期刊
MACROMOLECULAR RAPID COMMUNICATIONS
卷 42, 期 7, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/marc.202000718
关键词
crosslinking; dynamic disulfide bonds; polythiourethane; reprocessing properties
资金
- National Natural Science Foundation of China [51973113, 51133003, 21774078]
Polythiourethanes (PTUs) crosslinked with dynamic disulfide bonds are synthesized using a nonisocyanate approach. The materials can be tailored into thermosetting plastics or crosslinked elastomers depending on the molar masses of the alpha,omega-diamino poly(propylene oxide)s. These materials display excellent reprocessing properties at elevated temperatures due to the metathesis reaction of dynamic disulfide bonds.
Polythiourethanes (PTUs) crosslinked with dynamic disulfide bonds are synthesized via a nonisocyanate approach. First, a difunctional five-membered cyclic trithiocarbonate (1) is synthesized via the reaction of diglycidyl ether of bisphenol A (DGEBA) with carbon disulfide (CS2). Thereafter, the step-growth polymerizations of 1 with alpha,omega-diamino poly(propylene oxide)s with various molar masses are carried out to obtain a series of linear poly(mercapto thiourethane)s. These linear poly(mercapto thiourethane)s are readily crosslinked upon formation of disulfide bonds, which are generated via radical coupling reaction with the side mercapto groups. These crosslinked PTUs can be tailored into the materials from thermosetting plastics to crosslinked elastomers, depending on the molar masses of alpha,omega-diamino poly(propylene oxide)s. More importantly, these crosslinked PTUs display excellent reprocessing properties at elevated temperatures, which is attributable to the metathesis reaction of dynamic disulfide bonds.
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