Genesis of MgCl2 -based Ziegler-Natta Catalysts as Probed with Operando Spectroscopy

Quality control for Ziegler-Natta catalysis via spectroscopic fingerprinting

(2018) Paul Pletcher et al.   JOURNAL OF CATALYSIS

Ligands Make the Difference! Molecular Insights into CrVI/SiO2 Phillips Catalyst during Ethylene Polymerization

(2017) Caterina Barzan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Tuning the Ti3+ and Al3+ Synergy in an Al2O3/TiClx Catalyst To Modulate the Grade of the Produced Polyethylene

(2017) Alessandro Piovano et al.   ACS Catalysis

Toward Rational Design of Cu/SSZ-13 Selective Catalytic Reduction Catalysts: Implications from Atomic-Level Understanding of Hydrothermal Stability

(2017) James Song et al.   ACS Catalysis

Demystifying Ziegler–Natta Catalysts: The Origin of Stereoselectivity

(2017) Antonio Vittoria et al.   ACS Catalysis

Unraveling the Catalytic Synergy between Ti3+and Al3+Sites on a Chlorinated Al2O3: A Tandem Approach to Branched Polyethylene

(2016) Alessandro Piovano et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Accelerating the Research Approach to Ziegler–Natta Catalysts

(2016) Vincenzo Busico et al.   INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH

Heterogeneous Ziegler–Natta catalysts with various sizes of MgCl2 crystallites: synthesis and characterization

(2016) Eldin Redzic et al.   IRANIAN POLYMER JOURNAL

Determination and Modeling of MgCl2 Solubility in Methanol, Ethanol, 2-Propanol, and Their Mixtures from 283 to 343 K

(2016) Lanmu Zeng et al.   JOURNAL OF CHEMICAL AND ENGINEERING DATA

Structural Characterization of the EtOH–TiCl4–MgCl2 Ziegler–Natta Precatalyst

(2016) V. D’Anna et al.   Journal of Physical Chemistry C

Methoxymagnesium Chloride—Structure and Interaction with Electron Donors: Experimental and Computational Study

(2016) Ville H. Nissinen et al.   Journal of Physical Chemistry C

Surface Investigation and Morphological Analysis of Structurally Disordered MgCl2 and MgCl2/TiCl4 Ziegler–Natta Catalysts

(2016) Maddalena D’Amore et al.   ACS Catalysis

Structure–performance relationships of Cr/Ti/SiO2 catalysts modified with TEAl for oligomerisation of ethylene: tuning the selectivity towards 1-hexene

(2016) D. Cicmil et al.   Catalysis Science & Technology

Application of operando spectroscopy on catalytic reactions

(2016) Yulong Zhang et al.   Current Opinion in Chemical Engineering

Probing the Coordinative Unsaturation and Local Environment of Ti3+ Sites in an Activated High-Yield Ziegler-Natta Catalyst

(2015) Elena Morra et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stability of Fe-N-C Catalysts in Acidic Medium Studied by Operando Spectroscopy

(2015) Chang Hyuck Choi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

XAS and XES Techniques Shed Light on the Dark Side of Ziegler-Natta Catalysts: Active-Site Generation

(2015) Elena Groppo et al.   ChemCatChem

Polyethers as potential electron donors for Ziegler–Natta ethylene polymerization catalysts

(2015) Sami Pirinen et al.   JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL

Rational design of a CO 2 -resistant toluene hydrogenation catalyst based on FT-IR spectroscopy studies

(2014) Julien Scalbert et al.   JOURNAL OF CATALYSIS

Ziegler–Natta catalysts supported on crystalline and amorphous MgCl2/THF complexes

(2014) Sami Pirinen et al.   JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL

Multilateral characterization for industrial Ziegler–Natta catalysts toward elucidation of structure–performance relationship

(2013) Toshiaki Taniike et al.   JOURNAL OF CATALYSIS

MgCl2·6CH3OH: A Simple Molecular Adduct and Its Influence As a Porous Support for Olefin Polymerization

