlene Tsay et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Increasing the rate of hydrogen oxidation without increasing the overpotential: a bio-inspired iron molecular electrocatalyst with an outer coordination sphere proton relay

(2015) Jonathan M. Darmon et al.   Chemical Science

An Iron Electrocatalyst for Selective Reduction of CO2 to Formate in Water: Including Thermochemical Insights

(2015) Atefeh Taheri et al.   ACS Catalysis

Intramolecular Iron-Mediated C–H Bond Heterolysis with an Assist of Pendant Base in a [FeFe]-Hydrogenase Model

(2014) Dehua Zheng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pendant Acid–Base Groups in Molecular Catalysts: H-Bond Promoters or Proton Relays? Mechanisms of the Conversion of CO2 to CO by Electrogenerated Iron(0)Porphyrins Bearing Prepositioned Phenol Functionalities

(2014) Cyrille Costentin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electrocatalytic H2 Evolution by Proton-Gated Hangman Iron Porphyrins

(2014) Daniel J. Graham et al.   ORGANOMETALLICS

Electrocatalytic CO2 reduction by M(bpy-R)(CO)4 (M = Mo, W; R = H, tBu) complexes. Electrochemical, spectroscopic, and computational studies and comparison with group 7 catalysts

(2014) Melissa L. Clark et al.   Chemical Science

Two Pathways for Electrocatalytic Oxidation of Hydrogen by a Nickel Bis(diphosphine) Complex with Pendant Amines in the Second Coordination Sphere

(2013) Jenny Y. Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Thermodynamic and Kinetic Hydricity of Ruthenium(II) Hydride Complexes

(2012) Yasuo Matsubara et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electrocatalytic Oxygen Reduction by Iron Tetra-arylporphyrins Bearing Pendant Proton Relays

(2012) Colin T. Carver et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electrocatalytic Hydrogen Evolution in Acidic Water with Molecular Cobalt Tetraazamacrocycles

(2012) Charles C. L. McCrory et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Local Proton Source Enhances CO2 Electroreduction to CO by a Molecular Fe Catalyst

(2012) C. Costentin et al.   SCIENCE

Molecular Electrocatalysts for the Oxidation of Hydrogen and the Production of Hydrogen - The Role of Pendant Amines as Proton Relays

(2011) Daniel L. DuBois et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Directing the Reactivity of [HFe4N(CO)12]−toward H+or CO2Reduction by Understanding the Electrocatalytic Mechanism

(2011) M. Diego Rail et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electrocatalytic Oxidation of Formate by [Ni(PR2NR′2)2(CH3CN)]2+Complexes

(2011) Brandon R. Galan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydrogen Generation by Hangman Metalloporphyrins

(2011) Chang Hoon Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Trialkylborane-Assisted CO2Reduction by Late Transition Metal Hydrides

(2011) Alexander J. M. Miller et al.   ORGANOMETALLICS

A Synthetic Nickel Electrocatalyst with a Turnover Frequency Above 100,000 s-1 for H2 Production

(2011) M. L. Helm et al.   SCIENCE

Hangman Corroles: Efficient Synthesis and Oxygen Reaction Chemistry

(2010) Dilek K. Dogutan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

First-Principles Calculation of pKaValues for Organic Acids in Nonaqueous Solution

(2009) Feizhi Ding et al.   JOURNAL OF ORGANIC CHEMISTRY

Efficient Synthesis of Water-Soluble Alkyl-bis(m-sulfonated-phenyl)- and Dialkyl-(m-sulfonated-phenyl)-phosphines and Their Evaluation in Rhodium-Catalyzed Hydrogenation of Maleic Acid in Water

(2009) László T. Mika et al.   ORGANOMETALLICS

Electrocatalytic and homogeneous approaches to conversion of CO2to liquid fuels

(2008) Eric E. Benson et al.   CHEMICAL SOCIETY REVIEWS

Pentakis(trifluoromethyl)phenyl, a Sterically Crowded and Electron-withdrawing Group:  Synthesis and Acidity of Pentakis(trifluoromethyl)benzene, -toluene, -phenol, and -aniline

(2008) Agnes Kütt et al.   JOURNAL OF ORGANIC CHEMISTRY