Nickel-centred proton reduction catalysis in a model of [NiFe] hydrogenase

Electrocatalytic Dihydrogen Production with a Robust Mesoionic Pyridylcarbene Cobalt Catalyst

(2015) Margarethe van der Meer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Infrared Spectroscopy During Electrocatalytic Turnover Reveals the Ni-L Active Site State During H2Oxidation by a NiFe Hydrogenase

(2015) Ricardo Hidalgo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Ni(i)Fe(ii) analogue of the Ni-L state of the active site of the [NiFe] hydrogenases

(2015) Carlo U. Perotto et al.   CHEMICAL COMMUNICATIONS

Metallodithiolates as Ligands in Coordination, Bioinorganic, and Organometallic Chemistry

(2015) Jason A. Denny et al.   CHEMICAL REVIEWS

Models of the Ni-L and Ni-SIa States of the [NiFe]-Hydrogenase Active Site

(2015) Geoffrey M. Chambers et al.   INORGANIC CHEMISTRY

Electrocatalytic Dihydrogen Production by an Earth-Abundant Manganese Bipyridine Catalyst

(2015) Matthew D. Sampson et al.   INORGANIC CHEMISTRY

Discovery of Dark pH-Dependent H+ Migration in a [NiFe]-Hydrogenase and Its Mechanistic Relevance: Mobilizing the Hydrido Ligand of the Ni-C Intermediate

(2015) Bonnie J. Murphy et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Proton-Coupled Electron Transfer Dynamics in the Catalytic Mechanism of a [NiFe]-Hydrogenase

(2015) Brandon L. Greene et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydrogens detected by subatomic resolution protein crystallography in a [NiFe] hydrogenase

(2015) Hideaki Ogata et al.   NATURE

Cofactor composition and function of a H2-sensing regulatory hydrogenase as revealed by Mössbauer and EPR spectroscopy

(2015) Federico Roncaroli et al.   Chemical Science

Hydrogenases

(2014) Wolfgang Lubitz et al.   CHEMICAL REVIEWS

Mimicking hydrogenases: From biomimetics to artificial enzymes

(2014) Trevor R. Simmons et al.   COORDINATION CHEMISTRY REVIEWS

[NiFe] hydrogenases: how close do structural and functional mimics approach the active site?

(2014) Sandeep Kaur-Ghumaan et al.   DALTON TRANSACTIONS

Toward the rational benchmarking of homogeneous H2-evolving catalysts

(2014) Vincent Artero et al.   Energy & Environmental Science

Hydride Binding to the Active Site of [FeFe]-Hydrogenase

(2014) Petko Chernev et al.   INORGANIC CHEMISTRY

Molecular Catalysis of H2 Evolution: Diagnosing Heterolytic versus Homolytic Pathways

(2014) Cyrille Costentin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel(II) Pincer Carbene Complexes: Oxidative Addition of an Aryl C–H Bond to Form a Ni(II) Hydride

(2014) Ellen M. Matson et al.   ORGANOMETALLICS

Transmethylation of a four-coordinate nickel(i) monocarbonyl species with methyl iodide

(2014) Changho Yoo et al.   Chemical Science

Catalytic Hydrogen Oxidation: Dawn of a New Iron Age

(2013) Trevor R. Simmons et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A modular, energy-based approach to the development of nickel containing molecular electrocatalysts for hydrogen production and oxidation

(2013) Wendy J. Shaw et al.   BIOCHIMICA ET BIOPHYSICA ACTA-BIOENERGETICS

Catalytic hydrogen production by a Ni–Ru mimic of NiFe hydrogenases involves a proton-coupled electron transfer step

(2013) Sigolène Canaguier et al.   CHEMICAL COMMUNICATIONS

Synthesis, Structural Characterization, and Electrochemical Properties of Dinuclear Ni/Mn Model Complexes for the Active Site of [NiFe]-Hydrogenases

(2013) Li-Cheng Song et al.   INORGANIC CHEMISTRY

A Metal–Metal Bond in the Light-Induced State of [NiFe] Hydrogenases with Relevance to Hydrogen Evolution

(2013) Mario Kampa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Functional [NiFe]Hydrogenase Mimic That Catalyzes Electron and Hydride Transfer from H2

(2013) S. Ogo et al.   SCIENCE

Identification and Characterization of the “Super-Reduced” State of the H-Cluster in [FeFe] Hydrogenase: A New Building Block for the Catalytic Cycle?

(2012) Agnieszka Adamska et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Biomimetic model for [FeFe]-hydrogenase: asymmetrically disubstituted diiron complex with a redox-active 2,2′-bipyridyl ligand

(2012) Souvik Roy et al.   DALTON TRANSACTIONS

Synthetic Models for the Active Site of the [FeFe]-Hydrogenase: Catalytic Proton Reduction and the Structure of the Doubly Protonated Intermediate

(2012) Maria E. Carroll et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Turnover Numbers, Turnover Frequencies, and Overpotential in Molecular Catalysis of Electrochemical Reactions. Cyclic Voltammetry and Preparative-Scale Electrolysis

(2012) Cyrille Costentin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Terminal vs Bridging Hydrides of Diiron Dithiolates: Protonation of Fe2(dithiolate)(CO)2(PMe3)4

(2012) Riccardo Zaffaroni et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis, Reactivity, and Catalytic Application of a Nickel Pincer Hydride Complex

(2012) Jan Breitenfeld et al.   ORGANOMETALLICS

A nickel–manganese catalyst as a biomimic of the active site of NiFe hydrogenases: a combined electrocatalytical and DFT mechanistic study

(2011) Vincent Fourmond et al.   Energy & Environmental Science

Influence of Mixed Thiolate/Thioether versus Dithiolate Coordination on the Accessibility of the Uncommon +I and +III Oxidation States for the Nickel Ion: An Experimental and Computational Study

(2011) Marcello Gennari et al.   INORGANIC CHEMISTRY

Combining acid–base, redox and substrate binding functionalities to give a complete model for the [FeFe]-hydrogenase

(2011) James M. Camara et al.   Nature Chemistry

A structural and functional mimic of the active site of NiFe hydrogenases

(2010) Sigolène Canaguier et al.   CHEMICAL COMMUNICATIONS

Intermediates in the Catalytic Cycle of [NiFe] Hydrogenase: Functional Spectroscopy of the Active Site

(2010) Maria-Eirini Pandelia et al.   CHEMPHYSCHEM

Cp*--Ruthenium-Nickel-Based H2-Evolving Electrocatalysts as Bio-inspired Models of NiFe Hydrogenases

(2010) Sigolène Canaguier et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Thiolate-Bridged Iron-Nickel Models for the Active Site of [NiFe] Hydrogenase

(2010) Yasuhiro Ohki et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Reversible Apical Coordination of Imidazole between the Ni(III) and Ni(II) Oxidation States of a Dithiolate Complex: A Process Related to the Ni Superoxide Dismutase

(2010) Marcello Gennari et al.   INORGANIC CHEMISTRY

Role of the Azadithiolate Cofactor in Models for [FeFe]-Hydrogenase: Novel Structures and Catalytic Implications

(2010) Matthew T. Olsen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydride-Containing Models for the Active Site of the Nickel−Iron Hydrogenases

(2010) Bryan E. Barton et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Structural and Functional Analogues of the Active Sites of the [Fe]-, [NiFe]-, and [FeFe]-Hydrogenases†

(2009) Cédric Tard et al.   CHEMICAL REVIEWS

Mechanism of hydrogen evolution catalyzed by NiFe hydrogenases: insights from a Ni–Ru model compound

(2009) Loredana Vaccaro et al.   DALTON TRANSACTIONS

Synthesis, Characterization, and Reactivity of Nickel Hydride Complexes Containing 2,6-C6H3(CH2PR2)2(R =tBu,cHex, andiPr) Pincer Ligands

(2009) Brian J. Boro et al.   INORGANIC CHEMISTRY

Nickel−Iron Dithiolato Hydrides Relevant to the [NiFe]-Hydrogenase Active Site

(2009) Bryan E. Barton et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Aza- and Oxadithiolates Are Probable Proton Relays in Functional Models for the [FeFe]-Hydrogenases

(2008) Bryan E. Barton et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY