Aerobic Oxidative Dehydrogenation of Ketones to 1,4-Enediones

Synthetic Strategy: Palladium-Catalyzed Dehydrogenation of Carbonyl Compounds

(2019) Toshikazu Hirao   JOURNAL OF ORGANIC CHEMISTRY

Copper-Catalyzed Desaturation of Lactones, Lactams, and Ketones under pH-Neutral Conditions

(2019) Ming Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Diastereoselective sp3-C-H Functionalization of Arylmethyl Ketones and Transformation of E - to Z -Products Through Photocatalysis

(2019) Gaurav K. Rastogi et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

α-Functionalization of 2-Vinylpyridines via a Chiral Phosphine Catalyzed Enantioselective Cross Rauhut–Currier Reaction

(2018) Cong Qin et al.   ORGANIC LETTERS

A Catalytic Cross-Olefination of Diazocompounds with Sulfoxonium Ylides

(2018) James Neuhaus et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Alkene Synthesis Using Phosphonium Ylides as Umpolung Reagents

(2018) Minh Duy Vu et al.   Asian Journal of Organic Chemistry

Metal- and Solvent-Free Phosphine Mediated Synthesis of Multisubstituted Furans via Intramolecular Annulation of 1, 4-Enediones

(2018) Venkatachalam Rajeshkumar et al.   ChemistrySelect

Crossover-Annulation/Oxygenation Approach to Functionalized Phenanthridines by Palladium–Copper Relay Catalysis

(2017) Xiang Liu et al.   ORGANIC LETTERS

Base-Free Conditions for Rhodium-Catalyzed Asymmetric Arylation To Produce Stereochemically Labile α-Aryl Ketones

(2016) Xiaowei Dou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium/Copper Co-catalyzed Oxidative C–H/C–H Carbonylation of Diphenylamines: A Way To Access Acridones

(2016) Jiangwei Wen et al.   ORGANIC LETTERS

Visible-Light-Mediated Oxidative Dimerization of Arylalkynes in the Open Air: Stereoselective Synthesis of (Z)-1,4-Enediones

(2016) Donglei Wei et al.   ORGANIC LETTERS

Palladium-Catalyzed Aerobic Dehydrogenation of Cyclic Hydrocarbons for the Synthesis of Substituted Aromatics and Other Unsaturated Products

(2016) Andrei V. Iosub et al.   ACS Catalysis

Chiral Sulfinamide Bisphosphine Catalysts: Design, Synthesis, and Application in Highly Enantioselective Intermolecular Cross-Rauhut-Currier Reactions

(2015) Wei Zhou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Heterogeneous synthesis of 1,4-enediones and 1,4-diketones with manganese oxide molecular sieves OMS-2 as a recyclable catalyst

(2015) Xu Meng et al.   CATALYSIS COMMUNICATIONS

C–H functionalization of terminal alkynes towards stereospecific synthesis of (E) or (Z) 2-methylthio-1,4-ene-diones

(2015) Shekaraiah Devari et al.   CHEMICAL COMMUNICATIONS

Palladium-Catalyzed Aerobic Oxidative Dehydrogenation of Cyclohexenes to Substituted Arene Derivatives

(2015) Andrei V. Iosub et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

I2/Cu-mediated self-sorting domino reaction of aryl β-ketoesters into symmetrical 2-carboalkoxy-1,4-enediones: application to synthesis of pyrazine, β-carboline and quinoxalines

(2015) Gandhesiri Satish et al.   RSC Advances

ZnII- and AuI-Catalyzed Regioselective Hydrative Oxidations of 3-En-1-ynes with Selectfluor: Realization of 1,4-Dioxo and 1,4-Oxohydroxy Functionalizations

(2014) Appaso Mahadev Jadhav et al.   CHEMISTRY-A EUROPEAN JOURNAL

Wacker-Type Oxidation and Dehydrogenation of Terminal Olefins Using Molecular Oxygen as the Sole Oxidant without Adding Ligand

(2014) Yu-Fei Wang et al.   ORGANIC LETTERS

Aerobic Oxidative Heck/Dehydrogenation Reactions of Cyclohexenones: Efficient Access tometa-Substituted Phenols

(2013) Yusuke Izawa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Aerobic Dehydrogenation of Cyclohexanone to Phenol Catalyzed by Pd(TFA)2/2-Dimethylaminopyridine: Evidence for the Role of Pd Nanoparticles

(2013) Doris Pun et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Aerobic Dehydrogenation of Cyclohexanone to Cyclohexenone Catalyzed by Pd(DMSO)2(TFA)2: Evidence for Ligand-Controlled Chemoselectivity

(2013) Tianning Diao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Efficient Synthesis of 3a,6a-Dihydrofuro[2,3-b]furans via a Novel Bicyclization

(2013) Wen-Ming Shu et al.   ORGANIC LETTERS

A Highly Tunable Stereoselective Dimerization of Methyl Ketone: Efficient Synthesis of E- and Z-1,4-Enediones

