Tuning the redox properties of the titanocene(iii)/(iv)-couple for atom-economical catalysis in single electron steps

Cationic Titanocene(III) Complexes for Catalysis in Single-Electron Steps

(2015) Andreas Gansäuer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Proton-Coupled Electron Transfer in the Reduction of Arenes by SmI2–Water Complexes

(2015) Tesia V. Chciuk et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cross-Coupling Reactions Using Samarium(II) Iodide

(2014) Michal Szostak et al.   CHEMICAL REVIEWS

Mechanistic Study of the Titanocene(III)-Catalyzed Radical Arylation of Epoxides

(2014) Andreas Gansäuer et al.   CHEMISTRY-A EUROPEAN JOURNAL

Mechanism of SmI2/Amine/H2O-Promoted Chemoselective Reductions of Carboxylic Acid Derivatives (Esters, Acids, and Amides) to Alcohols

(2014) Michal Szostak et al.   JOURNAL OF ORGANIC CHEMISTRY

Ketyl-Type Radicals from Cyclic and Acyclic Esters are Stabilized by SmI2(H2O)n: The Role of SmI2(H2O)n in Post-Electron Transfer Steps

(2014) Michal Szostak et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Substituent Effects and Supramolecular Interactions of Titanocene(III) Chloride: Implications for Catalysis in Single Electron Steps

(2014) Andreas Gansäuer et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Convenient Titanium(III)-Catalyzed Synthesis of Cyclic Aminoketones and Pyrrolidinones-Development of a Formal [4+1] Cycloaddition

(2013) Georg Frey et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The cross-selective titanium(iii)-catalysed acyloin reaction

(2013) Markus Feurer et al.   CHEMICAL COMMUNICATIONS

Recent advances in the chemoselective reduction of functional groups mediated by samarium(ii) iodide: a single electron transfer approach

(2013) Michal Szostak et al.   CHEMICAL SOCIETY REVIEWS

Carbene Radicals in Cobalt(II)-Porphyrin-Catalysed Carbene Carbonylation Reactions; A Catalytic Approach to Ketenes

(2013) Nanda D. Paul et al.   CHEMISTRY-A EUROPEAN JOURNAL

Metalloradical Approach to 2H-Chromenes

(2013) Nanda D. Paul et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Titanium(III)-Catalyzed Reductive Cyclization of Ketonitriles

(2012) Jan Streuff et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Hydrogen Atom Transfer (HAT) for Sustainable and Diastereoselective Radical Reduction

(2012) Andreas Gansäuer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic, Atom-Economical Radical Arylation of Epoxides

(2012) Andreas Gansäuer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Combining the Power of TiIII-Mediated Processes for Easy Access to Hydroxylated Polycyclic Terpenoids: Synthesis of Sesterstatin 1 and C-D Rings of Aspergilloxide

(2012) Tania Jiménez et al.   CHEMISTRY-A EUROPEAN JOURNAL

Radical 4-exo Cyclizations via Template Catalysis

(2012) Andreas Gansäuer et al.   CHEMISTRY-A EUROPEAN JOURNAL

Bioinspired terpene synthesis: a radical approach

(2011) José Justicia et al.   CHEMICAL SOCIETY REVIEWS

The radical mechanism of cobalt(ii) porphyrin-catalyzed olefin aziridination and the importance of cooperative H-bonding

(2011) Alma I. Olivos Suarez et al.   DALTON TRANSACTIONS

Mechanism of Cobalt(II) Porphyrin-Catalyzed C–H Amination with Organic Azides: Radical Nature and H-Atom Abstraction Ability of the Key Cobalt(III)–Nitrene Intermediates

(2011) Volodymyr Lyaskovskyy et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Experimental Evidence for Cobalt(III)-Carbene Radicals: Key Intermediates in Cobalt(II)-Based Metalloradical Cyclopropanation

(2011) Hongjian Lu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Uncovering the Mechanistic Role of HMPA in the Samarium Barbier Reaction

(2010) Kimberly A. Choquette et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

‘Carbene Radicals’ in CoII(por)-Catalyzed Olefin Cyclopropanation

(2010) Wojciech I. Dzik et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Enantioselective Radical Cyclization via Regiodivergent Epoxide Opening

(2010) Andreas Gansäuer et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

4-exoCyclizations by Template Catalysis

(2009) Andreas Gansäuer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalysis via Homolytic Substitutions with C−O and Ti−O Bonds: Oxidative Additions and Reductive Eliminations in Single Electron Steps

(2009) Andreas Gansäuer et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cobalt(II)-Catalyzed Intermolecular Benzylic C−H Amination with 2,2,2-Trichloroethoxycarbonyl Azide (TrocN3)

(2009) Hongjian Lu et al.   ORGANOMETALLICS

Mechanistic Study of Samarium Diiodide-HMPA Initiated 5-exo-trigKetyl−Olefin Coupling: The Role of HMPA in Post-Electron Transfer Steps

(2008) Dhandapani V. Sadasivam et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Titanocene Catalyzed 4-exoCyclizations:  Mechanism, Experiment, Catalyst Design

(2008) Joachim Friedrich et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

On the Role of Samarium/HMPA in the Post Electron-Transfer Steps in SmI2Reductions

(2008) Hani Farran et al.   ORGANIC LETTERS