Article
Chemistry, Analytical
Jeewon Park, Wansu Jang, Changhwan Shin
Summary: A gate-stack engineering technique was proposed to enhance the performance of a 28 nm low-power high-k/metal-gate device. By using HfSiO thin films instead of HfSiON, the device performance was improved with suppressed gate leakage current. The new device showed reduced thickness of the electrical oxide layer and reliable performance enhancement.
Article
Engineering, Electrical & Electronic
Gaspard Hiblot, Narendra Parihar, Emmanuel Dupuy, Geert Mannaert, Sylvain Baudot, Ben Kaczer, Jacopo Franco, Anne Vandooren, Vincent De Heyn, Abdelkarim Mercha
Summary: This study investigates charging damage induced by gate antennae in high-kappa Replacement Metal Gate technology, comparing plate and comb layouts for HK-first and HK-last integration flows. Results show significant degradation in Gate Induced Drain Leakage for both types of antennae in HK-first devices, while the degradation of HK-last transistors is mainly attributed to top oxide deposition. Differences in degradation patterns are correlated with the aspect ratio of the antenna and are explained based on plasma characteristics.
IEEE TRANSACTIONS ON DEVICE AND MATERIALS RELIABILITY
(2021)
Article
Physics, Applied
Shota Nunomura, Hiroyuki Ota, Toshifumi Irisawa, Kazuhiko Endo, Yukinori Morita
Summary: The defect generation and recovery in a high-k HfO2/SiO2/Si stack for MOSFETs were studied at each fabrication step. The measurements of carrier lifetime indicated that defects were generated during the formation of the HfO2/SiO2 stack, as well as post-deposition annealing (PDA) and O-2 plasma treatment, while they were mostly recovered by forming gas annealing (FGA).
APPLIED PHYSICS EXPRESS
(2023)
Article
Chemistry, Multidisciplinary
Kibret A. Messalea, Nitu Syed, Ali Zavabeti, Md Mohiuddin, Azmira Jannat, Patjaree Aukarasereenont, Chung K. Nguyen, Mei Xian Low, Sumeet Walia, Benedikt Haas, Christoph T. Koch, Nasir Mahmood, Khashayar Khoshmanesh, Kourosh Kalantar-Zadeh, Torben Daeneke
Summary: A stoichiometric cubic polymorph of 2D antimony oxide (Sb2O3) was synthesized as an ideal high-k dielectric sheet using a low-temperature, substrate-independent, silicon-industry-compatible liquid metal synthesis technique. The obtained alpha-Sb2O3 exhibited high crystallinity, wide band gap of approximately 4.4 eV, and a maximum relative permittivity of 84 with a breakdown electric field of around 10 MV/cm. The isolated 2D alpha-Sb2O3 nanosheets showed promise as gate oxides for conventional and van der Waals heterostructure-based electronics due to low leakage currents in top-gated field-effect transistors.
Article
Chemistry, Physical
Asharani Samal, Kumar Prasannajit Pradhan, Sushanta Kumar Mohapatra
Summary: This paper extensively studies the spacer technology, including low-k/high-k, single/dual dielectrics on the device performances focusing on the leakage current. The strategic use of a spacer, the introduction of a low bandgap material as a pocket on the source side along with the incorporation of gate dielectrics helped to improve the switching ratio effectively. Various device architectures are evaluated showing significant improvements in on current (I-on) and off state leakage (I-off).
Article
Engineering, Electrical & Electronic
Jiafei Yao, Zhenyu Zhang, Yufeng Guo, Jiayi Wu, Yongchen He, Man Li, Hong Lin
Summary: This article introduces a novel lateral double-diffused metal oxide semiconductor (LDMOS) with integrated triple direction high-k gate and field dielectrics (HKGF LDMOS). The new structure helps to reduce ON-resistance, threshold voltage, and increase transconductance and breakdown voltage compared to conventional LDMOS.
IEEE TRANSACTIONS ON ELECTRON DEVICES
(2021)
Article
Chemistry, Physical
Jun -Dar Hwang, Cyuan-Sin Li, Chin -Yang Chang
Summary: With the development of MIS field-effect transistors, the use of MgO/SiOx stack dielectrics can effectively suppress the gate leakage current and improve the performance of MIS diodes. The stack reduces the oxygen vacancy of MgO, decreases the fixed oxide charge and interface trap charge density, and enhances the rectification ratio. The barrier height also increases in the stack, allowing for Fowler-Nordheim tunneling at high reverse-bias voltage and direct tunneling at low reverse-bias voltages.
JOURNAL OF ALLOYS AND COMPOUNDS
(2023)
Article
Nanoscience & Nanotechnology
Heesoo Lee, Hoijoon Kim, Kihyun Kim, Kwangsik Jeong, Mirine Leem, Seunghyun Park, Jieun Kang, Geunyoung Yeom, Hyoungsub Kim
Summary: This study developed a three-dimensional and damage-free surface treatment method for two-dimensional transition metal dichalcogenide semiconductors, and successfully achieved uniform atomic layer-deposition of a high-k dielectric film. The results demonstrate the potential application of this method in realizing next-generation gate-all-around field-effect transistors.
