期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 21, 期 1, 页码 280-289出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201404404
关键词
arylation; cyclic voltammetry; DFT; epoxides; radicals; titanium
资金
- Chemistry at Spin Centers [SFB 813]
- Jurgen Manchot Stiftung
- Studienstiftung des Deutschen Volkes
- Hans-Bockler-Stiftung
- US National Science Foundation [CHE-1123815]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1123815] Funding Source: National Science Foundation
An atom-economical and catalytic arylation of epoxide-derived radicals is described. The key step of the catalytic system is a sequential electron and proton transfer for the rearomatization of the radical sigma-complex and catalyst regeneration. Kinetic, computational, spectroscopic, and cyclovoltammetric investigations highlight the key issues of the reaction mechanism and catalyst stabilization by collidine hydrochloride. Studies employing radicophiles rule out the participation of cations as reactive intermediates.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据