(2013) Kun Xu et al.   ORGANIC LETTERS

Target-oriented synthesis: miscellaneous synthetic routes to access 1,4-enediones through the coupling of 1,3-dicarbonyl compounds with multiform substrates

(2013) Yan-ping Zhu et al.   TETRAHEDRON

Total Synthesis of Thiaplakortone A: Derivatives as Metabolically Stable Leads for the Treatment of Malaria

(2013) Rebecca H. Pouwer et al.   ACS Medicinal Chemistry Letters

Overcoming the “Oxidant Problem”: Strategies to Use O2 as the Oxidant in Organometallic C–H Oxidation Reactions Catalyzed by Pd (and Cu)

(2012) Alison N. Campbell et al.   ACCOUNTS OF CHEMICAL RESEARCH

Recent advances in transition-metal catalyzed reactions using molecular oxygen as the oxidant

(2012) Zhuangzhi Shi et al.   CHEMICAL SOCIETY REVIEWS

Oxidative Ring Opening of 1,3-Diarylbenzo[c]heterocycles Using m-CPBA: Preparation of 1,2-Diaroylbenzenes

(2012) Meganathan Nandakumar et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Palladium-Catalyzed Intermolecular C3 Alkenylation of Indoles Using Oxygen as the Oxidant

(2012) Wen-Liang Chen et al.   ORGANIC LETTERS

Imparting Catalyst Control upon Classical Palladium-Catalyzed Alkenyl C–H Bond Functionalization Reactions

(2011) Matthew S. Sigman et al.   ACCOUNTS OF CHEMICAL RESEARCH

Catalytic Dehydrogenative Cross-Coupling: Forming Carbon−Carbon Bonds by Oxidizing Two Carbon−Hydrogen Bonds

(2011) Charles S. Yeung et al.   CHEMICAL REVIEWS

Laccase-catalyzed stereoselective oxidative ring opening of 2,5-dialkylfurans into 2-ene-1,4-diones using air as an oxidant

(2011) Chimène Asta et al.   GREEN CHEMISTRY

Synthesis of Cyclic Enones via Direct Palladium-Catalyzed Aerobic Dehydrogenation of Ketones

(2011) Tianning Diao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Aerobic Dehydrogenation of Substituted Cyclohexanones to Phenols

(2011) Y. Izawa et al.   SCIENCE

Direct aerobic α,β-dehydrogenation of aldehydes and ketones with a Pd(TFA)2/4,5-diazafluorenone catalyst

(2011) Tianning Diao et al.   Chemical Science

General palladium-catalyzed aerobic dehydrogenation to generate double bonds

(2011) Weiming Gao et al.   Chemical Science

One-Pot Syntheses of α,β-Unsaturated Carbonyl Compounds through Palladium-Mediated Dehydrogenation of Ketones, ­Aldehydes, Esters, Lactones and Amides

(2010) Jacques Muzart   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Development of safe and scalable continuous-flow methods for palladium-catalyzed aerobic oxidation reactions

(2010) Xuan Ye et al.   GREEN CHEMISTRY

Experimental and Computational Study of a Direct O2-Coupled Wacker Oxidation: Water Dependence in the Absence of Cu Salts

(2010) Brian J. Anderson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An Efficient Synthesis of Hydantoins via Sustainable Integration of Coupled Domino Processes

(2010) Meng Gao et al.   ORGANIC LETTERS

Formation of Unsymmetrical 1,4-Enediones via A Focusing Domino Strategy: Cross-Coupling of 1,3-Dicarbonyl Compounds and Methyl Ketones or Terminal Aryl Alkenes

(2010) Meng Gao et al.   ORGANIC LETTERS

The Mechanism of the Wacker Reaction: A Tale of Two Hydroxypalladations

(2009) John���A. Keith et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent advancements and challenges of palladiumII-catalyzed oxidation reactions with molecular oxygen as the sole oxidant

(2009) Keith M. Gligorich et al.   CHEMICAL COMMUNICATIONS

Rhabdastrellins A−F, Isomalabaricane Triterpenes from the Marine SpongeRhabdastrellaaff.distincta

(2008) Fang Lv et al.   JOURNAL OF NATURAL PRODUCTS

A New Facile Approach to the Synthesis of 3-Methylthio-Substituted Furans, Pyrroles, Thiophenes, and Related Derivatives

(2008) Guodong Yin et al.   JOURNAL OF ORGANIC CHEMISTRY

Allylic Oxidations Catalyzed by Dirhodium Caprolactamate via Aqueoustert-Butyl Hydroperoxide: The Role of thetert-Butylperoxy Radical

(2008) Emily C. McLaughlin et al.   JOURNAL OF ORGANIC CHEMISTRY

Mechanistic Study of β-Hydrogen Elimination from Organoplatinum(II) Enolate Complexes

(2008) Erik J. Alexanian et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY