Cobalt-Catalyzed Intermolecular C–H Amidation of Unactivated Alkanes

New Strategies for the Transition-Metal Catalyzed Synthesis of Aliphatic Amines

(2020) Aaron Trowbridge et al.   CHEMICAL REVIEWS

Cobalt‐Catalyzed Oxidative C−H Activation: Strategies and Concepts

(2020) Ruhuai Mei et al.   ChemSusChem

Quantitative Analysis on Two-Point Ligand Modulation of Iridium Catalysts for Chemodivergent C–H Amidation

(2020) Yeongyu Hwang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

C–H Amination Mediated by Cobalt Organoazide Adducts and the Cor-responding Cobalt Nitrenoid Intermediates

(2020) Yunjung Baek et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cerium-Catalyzed C–H Functionalizations of Alkanes Utilizing Alcohols as Hydrogen Atom Transfer Agents

(2020) Qing An et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cobalt-catalysed C–H methylation for late-stage drug diversification

(2020) Stig D. Friis et al.   Nature Chemistry

C‐H Activation Based Copper‐Catalyzed One‐Shot Synthesis of Organic Difluoroboron Complexes

(2020) Guangying Tan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Versatile Cp*Co(III)(LX) Catalyst System for Selective Intramolecular C–H Amidation Reactions

(2020) Jia Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Modular Tuning of Electrophilic Reactivity of Iridium Nitrenoids for the Intermolecular Selective α-Amidation of β-Keto Esters

(2020) Minhan Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

C(sp3)–H functionalizations of light hydrocarbons using decatungstate photocatalysis in flow

(2020) Gabriele Laudadio et al.   SCIENCE

Enantioconvergent Amination of Racemic Tertiary C–H Bonds

(2020) Kai Lang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Intermolecular Radical C–H Amination

(2020) Li-Mei Jin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed C(sp3 )−H Amidation: Sterically Driven Primary and Secondary C−H Site-Selectivity

(2019) Abolghasem Gus Bakhoda et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Selective N Functionalization of Methane and Ethane to Aminated Derivatives by Main-Group-Directed C–H Activation

(2019) Niles Jensen Gunsalus et al.   ORGANOMETALLICS

Asymmetric Induction and Enantiodivergence in Catalytic Radical C–H Amination via Enantiodifferentiative H-Atom Abstraction and Stereoretentive Radical Substitution

(2019) Kai Lang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Radical Construction of 5-Membered Cyclic Sulfonamides by Metalloradical C–H Amination

(2019) Yang Hu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Photocatalytic regio- and stereoselective C(sp3)–H functionalization of benzylic and allylic hydrocarbons as well as unactivated alkanes

(2019) Yanjun Li et al.   Nature Catalysis

Selective formation of γ-lactams via C–H amidation enabled by tailored iridium catalysts

(2018) Seung Youn Hong et al.   SCIENCE

Cobalt-Catalyzed C(sp3 )−H Functionalization Reactions

(2018) Tatsuhiko Yoshino et al.   Asian Journal of Organic Chemistry

Selective functionalization of methane, ethane, and higher alkanes by cerium photocatalysis

(2018) Anhua Hu et al.   SCIENCE

Catalytic Radical Process for Enantioselective Amination of C(sp3 )−H Bonds

(2018) Chaoqun Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective C(sp3 )-H Amidation of Thioamides Catalyzed by a CobaltIII /Chiral Carboxylic Acid Hybrid System

(2018) Seiya Fukagawa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Desymmetrization of cyclohexanes by site- and stereoselective C–H functionalization

(2018) Jiantao Fu et al.   NATURE

Metal-Catalyzed and Metal-Free Intermolecular Amination of Light Alkanes and Benzenes

(2016) Pericles Stavropoulos   COMMENTS ON INORGANIC CHEMISTRY

Copper Catalyzed sp3 C–H Etherification with Acyl Protected Phenols

(2016) Tolani K. Salvador et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic borylation of methane

(2016) K. T. Smith et al.   SCIENCE

Catalyst-controlled selectivity in the C-H borylation of methane and ethane

(2016) A. K. Cook et al.   SCIENCE

Intramolecular 1,5-C(sp3)–H radical amination via Co(ii)-based metalloradical catalysis for five-membered cyclic sulfamides

