Synergy between metals for small molecule activation: Enzymes and bio-inspired complexes

Electron Transfer in Nitrogenase

(2020) Hannah L. Rutledge et al.   CHEMICAL REVIEWS

The Spectroscopy of Nitrogenases

(2020) Casey Van Stappen et al.   CHEMICAL REVIEWS

Activation of Dinitrogen by Polynuclear Metal Complexes

(2020) Devender Singh et al.   CHEMICAL REVIEWS

Reduction of Substrates by Nitrogenases

(2020) Lance C. Seefeldt et al.   CHEMICAL REVIEWS

Catalytic N2-to-NH3 (or -N2H4) Conversion by Well-Defined Molecular Coordination Complexes

(2020) Matthew J. Chalkley et al.   CHEMICAL REVIEWS

Metal–Sulfur Compounds in N2 Reduction and Nitrogenase-Related Chemistry

(2020) Kazuki Tanifuji et al.   CHEMICAL REVIEWS

Mimicking the Constrained Geometry of a Nitrogen-Fixation Intermediate

(2020) Tianchang Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Current State of [FeFe]-hydrogenase Research - Biodiversity and Spectroscopic Investigations

(2020) Henrik Land et al.   ACS Catalysis

Structural Enzymology of Nitrogenase Enzymes

(2020) Oliver Einsle et al.   CHEMICAL REVIEWS

A W/Cu Synthetic Model for the Mo/Cu Cofactor of Aerobic CODH Indicates That Biochemical CO Oxidation Requires a Frustrated Lewis Acid/Base Pair

(2020) Dibbendu Ghosh et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Biochemical Nickel(I) State Supports Nucleophilic Alkyl Addition: A Roadmap for Methyl Reactivity in Acetyl Coenzyme A Synthase

(2019) Anastasia C. Manesis et al.   INORGANIC CHEMISTRY

Source and reduction of nitrous oxide

(2019) Sofia R. Pauleta et al.   COORDINATION CHEMISTRY REVIEWS

Structure Effects of Metal Corroles on Energy-Related Small Molecule Activation Reactions

(2019) Haitao Lei et al.   ACS Catalysis

Engineered Enzymes and Bioinspired Catalysts for Energy Conversion

(2019) Jennifer M. Le et al.   ACS Energy Letters

Unifying Activity, Structure, and Spectroscopy of [NiFe] Hydrogenases: Combining Techniques To Clarify Mechanistic Understanding

(2019) Philip A. Ash et al.   ACCOUNTS OF CHEMICAL RESEARCH

N2 O Reductase Activity of a [Cu4 S] Cluster in the 4CuI Redox State Modulated by Hydrogen Bond Donors and Proton Relays in the Secondary Coordination Sphere

(2019) Chia-Wei Hsu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Spectroscopic and Computational Evidence that [FeFe] Hydrogenases Operate Exclusively with CO-Bridged Intermediates

(2019) James A. Birrell et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Role of the Metal Ion in Bio-Inspired Hydrogenase Models: Investigation of a Homodinuclear FeFe Complex vs Its Heterodinuclear NiFe Analogue

(2019) Lianke Wang et al.   ACS Catalysis

The Molecular Proceedings of Biological Hydrogen Turnover

(2018) Michael Haumann et al.   ACCOUNTS OF CHEMICAL RESEARCH

Hydrogen and oxygen trapping at the H-cluster of [FeFe]-hydrogenase revealed by site-selective spectroscopy and QM/MM calculations

(2018) Stefan Mebs et al.   BIOCHIMICA ET BIOPHYSICA ACTA-BIOENERGETICS

Oxidation of a [Cu2S] complex by N2O and CO2: insights into a role of tetranuclearity in the CuZ site of nitrous oxide reductase

(2018) Sharareh Bagherzadeh et al.   CHEMICAL COMMUNICATIONS

Oxygen Reduction by Homogeneous Molecular Catalysts and Electrocatalysts

(2018) Michael L. Pegis et al.   CHEMICAL REVIEWS

Oxygen Activation and Energy Conservation by Cytochrome c Oxidase

(2018) Mårten Wikström et al.   CHEMICAL REVIEWS

Cooperative bimetallic reactivity of a heterodinuclear molybdenum–copper model of Mo–Cu CODH

