期刊
ORGANIC LETTERS
卷 15, 期 5, 页码 1140-1143出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol400334u
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-
资金
- National Institutes of Health [P50-GM086145]
A set of general methods for the palladium-catalyzed decarboxylative C3-allylation and C3-benzylation of indoles, starting from the corresponding N-alloc and N-Cbz indoles, respectively, is reported. This chemistry provides ready access to a wide range of functionalized indolenines in good to excellent yields. A tandem process, wherein the palladium catalyzed allylation chemistry is coupled with a Mizoroki-Heck reaction, offers a simple route to cinnamylated products.
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