ACS APPLIED MATERIALS & INTERFACES
(2023)
Article
Chemistry, Multidisciplinary
Jehyun An, Kyeongkeun Choi, Jongseo Park, Bohyeon Kang, Hyunseo You, Sungmin Ahn, Rockhyun Baek
Summary: The electrical properties of Al2O3 film were optimized to enhance the passivation layer of CMOS image sensors (CISs). Adjusting the O-2 plasma exposure time and performing H-2 plasma treatment and post-metallization annealing (PMA) were key steps. Shorter O-2 plasma exposure time caused significant shifts in flat-band voltage (V-fb), while longer exposure time reduced carbon impurity content. Increasing the O-2 plasma exposure time and applying PMA reduced the number of interface traps (D-it). Ultimately, the Al2O3 film with reduced interface traps was fabricated, but the film deteriorated with increased O-2 plasma exposure time due to plasma damage after H-2 plasma treatment.
Article
Materials Science, Multidisciplinary
Zhenchuan Lu, Kamale Tuokedaerhan, Haotian Cai, Hongguo Du, Renjia Zhang
Summary: This article introduces the sol-gel method for depositing La2O3 thin films on n-type Si substrates and quartz substrates, with a focus on the impact of annealing temperature on the microcomposition, surface morphology, optical properties, and band characteristics of the films. The results show that annealing leads to the formation of a hexagonal-phase La2O3 and new impurities. The La2O3 film exhibits a smooth, uniform surface without cracks, and its transmittance is above 75%. The calculated band offset of the La2O3 film meets the minimum requirements for MOS devices, indicating its promising prospects in MOS applications.
Article
Materials Science, Multidisciplinary
Chih-Yen Lee, Chi-Yang Yan, Yi-Lung Cheng
Summary: This study proposed a novel process for repairing plasma-induced damage and capping a barrier for porous low-k materials using HDMS plasma treatment, which can significantly enhance the performance and reliability of porous low-k materials.
Article
Chemistry, Physical
Y. X. Ma, X. D. Huang, P. T. Lai, W. M. Tang
Summary: This study investigates the application of Nd oxynitrides and Ta-doped Nd oxynitrides as gate dielectrics in organic thin-film transistors. The results show that Ta doping can improve the performance of the transistors, including high carrier mobility and small threshold voltage, and enhance the smoothness and moisture resistance of the dielectric surface.
APPLIED SURFACE SCIENCE
(2022)
Article
Chemistry, Multidisciplinary
Qiuju Wu, Qing Yu, Gang He, Wenhao Wang, Jinyu Lu, Bo Yao, Shiyan Liu, Zebo Fang
Summary: This paper investigates the impact of atomic layer deposition (ALD)-derived Al2O3 passivation layers and annealing temperatures on the interfacial chemistry and transport properties of sputtering-deposited Er2O3 high-k gate dielectrics on Si substrate. X-ray photoelectron spectroscopy (XPS) analyses reveal that the ALD-derived Al2O3 passivation layer effectively prevents the formation of low-k hydroxides and optimizes the gate dielectric properties. Electrical performance measurements demonstrate that the Al2O3/Er2O3/Si MOS capacitor achieves the lowest leakage current density of 4.57 x 10(-9) A/cm(2) and the smallest interfacial density of states (Dit) of 2.38 x 10(12) cm(-2) eV(-1) due to the optimized interface chemistry. Furthermore, annealing the Al2O3/Er2O3/Si gate stacks at 450 degrees C improves the dielectric properties with a leakage current density of 1.38 x 10(-9) A/cm(2), and different conduction mechanisms of MOS devices under various stack structures are investigated systematically.
Article
Polymer Science
Ching-Lin Fan, Hou-Yen Tsao, Yu-Shien Shiah, Che-Wei Yao, Po-Wei Cheng
Summary: This study proposed using a high-K PVA/low-K PVP bilayer structure as the gate insulator to enhance a pentacene-based organic thin-film transistor. The bilayer gate dielectric with a dielectric constant of 5.6 resulted in increased gate capacitance and drain current. The device performances were significantly improved, with the field-effect mobility increasing from 0.16 to 1.12 cm(2)/(Vs), 7 times higher than that of the control sample.
Article
Materials Science, Ceramics
Jaemin Kim, Jinsu Park, Duy Phong Pham, Myung Soo Yeo, HwaSung Rhee, Youg-Sang Kim, Eun-Chel Cho, Junsin Yi
Summary: The characteristics of HfO2 thin films with and without UV exposure post-treatment were discussed in this study. The results showed that the post-treated HfO2 films had higher crystallinity, lower suboxide bond proportion, higher dielectric constant, and improved device capacitance compared to the untreated films. The proposed post-treatment process has the significant potential in enhancing the quality of HfO2 thin films for semiconductor devices.
CERAMICS INTERNATIONAL
(2021)
Article
Engineering, Electrical & Electronic
Hsin-Kai Fang, Kuei-Shu Chang-Liao, Chia-Hsin Cheng, Yu-Chin Lu, Wen-Hsien Huang, Chang-Hong Shen, Jia-Min Shieh
IEEE TRANSACTIONS ON ELECTRON DEVICES
(2020)
Article
Engineering, Electrical & Electronic
Hsin-Kai Fang, Kuei-Shu Chang-Liao, Kuan-Chi Chou, Tzu-Cheng Chao, Jung-En Tsai, Yan-Lin Li, Wen-Hsien Huang, Chang-Hong Shen, Jia-Min Shieh
IEEE ELECTRON DEVICE LETTERS
(2020)