(2013) Edwin S. Gnanakumar et al.   ACS Catalysis

Precise Active Site Analysis for TiCl3/MgCl2 Ziegler-Natta Model Catalyst Based on Fractionation and Statistical Methods

(2013) Shougo Takahashi et al.   Catalysts

MgCl2·4((CH3)2CHCH2OH): A new molecular adduct for the preparation of TiClx/MgCl2 catalyst for olefin polymerization

(2012) K. S. Thushara et al.   DALTON TRANSACTIONS

Active centers in Ziegler–Natta catalysts: Formation kinetics and structure

(2012) Yury V. Kissin   JOURNAL OF CATALYSIS

Coadsorption model for first-principle description of roles of donors in heterogeneous Ziegler–Natta propylene polymerization

(2012) Toshiaki Taniike et al.   JOURNAL OF CATALYSIS

Theoretical Investigation of Active Sites at the Corners of MgCl2 Crystallites in Supported Ziegler–Natta Catalysts

(2012) Andrea Correa et al.   MACROMOLECULES

Operando surface spectroscopy—placing catalytic solids at work under the spotlight

(2012) C. O. Arean et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Tetrahydrofuran in TiCl4/THF/MgCl2: a Non-Innocent Ligand for Supported Ziegler–Natta Polymerization Catalysts

(2012) Etienne Grau et al.   ACS Catalysis

The potential of spectroscopic methods applied to heterogeneous catalysts for olefinpolymerization

(2012) Elena Groppo et al.   Catalysis Science & Technology

Operando Spectroscopy: the Knowledge Bridge to Assessing Structure-Performance Relationships in Catalyst Nanoparticles

(2011) Miguel A. Bañares   ADVANCED MATERIALS

Spectroscopic Investigation of Heterogeneous Ziegler-Natta Catalysts: Ti and Mg Chloride Tetrahydrofuranates, Their Interaction Compound, and the Role of the Activator

(2011) Kalaivani Seenivasan et al.   CHEMISTRY-A EUROPEAN JOURNAL

A periodic hybrid DFT approach (including dispersion) to MgCl2-supported Ziegler–Natta catalysts – 1: TiCl4 adsorption on MgCl2 crystal surfaces

(2011) Maddalena D’Amore et al.   JOURNAL OF CATALYSIS

Moving up and down the Titanium Oxidation State in Ziegler−Natta Catalysis

(2011) Naeimeh Bahri-Laleh et al.   MACROMOLECULES

Toward an Understanding of the Molecular Level Properties of Ziegler−Natta Catalyst Support with and without the Internal Electron Donor

(2010) K. S. Thushara et al.   Journal of Physical Chemistry C

Investigation of Planar Ziegler-Natta Model Catalysts Using Attenuated Total Reflection Infrared Spectroscopy

(2009) Adelaida Andoni et al.   CATALYSIS LETTERS

Active Site Formation in MgCl2−Supported Ziegler−Natta Catalysts. A Density Functional Theory Study

(2009) Denis V. Stukalov et al.   Journal of Physical Chemistry C

Surface Species of Titanium(IV) and Titanium(III) in MgCl2-Supported Ziegler−Natta Catalysts. A Periodic Density Functional Theory Study

(2009) Denis V. Stukalov et al.   MACROMOLECULES

Effect of dealcoholation of support in MgCl2-supported Ziegler–Natta catalysts on catalyst activity and polypropylene powder morphology

(2009) Ebrahim Jalali Dil et al.   POLYMER BULLETIN

Theoretical investigation of (MgCl2)xpolynuclear species formed during preparation of MgCl2-supported Ziegler–Natta catalysts from solid solvates

(2008) Finizia Auriemma et al.   JOURNAL OF APPLIED CRYSTALLOGRAPHY

The role of electron donors on lateral surfaces of MgCl2-supported Ziegler–Natta catalysts: Observation by AFM and SEM

(2008) A ANDONI et al.   JOURNAL OF CATALYSIS

Reductive Formation of Isospecific Ti Dinuclear Species on a MgCl2(110) Surface in Heterogeneous Ziegler-Natta Catalysts

(2008) Toshiaki Taniike et al.   MACROMOLECULAR RAPID COMMUNICATIONS