(2018) Thilini S. Hollingsworth et al.   DALTON TRANSACTIONS

Direct Detection of the Terminal Hydride Intermediate in [FeFe] Hydrogenase by NMR Spectroscopy

(2018) Sigrun Rumpel et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reaction Mechanism and Kinetics for Ammonia Synthesis on the Fe(111) Surface

(2018) Jin Qian et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct CO2 Addition to a Ni(0)–CO Species Allows the Selective Generation of a Nickel(II) Carboxylate with Expulsion of CO

(2018) Dipankar Sahoo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Incorporating light atoms into synthetic analogues of FeMoco

(2018) Daniel E. DeRosha et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

A water-soluble supramolecular complex that mimics the heme/copper hetero-binuclear site of cytochrome c oxidase

(2018) Hiroaki Kitagishi et al.   Chemical Science

Models for aerobic carbon monoxide dehydrogenase: synthesis, characterization and reactivity of paramagnetic MoVO(μ-S)CuI complexes

(2018) Craig Gourlay et al.   Chemical Science

Synthetic Fe/Cu Complexes: Toward Understanding Heme-Copper Oxidase Structure and Function

(2018) Suzanne M. Adam et al.   CHEMICAL REVIEWS

Tuning Reactivity of Bioinspired [NiFe]-Hydrogenase Models by Ligand Design and Modeling the CO Inhibition Process

(2018) Deborah Brazzolotto et al.   ACS Catalysis

The catalytic cycle of nitrous oxide reductase — The enzyme that catalyzes the last step of denitrification

(2017) Cíntia Carreira et al.   JOURNAL OF INORGANIC BIOCHEMISTRY

Intercluster Redox Coupling Influences Protonation at the H-cluster in [FeFe] Hydrogenases

(2017) Patricia Rodríguez-Maciá et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Self-Assembled Cofacial Cobalt Porphyrin Prism for Oxygen Reduction Catalysis

(2017) Amanda N. Oldacre et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Activation of Small Molecules at Nickel(I) Moieties

(2017) Philipp Zimmermann et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Spectroscopic Definition of the CuZ° Intermediate in Turnover of Nitrous Oxide Reductase and Molecular Insight into the Catalytic Mechanism

(2017) Esther M. Johnston et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Proton Coupled Electronic Rearrangement within the H-Cluster as an Essential Step in the Catalytic Cycle of [FeFe] Hydrogenases

(2017) Constanze Sommer et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct Observation of an Iron-Bound Terminal Hydride in [FeFe]-Hydrogenase by Nuclear Resonance Vibrational Spectroscopy

(2017) Edward J. Reijerse et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Carbon dioxide binding at a Ni/Fe center: synthesis and characterization of Ni(η1-CO2-κC) and Ni-μ-CO2-κC:κ2O,O′-Fe

(2017) Changho Yoo et al.   Chemical Science

Remarkable catalytic activity of dinitrogen-bridged dimolybdenum complexes bearing NHC-based PCP-pincer ligands toward nitrogen fixation

(2017) Aya Eizawa et al.   Nature Communications

Bioinspired catalytic materials for energy-relevant conversions

(2017) Vincent Artero   Nature Energy

Interplay between Theory and Experiment for Ammonia Synthesis Catalyzed by Transition Metal Complexes

(2016) Hiromasa Tanaka et al.   ACCOUNTS OF CHEMICAL RESEARCH

Nitrogen-Based Fuels: A Power-to-Fuel-to-Power Analysis

(2016) Alon Grinberg Dana et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Hydrogenase Enzymes and Their Synthetic Models: The Role of Metal Hydrides

(2016) David Schilter et al.   CHEMICAL REVIEWS

Energy-Related Small Molecule Activation Reactions: Oxygen Reduction and Hydrogen and Oxygen Evolution Reactions Catalyzed by Porphyrin- and Corrole-Based Systems

(2016) Wei Zhang et al.   CHEMICAL REVIEWS

Recent Advances in Electrocatalysts for Oxygen Reduction Reaction

(2016) Minhua Shao et al.   CHEMICAL REVIEWS

Small molecule activation

(2016) Barbara Milani et al.   DALTON TRANSACTIONS

A perspective on low-temperature solid oxide fuel cells

(2016) Zhan Gao et al.   Energy & Environmental Science

A One-Hole Cu4S Cluster with N2O Reductase Activity: A Structural and Functional Model for CuZ*

(2016) Brittany J. Johnson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Insight into the Iron–Molybdenum Cofactor of Nitrogenase from Synthetic Iron Complexes with Sulfur, Carbon, and Hydride Ligands

(2016) Ilija Čorić et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hemilabile Bridging Thiolates as Proton Shuttles in Bioinspired H2 Production Electrocatalysts

(2016) Shengda Ding et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reductive Elimination of H2 Activates Nitrogenase to Reduce the N≡N Triple Bond: Characterization of the E4(4H) Janus Intermediate in Wild-Type Enzyme

(2016) Dmitriy Lukoyanov et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-centred proton reduction catalysis in a model of [NiFe] hydrogenase

(2016) Deborah Brazzolotto et al.   Nature Chemistry

Why copper is preferred over iron for oxygen activation and reduction in haem-copper oxidases

(2016) Ambika Bhagi-Damodaran et al.   Nature Chemistry

A broken-symmetry density functional study of structures, energies, and protonation states along the catalytic O–O bond cleavage pathway in ba3 cytochrome c oxidase from Thermus thermophilus

(2016) Wen-Ge Han Du et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Stepwise N–H bond formation from N2-derived iron nitride, imide and amide intermediates to ammonia

(2016) K. Cory MacLeod et al.   Chemical Science

Metal–Metal Bonds in Catalysis

(2016) Ian G. Powers et al.   ACS Catalysis

Dinitrogen Binding and Cleavage by Multinuclear Iron Complexes

(2015) Sean F. McWilliams et al.   ACCOUNTS OF CHEMICAL RESEARCH

Combining a Nitrogenase Scaffold and a Synthetic Compound into an Artificial Enzyme

(2015) Kazuki Tanifuji et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Infrared Spectroscopy During Electrocatalytic Turnover Reveals the Ni-L Active Site State During H2Oxidation by a NiFe Hydrogenase

(2015) Ricardo Hidalgo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Lessons from Nature: A Bio-Inspired Approach to Molecular Design

(2015) Sarah A. Cook et al.   BIOCHEMISTRY

Infrared and Raman spectroscopic investigation of the reaction mechanism of cytochrome c oxidase

(2015) Satoru Nakashima et al.   BIOCHIMICA ET BIOPHYSICA ACTA-BIOENERGETICS

Metallodithiolates as Ligands in Coordination, Bioinorganic, and Organometallic Chemistry

(2015) Jason A. Denny et al.   CHEMICAL REVIEWS

Reaction Mechanism of Cytochrome c Oxidase

(2015) Shinya Yoshikawa et al.   CHEMICAL REVIEWS

Hydrogen-activating models of hydrogenases

(2015) Tao Xu et al.   COORDINATION CHEMISTRY REVIEWS

Identification of a Key Catalytic Intermediate Demonstrates That Nitrogenase Is Activated by the Reversible Exchange of N2 for H2

(2015) Dmitriy Lukoyanov et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Discovery of Dark pH-Dependent H+ Migration in a [NiFe]-Hydrogenase and Its Mechanistic Relevance: Mobilizing the Hydrido Ligand of the Ni-C Intermediate

(2015) Bonnie J. Murphy et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Proton-Coupled Electron Transfer Dynamics in the Catalytic Mechanism of a [NiFe]-Hydrogenase

(2015) Brandon L. Greene et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Diiron Bridged-Thiolate Complexes That Bind N2 at the FeIIFeII, FeIIFeI, and FeIFeI Redox States

(2015) Sidney E. Creutz et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dioxygen Activation and Catalytic Reduction to Hydrogen Peroxide by a Thiolate-Bridged Dimanganese(II) Complex with a Pendant Thiol

(2015) Marcello Gennari et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electrocatalytic O2-Reduction by Synthetic Cytochrome c Oxidase Mimics: Identification of a “Bridging Peroxo” Intermediate Involved in Facile 4e–/4H+ O2-Reduction

(2015) Sudipta Chatterjee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydrogens detected by subatomic resolution protein crystallography in a [NiFe] hydrogenase

(2015) Hideaki Ogata et al.   NATURE

Nitrogen fixation catalyzed by ferrocene-substituted dinitrogen-bridged dimolybdenum–dinitrogen complexes: unique behavior of ferrocene moiety as redox active site

(2015) Shogo Kuriyama et al.   Chemical Science

Dinitrogen Activation Upon Reduction of a Triiron(II) Complex

(2014) Yousoon Lee et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Quantum Chemical Studies of Mechanisms for Metalloenzymes

(2014) Margareta R. A. Blomberg et al.   CHEMICAL REVIEWS

The Mononuclear Molybdenum Enzymes

(2014) Russ Hille et al.   CHEMICAL REVIEWS

Multimetallic Catalysis Based on Heterometallic Complexes and Clusters

(2014) Paulin Buchwalter et al.   CHEMICAL REVIEWS

Developments in the Biomimetic Chemistry of Cubane-Type and Higher Nuclearity Iron–Sulfur Clusters

(2014) Sonny C. Lee et al.   CHEMICAL REVIEWS

Mechanism of Nitrogen Fixation by Nitrogenase: The Next Stage

(2014) Brian M. Hoffman et al.   CHEMICAL REVIEWS

Hydrogenases

(2014) Wolfgang Lubitz et al.   CHEMICAL REVIEWS

Structure, Function, and Mechanism of the Nickel Metalloenzymes, CO Dehydrogenase, and Acetyl-CoA Synthase

(2014) Mehmet Can et al.   CHEMICAL REVIEWS

Mimicking hydrogenases: From biomimetics to artificial enzymes

(2014) Trevor R. Simmons et al.   COORDINATION CHEMISTRY REVIEWS

[NiFe] hydrogenases: how close do structural and functional mimics approach the active site?

(2014) Sandeep Kaur-Ghumaan et al.   DALTON TRANSACTIONS

Linking Chemical Electron–Proton Transfer to Proton Pumping in Cytochrome c Oxidase: Broken-Symmetry DFT Exploration of Intermediates along the Catalytic Reaction Pathway of the Iron–Copper Dinuclear Complex

(2014) Louis Noodleman et al.   INORGANIC CHEMISTRY

Alkali Metal Control over N–N Cleavage in Iron Complexes

(2014) Katarzyna Grubel et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Formation of Ammonia from Molecular Dinitrogen by Use of Dinitrogen-Bridged Dimolybdenum–Dinitrogen Complexes Bearing PNP-Pincer Ligands: Remarkable Effect of Substituent at PNP-Pincer Ligand

(2014) Shogo Kuriyama et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Multi-iron System Capable of Rapid N2 Formation and N2 Cleavage

(2014) K. Cory MacLeod et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Investigations on the Role of Proton-Coupled Electron Transfer in Hydrogen Activation by [FeFe]-Hydrogenase

(2014) David W. Mulder et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Transmethylation of a four-coordinate nickel(i) monocarbonyl species with methyl iodide

(2014) Changho Yoo et al.   Chemical Science

N2O reduction at a dissymmetric {Cu2S}-containing mixed-valent center

(2014) Charlène Esmieu et al.   Chemical Science

Identification of a spin-coupled Mo(iii) in the nitrogenase iron–molybdenum cofactor

(2014) Ragnar Bjornsson et al.   Chemical Science

Unique behaviour of dinitrogen-bridged dimolybdenum complexes bearing pincer ligand towards catalytic formation of ammonia

(2014) Hiromasa Tanaka et al.   Nature Communications

Nitrogenase: A Draft Mechanism

(2013) Brian M. Hoffman et al.   ACCOUNTS OF CHEMICAL RESEARCH

The Haber-Bosch Process Revisited: On the Real Structure and Stability of “Ammonia Iron” under Working Conditions

(2013) Timur Kandemir et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mechanistic aspects of dinitrogen cleavage and hydrogenation to produce ammonia in catalysis and organometallic chemistry: relevance of metal hydride bonds and dihydrogen

(2013) Hong-Peng Jia et al.   CHEMICAL SOCIETY REVIEWS

Effective Pumping Proton Collection Facilitated by a Copper Site (CuB) of Bovine Heart CytochromecOxidase, Revealed by a Newly Developed Time-resolved Infrared System

(2013) Minoru Kubo et al.   JOURNAL OF BIOLOGICAL CHEMISTRY

A Metal–Metal Bond in the Light-Induced State of [NiFe] Hydrogenases with Relevance to Hydrogen Evolution

(2013) Mario Kampa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

EPR and FTIR Analysis of the Mechanism of H2 Activation by [FeFe]-Hydrogenase HydA1 from Chlamydomonas reinhardtii

(2013) David W. Mulder et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Determination of the Active Form of the Tetranuclear Copper Sulfur Cluster in Nitrous Oxide Reductase

(2013) Esther M. Johnston et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Biomimetic assembly and activation of [FeFe]-hydrogenases

(2013) G. Berggren et al.   NATURE

Recent developments in the homogeneous reduction of dinitrogen by molybdenum and iron

(2013) K. Cory MacLeod et al.   Nature Chemistry

Dinuclear heme and non-heme metal complexes as bioinspired catalysts for oxidation reactions

(2013) Valentina Pirota et al.   NEW JOURNAL OF CHEMISTRY

On reversible H2 loss upon N2 binding to FeMo-cofactor of nitrogenase

(2013) Z.-Y. Yang et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

A Functional [NiFe]Hydrogenase Mimic That Catalyzes Electron and Hydride Transfer from H2

(2013) S. Ogo et al.   SCIENCE

Multimetallic cooperativity in activation of dinitrogen at iron–potassium sites

(2013) Karen P. Chiang et al.   Chemical Science

New Insights into the Biological and Synthetic Fixation of Nitrogen

(2012) Markus G. Scheibel et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Identification and Characterization of the “Super-Reduced” State of the H-Cluster in [FeFe] Hydrogenase: A New Building Block for the Catalytic Cycle?

(2012) Agnieszka Adamska et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nature’s way of handling a greenhouse gas: the copper-sulfur cluster of purple nitrous oxide reductase

(2012) Anja Wüst et al.   BIOLOGICAL CHEMISTRY

Four-electron reduction of dioxygen catalysed by dinuclear cobalt complexes bridged by bis(terpyridyl)anthracene

(2012) Tohru Wada et al.   CHEMICAL COMMUNICATIONS

Electron-Transfer Reduction of Dinuclear Copper Peroxo and Bis-μ-oxo Complexes Leading to the Catalytic Four-Electron Reduction of Dioxygen to Water

(2012) Laleh Tahsini et al.   CHEMISTRY-A EUROPEAN JOURNAL

Simple Ligand Effects Switch a Hydrogenase Mimic between H2and O2Activation

(2012) Kyoungmok Kim et al.   Chemistry-An Asian Journal

Nitrous oxide reductase

(2012) Sofia R. Pauleta et al.   COORDINATION CHEMISTRY REVIEWS

Cooperativity Between Low-Valent Iron and Potassium Promoters in Dinitrogen Fixation

(2012) Travis M. Figg et al.   INORGANIC CHEMISTRY

A Nitrogenase Cluster Model [Fe8S6O] with an Oxygen Unsymmetrically Bridging Two Proto-Fe4S3 Cubes: Relevancy to the Substrate Binding Mode of the FeMo Cofactor

(2012) Shun Ohta et al.   INORGANIC CHEMISTRY

Catalytic Four-Electron Reduction of O2 via Rate-Determining Proton-Coupled Electron Transfer to a Dinuclear Cobalt-μ-1,2-peroxo Complex

(2012) Shunichi Fukuzumi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Factors That Control Catalytic Two- versus Four-Electron Reduction of Dioxygen by Copper Complexes

(2012) Shunichi Fukuzumi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthetic Models for the Active Site of the [FeFe]-Hydrogenase: Catalytic Proton Reduction and the Structure of the Doubly Protonated Intermediate

(2012) Maria E. Carroll et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Functional [NiFe]-Hydrogenase Model Compound That Undergoes Biologically Relevant Reversible Thiolate Protonation

(2012) Katharina Weber et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis and Catalytic Activity of Molybdenum–Dinitrogen Complexes Bearing Unsymmetric PNP-Type Pincer Ligands

(2012) Eriko Kinoshita et al.   ORGANOMETALLICS

Synthesis and Protonation of Molybdenum– and Tungsten–Dinitrogen Complexes Bearing PNP-Type Pincer Ligands

(2012) Kazuya Arashiba et al.   ORGANOMETALLICS

Unification of reaction pathway and kinetic scheme for N2 reduction catalyzed by nitrogenase

(2012) D. Lukoyanov et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Molecular Catalysis in a Fuel Cell

(2011) Takahiro Matsumoto et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Dinitrogen Complexes of Sulfur-Ligated Iron

(2011) Ayumi Takaoka et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

N2O binding at a [4Cu:2S] copper–sulphur cluster in nitrous oxide reductase

(2011) Anja Pomowski et al.   NATURE

Combining acid–base, redox and substrate binding functionalities to give a complete model for the [FeFe]-hydrogenase

(2011) James M. Camara et al.   Nature Chemistry

Homogeneous catalytic O2 reduction to water by a cytochrome c oxidase model with trapping of intermediates and mechanistic insights

(2011) Z. Halime et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

N2 Reduction and Hydrogenation to Ammonia by a Molecular Iron-Potassium Complex

(2011) M. M. Rodriguez et al.   SCIENCE

Evidence for Interstitial Carbon in Nitrogenase FeMo Cofactor

(2011) T. Spatzal et al.   SCIENCE

Binding and Activation of N2O at Transition-Metal Centers: Recent Mechanistic Insights

(2010) William B. Tolman   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Attachment of a Hydrogen-Bonding Carboxylate Side Chain to an [FeFe]-Hydrogenase Model Complex: Influence on the Catalytic Mechanism

(2010) Weiming Gao et al.   CHEMISTRY-A EUROPEAN JOURNAL

A dinuclear nickel complex modeling of the Nid(ii)-Nip(i) state of the active site of acetyl CoA synthase

(2010) Tsuyoshi Matsumoto et al.   DALTON TRANSACTIONS

A new CuZ active form in the catalytic reduction of N2O by nitrous oxide reductase from Pseudomonas nautica

(2010) Simone Dell’Acqua et al.   JOURNAL OF BIOLOGICAL INORGANIC CHEMISTRY

Is Mo Involved in Hydride Binding by the Four-Electron Reduced (E4) Intermediate of the Nitrogenase MoFe Protein?

(2010) Dmitriy Lukoyanov et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A molybdenum complex bearing PNP-type pincer ligands leads to the catalytic reduction of dinitrogen into ammonia

(2010) Kazuya Arashiba et al.   Nature Chemistry

Climbing Nitrogenase: Toward a Mechanism of Enzymatic Nitrogen Fixation

(2009) Brian M. Hoffman et al.   ACCOUNTS OF CHEMICAL RESEARCH

Mechanism of Mo-Dependent Nitrogenase

(2009) Lance C. Seefeldt et al.   Annual Review of Biochemistry

Structural and Functional Analogues of the Active Sites of the [Fe]-, [NiFe]-, and [FeFe]-Hydrogenases†

(2009) Cédric Tard et al.   CHEMICAL REVIEWS

Reactions of Monodithiolene Tungsten(VI) Sulfido Complexes with Copper(I) in Relation to the Structure of the Active Site of Carbon Monoxide Dehydrogenase

(2009) Stanislav Groysman et al.   INORGANIC CHEMISTRY

Reduction of Nitrous Oxide to Dinitrogen by a Mixed Valent Tricopper-Disulfido Cluster

(2009) Itsik Bar-Nahum et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

14N HYSCORE investigation of the H-cluster of [FeFe] hydrogenase: evidence for a nitrogen in the dithiol bridge

(2009) Alexey Silakov et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Nitrous Oxide (N2O): The Dominant Ozone-Depleting Substance Emitted in the 21st Century

(2009) A. R. Ravishankara et al.   SCIENCE

Electron and proton transfers at diiron dithiolate sites relevant to the catalysis of proton reduction by the [FeFe]-hydrogenases

(2008) Jean-François Capon et al.   COORDINATION CHEMISTRY REVIEWS

Transformation of the Nitrogen Cycle: Recent Trends, Questions, and Potential Solutions

(2008) J. N. Galloway et al.   SCIENCE