(2016) Hongjian Lu et al.   Chemical Science

A Facile Access to Primary Alkylamines and Anilines via Ir(III)-Catalyzed C–H Amidation Using Azidoformates

(2016) Hyunwoo Kim et al.   ACS Catalysis

Undirected, Homogeneous C–H Bond Functionalization: Challenges and Opportunities

(2016) John F. Hartwig et al.   ACS Central Science

Transition-Metal-Catalyzed C–N Bond Forming Reactions Using Organic Azides as the Nitrogen Source: A Journey for the Mild and Versatile C–H Amination

(2015) Kwangmin Shin et al.   ACCOUNTS OF CHEMICAL RESEARCH

Characterization of Porphyrin-Co(III)-‘Nitrene Radical’ Species Relevant in Catalytic Nitrene Transfer Reactions

(2015) Monalisa Goswami et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Evolution of C–H Bond Functionalization from Methane to Methodology

(2015) John F. Hartwig   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cobalt-catalysed site-selective intra- and intermolecular dehydrogenative amination of unactivated sp3 carbons

(2015) Xuesong Wu et al.   Nature Communications

Copper(II) Anilides in sp3 C-H Amination

(2014) Eun Sil Jang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Versatile Tripodal Cu(I) Reagent for C–N Bond Construction via Nitrene-Transfer Chemistry: Catalytic Perspectives and Mechanistic Insights on C–H Aminations/Amidinations and Olefin Aziridinations

(2014) Vivek Bagchi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Intermolecular Amidation and Imidation of Unactivated Alkanes

(2014) Ba L. Tran et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

On the Interpretation of Deuterium Kinetic Isotope Effects in CH Bond Functionalizations by Transition-Metal Complexes

(2012) Eric M. Simmons et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

C–H Bond Amination by Photochemically Generated Transient Borylnitrenes at Room Temperature: A Combined Experimental and Theoretical Investigation of the Insertion Mechanism and Influence of Substituents

(2012) Matthias Filthaus et al.   ORGANOMETALLICS

Adding Aliphatic C-H Bond Oxidations to Synthesis

(2012) M. C. White   SCIENCE

If CH Bonds Could Talk: Selective CH Bond Oxidation

(2011) Timothy Newhouse et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

C–H functionalization logic in total synthesis

(2011) Will R. Gutekunst et al.   CHEMICAL SOCIETY REVIEWS

Guiding principles for site selective and stereoselective intermolecular C–H functionalization by donor/acceptor rhodium carbenes

(2011) Huw M. L. Davies et al.   CHEMICAL SOCIETY REVIEWS

Mechanism of Cobalt(II) Porphyrin-Catalyzed C–H Amination with Organic Azides: Radical Nature and H-Atom Abstraction Ability of the Key Cobalt(III)–Nitrene Intermediates

(2011) Volodymyr Lyaskovskyy et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Regioselective Amination of Unactivated Alkanes by Hypervalent Sulfonylimino- 3-Bromane

(2011) M. Ochiai et al.   SCIENCE

Catalytic C–H functionalization by metalloporphyrins: recent developments and future directions

(2010) Hongjian Lu et al.   CHEMICAL SOCIETY REVIEWS

Cobalt(II)-Catalyzed Intermolecular Benzylic C−H Amination with 2,2,2-Trichloroethoxycarbonyl Azide (TrocN3)

(2009) Hongjian Lu et al.   ORGANOMETALLICS

Metal-Free Conversion of Methane and Cycloalkanes to Amines and Amides by Employing a Borylnitrene

(2008) Holger F. Bettinger et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Coinage Metal Catalyzed C−H Bond Functionalization of Hydrocarbons

(2008) M. Mar Díaz-Requejo et al.   CHEMICAL REVIEWS

Easy Alkane Catalytic Functionalization

(2008) B. Pilar Gómez-Emeterio et al.   ORGANOMETALLICS

Toward a Synthetically Useful Stereoselective C−H Amination of Hydrocarbons

(2007) Chungen Liang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY