期刊
ELECTROCHIMICA ACTA
卷 218, 期 -, 页码 303-310出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2016.09.119
关键词
Oxygen reduction; Electrocatalysis; Carbon nanotubes; Nitrogen doping; Non-precious metal catalyst
资金
- institutional research funding of the Estonian Ministry of Education and Research [IUT20-16]
- Estonian Research Council [9323]
- Estonian Road Map Infrastructure project NAMUR
- EU through European Regional Development Fund (Advanced materials and high-technology devices for energy recuperation systems) [TK141]
Iron- and cobalt-containing nitrogen-doped carbon catalysts based on multi-walled carbon nanotubes are prepared using pyrolysis of dicyandiamide and CoCl2 or FeCl3 at 800 degrees C. The electroreduction of oxygen is studied in 0.5 M H2SO4 solution by the rotating disk electrode method and the surface morphology and composition of the catalysts are characterised by scanning and transmission electron microscopies and X-ray photoelectron spectroscopy. The as-prepared catalysts show mediocre electrocatalytic activity for oxygen reduction reaction (ORR), which increases as a result of acid treatment and second pyrolysis. The electrocatalytic activity of Fe-containing catalyst towards the ORR surpasses that of Co-based material and it supports a 4-electron reduction of O-2. Co-containing catalyst, in turn, shows higher stability. Both catalysts are highly methanol tolerant in acid media. The transition metal-containing N-doped carbon materials are promising cathode catalysts for low-temperature fuel cells. (C) 2016 Elsevier Ltd. All rights reserved.
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