Microporous carbon from a biological waste-stiff silkworm for capacitive energy storage

In general, carbon materials with high specific surface area (SSA), well-balanced pore size distributions, and appropriate content of heteroatom functionalities are essential to enhance the performance of electric double layer capacitors (EDLCs) for capacitive energy storage. In this study, a low-cost biological waste-stiff silkworm was first used as precursor for the synthesis of well-developed microporous carbon (SSMC) material by simple steps of carbonization and further activation. The SSMC was endowed with ultra-high SSA (2523 m(2) g(-1)), large pore volume (1.37 m(3) g(-1)), and high content of heteroatom functionalities (similar to 3.5 at% N and similar to 5.1 at% 0). EDLCs employed SSMC as active material showed high specific capacitance of 304 F g(-1) and 256 F g(-1) at current densities of 1 A g(-1) and 20 A g(-1), respectively, suggesting the good rate capability. Symmetric-two-electrode test in aqueous electrolyte also delivered the specific capacitance of 235 F g(-1) with the energy density of similar to 7.9 W h kg(-1). The findings confirmed the feasible way that using the eco-friendly biomass raw material to construct high performance capacitive energy storage device. (C) 2016 Elsevier Ltd. All rights reserved.