期刊
CHEMISTRY-AN ASIAN JOURNAL
卷 16, 期 15, 页码 2018-2021出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/asia.202100507
关键词
Metal-organic framework; MOF membrane; Gas permeation
资金
- PRESTO of the Japan Science and Technology Agency (JST) [JPMJPR141C]
- CREST of the Japan Science and Technology Agency (JST) [JPMJCR17I3]
- JSPS KAKENHI [JP18K14043, JP19H02734, JP20H02575, JP20K20564]
- China Scholarship Council [201806060138]
An efficient fabrication method for a metal-organic framework (MOF) membrane was reported in this study, with a 2D structure suitable for gas separation. The membrane obtained on a treated substrate was continuous and defect-free, while the one grown on an unmodified substrate had unfavorable crystal orientation.
In this study, we report an efficient fabrication method for the membrane of a metal-organic framework (MOF) (Kgm-OEt) which is one kind of kagome-type MOF with a two-dimensional (2D) sheet structure having one-dimensional (1D) channels suitable for separation of H-2 from other larger gases. The Kgm-OEt seed layer was created on an Al2O3 substrate using layer-by-layer (LBL) growth, then a membrane was fabricated by secondary growth. The membrane on a 3-aminopropyltriethoxysilane (APTEs)-treated substrate obtained in this method was continuous and defect-free with the crystal orientation suitable for gas transportation, while the membrane grown on an unmodified substrate was loosely packed with unfavorable crystal orientation.
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