Revealing the Dynamic Behaviors of Tetrahydrofuran for Tailoring the Active Species of Ziegler–Natta Catalysts

Revisiting the identity of δ-MgCl2: Part I. Structural disorder studied by synchrotron X-ray total scattering

(2020) Toru Wada et al.   JOURNAL OF CATALYSIS

Revisiting the identity of δ-MgCl2: Part II. Morphology and exposed surfaces studied by vibrational spectroscopies and DFT calculation

(2020) Alessandro Piovano et al.   JOURNAL OF CATALYSIS

Disclosing the Interaction between Carbon Monoxide and Alkylated Ti3+ Species: a Direct Insight into Ziegler–Natta Catalysis

(2020) Alessandro Piovano et al.   Journal of Physical Chemistry Letters

Entanglement Formation Mechanism in the POSS Modified Heterogeneous Ziegler–Natta Catalysts

(2019) Yuming Chen et al.   MACROMOLECULES

Facile high-temperature synthesis of weakly entangled polyethylene using a highly activated Ziegler-Natta catalyst

(2018) Wei Li et al.   JOURNAL OF CATALYSIS

Spectroscopic Evidences for TiCl4/Donor Complexes on the Surface of MgCl2-Supported Ziegler–Natta Catalysts

(2018) Alessandro Piovano et al.   Journal of Physical Chemistry C

The Multifaceted Role of Methylaluminoxane in Metallocene-Based Olefin Polymerization Catalysis

(2018) Marjolein E. Z. Velthoen et al.   MACROMOLECULES

Judicious Reduction of Supported Ti Catalyst Enables Access to Disentangled Ultrahigh Molecular Weight Polyethylene

(2018) Ravindra P. Gote et al.   MACROMOLECULES

Genesis of MgCl2 -based Ziegler-Natta Catalysts as Probed with Operando Spectroscopy

(2018) Alessandro Piovano et al.   CHEMPHYSCHEM

Ligands Make the Difference! Molecular Insights into CrVI/SiO2 Phillips Catalyst during Ethylene Polymerization

(2017) Caterina Barzan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Demystifying Ziegler–Natta Catalysts: The Origin of Stereoselectivity

(2017) Antonio Vittoria et al.   ACS Catalysis

Surface Investigation and Morphological Analysis of Structurally Disordered MgCl2 and MgCl2/TiCl4 Ziegler–Natta Catalysts

(2016) Maddalena D’Amore et al.   ACS Catalysis

Polyethylene with Reverse Co-monomer Incorporation: From an Industrial Serendipitous Discovery to Fundamental Understanding

(2015) Dimitrije Cicmil et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Probing the Coordinative Unsaturation and Local Environment of Ti3+ Sites in an Activated High-Yield Ziegler-Natta Catalyst

(2015) Elena Morra et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

From Multisite Polymerization Catalysis to Sustainable Materials and All-Polyolefin Composites

(2015) Markus Stürzel et al.   CHEMICAL REVIEWS

Activation and In Situ Ethylene Polymerization on Silica-Supported Ziegler–Natta Catalysts

(2015) Elena Groppo et al.   ACS Catalysis

Investigating Phthalate and 1,3-Diether Coverage and Dynamics on the (104) and (110) Surfaces of MgCl2-Supported Ziegler–Natta Catalysts

(2014) Raffaele Credendino et al.   Journal of Physical Chemistry C

Understanding the Chemical and Physical Transformations of a Ziegler-Natta Catalyst at the Initial Stage of Polymerization Kinetics: The Key Role of Alkylaluminum in the Catalyst Activation Process

(2014) Sumant Dwivedi et al.   MACROMOLECULAR CHEMISTRY AND PHYSICS

Olefin Polymerization with Supported Catalysts as an Exercise in Nanotechnology

(2013) Markus Klapper et al.   CHEMISTRY OF MATERIALS

Silica-supported Ti chloride tetrahydrofuranates, precursors of Ziegler–Natta catalysts

(2013) Kalaivani Seenivasan et al.   DALTON TRANSACTIONS

A Single-Crystal Model for MgCl2–Electron Donor Support Materials: [Mg3Cl5(THF)4Bu]2 (Bu = n-Butyl)

(2013) Sami Pirinen et al.   ORGANOMETALLICS

Tetrahydrofuran in TiCl4/THF/MgCl2: a Non-Innocent Ligand for Supported Ziegler–Natta Polymerization Catalysts

(2012) Etienne Grau et al.   ACS Catalysis

The potential of spectroscopic methods applied to heterogeneous catalysts for olefinpolymerization

(2012) Elena Groppo et al.   Catalysis Science & Technology

Quantitative Investigation of a Hybrid Ziegler-Natta Catalyst Support Prepared by Grafting Di(n-butyl)magnesium onto Partially Dehydroxylated Silica

(2011) Ming-Yung Lee et al.   CHEMISTRY-A EUROPEAN JOURNAL

Spectroscopic Investigation of Heterogeneous Ziegler-Natta Catalysts: Ti and Mg Chloride Tetrahydrofuranates, Their Interaction Compound, and the Role of the Activator

(2011) Kalaivani Seenivasan et al.   CHEMISTRY-A EUROPEAN JOURNAL

A periodic hybrid DFT approach (including dispersion) to MgCl2-supported Ziegler–Natta catalysts – 1: TiCl4 adsorption on MgCl2 crystal surfaces

(2011) Maddalena D’Amore et al.   JOURNAL OF CATALYSIS

Thermodynamics of Formation of Uncovered and Dimethyl Ether-Covered MgCl2 Crystallites. Consequences in the Structure of Ziegler–Natta Heterogeneous Catalysts

(2011) Raffaele Credendino et al.   Journal of Physical Chemistry C

Moving up and down the Titanium Oxidation State in Ziegler−Natta Catalysis

(2011) Naeimeh Bahri-Laleh et al.   MACROMOLECULES

Heterogeneity in the Distribution of Entanglement Density during Polymerization in Disentangled Ultrahigh Molecular Weight Polyethylene

(2011) Anurag Pandey et al.   MACROMOLECULES

Resolving surface chemical states in XPS analysis of first row transition metals, oxides and hydroxides: Sc, Ti, V, Cu and Zn

(2010) Mark C. Biesinger et al.   APPLIED SURFACE SCIENCE

Recent Developments in the Chemistry of Cubic Polyhedral Oligosilsesquioxanes

(2010) David B. Cordes et al.   CHEMICAL REVIEWS

Adsorption Species of Ethyl Benzoate in MgCl2-Supported Ziegler−Natta Catalysts. A Density Functional Theory Study

(2009) Denis V. Stukalov et al.   Journal of Physical Chemistry C

The role of electron donors on lateral surfaces of MgCl2-supported Ziegler–Natta catalysts: Observation by AFM and SEM

(2008) A ANDONI et al.   JOURNAL OF CATALYSIS

Periodic DFT and High-Resolution Magic-Angle-Spinning (HR-MAS)1H NMR Investigation of the Active Surfaces of MgCl2-Supported Ziegler−Natta Catalysts. The MgCl2Matrix

(2008) Vincenzo Busico et al.   Journal of Physical Chemistry C

Effects of MgCl2Crystallographic Structure on Active Centre Formation in Immobilized Single-Centre and Ziegler-Natta Catalysts for Ethylene Polymerization

(2008) Rubin Huang et al.   MACROMOLECULAR RAPID COMMUNICATIONS