期刊
ELECTROCHIMICA ACTA
卷 209, 期 -, 页码 235-243出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2016.05.077
关键词
Reduced graphene oxide; Lithium titanate; Rate capacity; Lithium ion battery
资金
- Open Project of Key Lab Adv. Energy Mat. Chem. (Nankai Univ.)
Considering spinel Li4Ti5O12 (LTO) and reduced graphene oxide (rGO) both have own unique natural performance advantages separately, so we utilize a facile hydrothermal route to fabricate a composite which is synthesized by the spinel LTO grown on the rGO sheets. Electrochemical tests reflect that the small ratio of rGO (about 6.2 wt %) plays a key role in the improvement of the original morphology, structure and high rate performance. Compared with the previously published LTO/rGO composite, the newly synthesized LTO/rGO composite delivers a higher reversible special capacity of 196.4 mAh g(-1) at 1C and even exhibits good cycle stability with 98.1% retention after 100 cycles. What's more, after cycling 500 times at 20C, the discharge capacity of composite retains 154.5 mAh g(-1) (96.5% retention), whereas the bare LTO is only 69 mAh g(-1) (79.7% retention). In addition, the Li4Ti5O12/rGO composite possesses fine high rate performance with the specific discharge capacities of 175.3 mAh g(-1)(at 10C), 167 mAh g(-1) (at 15C) and 160.1 mAh g(-1)(at 20C). Such electrochemical performance is attributed to its unique structure of conductive rGO sheets with clung Li4Ti5O12 particles. (C) 2016 Elsevier Ltd. All rights reserved.
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