期刊
IONICS
卷 27, 期 5, 页码 1957-1966出版社
SPRINGER HEIDELBERG
DOI: 10.1007/s11581-021-03977-3
关键词
Lithium-ion batteries; CVD method; Natural microcrystalline graphite; Si; C composites
资金
- National Key Research and Development Program of China [2018YFB1502504]
This paper presents a potential method for large-scale production of silicon/natural microcrystalline graphite@ carbon layer composites, which demonstrate high specific capacity and stability. These composites are expected to solve the high-level application problem of natural microcrystalline graphite.
Silicon/carbon composite is considered as one of the most potential anode materials to be commercialized because of silicon's high specific capacity and carbon's stability. Natural microcrystalline graphite features abundant resources, low price, and high stability. In consideration of these, it is an ingenious strategy to combine natural microcrystalline graphite with silicon as the anode material of lithium-ion batteries. In this paper, silicon/natural microcrystalline graphite@ carbon layer composites were fabricated by a two-step chemical vapor deposition (CVD) method. In this structure, natural microcrystalline graphite serves as the carbon matrix; silicon grows evenly on the surface and then pyrolytic carbon provides a tight coating. Therefore, the prepared composites deliver a high specific capacity of 560 mA h g(-1) after 200 cycles at a current density of 100 mA g(-1). This paper provides a potential method for large-scale production and is expected to solve the high-level application problem of natural microcrystalline graphite.
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