Pincer‐Type Ligand‐Assisted Catalysis and Small‐Molecule Activation by non‐VSEPR Main‐Group Compounds

Synthesis and Reactivity of Cationic Boron Complexes Distorted by Pyridine-based Pincer Ligands: Isolation of a Photochemical Hofmann-Martius-type Intermediate

(2020) Trevor Janes et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Fluorination of arylboronic esters enabled by bismuth redox catalysis

(2020) Oriol Planas et al.   SCIENCE

An Improved PIII/PV═O-Catalyzed Reductive C–N Coupling of Nitroaromatics and Boronic Acids by Mechanistic Differentiation of Rate- and Product-Determining Steps

(2020) Gen Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Bismuth-Catalyzed Oxidative Coupling of Arylboronic Acids with Triflate and Nonaflate Salts

(2020) Oriol Planas et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis, Characterization, and Reactivity of a Pincer-Type Aluminum(III) Complex

(2020) Penglong Wang et al.   ORGANOMETALLICS

Organophosphorus-Catalyzed Deoxygenation of Sulfonyl Chlorides: Electrophilic (Fluoroalkyl)sulfenylation by PIII/PV=O Redox Cycling

(2019) Avipsa Ghosh et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The reductive coupling of dinitrogen

(2019) Marc-André Légaré et al.   SCIENCE

Bi(I)-Catalyzed Transfer-Hydrogenation with Ammonia-Borane

(2019) Feng Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Heterodiatomic Multiple Bonding in Group 13: A Complex with a B-Al π Bond Reduces CO2

(2019) Alexander Hofmann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Redox-Confused Bismuth(I/III) Triamide with a T-Shaped Planar Ground State

(2019) Marcus B. Kindervater et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

CO2 Fixation and Catalytic Reduction by a Neutral Aluminium Double bond

(2019) Shigeyoshi Inoue et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Reversible C=C Bond Activation by an Intramolecularly Coordinated Antimony(I) Compound.

(2019) Monika Kořenková et al.   CHEMISTRY-A EUROPEAN JOURNAL

Phosphetane Oxides as Redox Cycling Catalysts in the Catalytic Wittig Reaction at Room Temperature

(2019) Lars Longwitz et al.   ACS Catalysis

Tricoordinate Nontrigonal Pnictogen-Centered Radical Anions: Isolation, Characterization, and Reactivity

(2019) Manas Kumar Mondal et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Pushing the Lewis Acidity Boundaries of Boron Compounds With Non-Planar Triarylboranes Derived from Triptycenes

(2019) Ali Ben Saida et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Aluminium-Mediated Carbon Dioxide Reduction by an Isolated Monoalumoxane Anion

(2019) Mathew D. Anker et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Periodicity in Structure, Bonding, and Reactivity for p‐Block Complexes of a Geometry Constraining Triamide Ligand

(2019) Katherine M. Marczenko et al.   CHEMISTRY-A EUROPEAN JOURNAL

PIII /PV =O Catalyzed Cascade Synthesis of N-Functionalized Azaheterocycles

(2019) Trevor V. Nykaza et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ambiphilic geometrically constrained phosphenium cation

(2018) Solomon Volodarsky et al.   CHEMICAL COMMUNICATIONS

NHCs in Main Group Chemistry

(2018) Vitaly Nesterov et al.   CHEMICAL REVIEWS

Oxidative Addition and Reductive Elimination at Main-Group Element Centers

(2018) Terry Chu et al.   CHEMICAL REVIEWS

Key factors in pincer ligand design

(2018) Eduardo Peris et al.   CHEMICAL SOCIETY REVIEWS

Catalytic Hydrodefluorination of C−F Bonds by an Air-Stable PIII Lewis Acid

(2018) Saurabh S. Chitnis et al.   CHEMISTRY-A EUROPEAN JOURNAL

Nitrogen fixation and reduction at boron

(2018) Marc-André Légaré et al.   SCIENCE

Sterically Constrained Bicyclic Phosphines: A Class of Fascinating Compounds Suitable for Application in Small Molecule Activation and Coordination Chemistry

(2018) Werner Uhl et al.   CHEMISTRY-A EUROPEAN JOURNAL

Intermolecular Reductive C–N Cross Coupling of Nitroarenes and Boronic Acids by PIII/PV═O Catalysis

(2018) Trevor V. Nykaza et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Phosphorus Coordination Chemistry in Catalysis: Air Stable P(III)-Dications as Lewis Acid Catalysts for the Allylation of C–F Bonds

(2018) Saurabh S. Chitnis et al.   ORGANOMETALLICS

P–N Cooperative Borane Activation and Catalytic Hydroboration by a Distorted Phosphorous Triamide Platform

(2017) Yi-Chun Lin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Biphilic Phosphetane Catalyzes N–N Bond-Forming Cadogan Heterocyclization via PIII/PV═O Redox Cycling

(2017) Trevor V. Nykaza et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Phosphorus Lewis acids: emerging reactivity and applications in catalysis

(2016) J. M. Bayne et al.   CHEMICAL SOCIETY REVIEWS

On the Ambiphilic Reactivity of Geometrically Constrained Phosphorus(III) and Arsenic(III) Compounds: Insights into Their Interaction with Ionic Substrates

(2016) Thomas P. Robinson et al.   CHEMISTRY-A EUROPEAN JOURNAL

Exploration of Earth-Abundant Transition Metals (Fe, Co, and Ni) as Catalysts in Unreactive Chemical Bond Activations

(2015) Bo Su et al.   ACCOUNTS OF CHEMICAL RESEARCH

E-H Bond Activation of Ammonia and Water by a Geometrically Constrained Phosphorus(III) Compound

(2015) Thomas P. Robinson et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Compounds with Low-Valent p-Block Elements for Small Molecule Activation and Catalysis

(2015) Sandeep Yadav et al.   ChemCatChem

From Dibismuthenes to Three- and Two-Coordinated Bismuthinidenes by Fine Ligand Tuning: Evidence for Aromatic BiC3N Rings through a Combined Experimental and Theoretical Study

(2015) Iva Vránová et al.   CHEMISTRY-A EUROPEAN JOURNAL

Small Molecule Activation by Constrained Phosphorus Compounds: Insights from Theory

(2015) Amrita Pal et al.   INORGANIC CHEMISTRY

Biphilic Organophosphorus Catalysis: Regioselective Reductive Transposition of Allylic Bromides via PIII/PV Redox Cycling

(2015) Kyle D. Reichl et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Phosphetane Catalyzes Deoxygenative Condensation of α-Keto Esters and Carboxylic Acids via PIII/PV═O Redox Cycling

(2015) Wei Zhao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Frustrated Lewis Pairs: From Concept to Catalysis

(2014) Douglas W. Stephan   ACCOUNTS OF CHEMICAL RESEARCH

Catalytic Transfer Hydrogenation by a Trivalent Phosphorus Compound: Phosphorus-Ligand Cooperation Pathway or PIII/PVRedox Pathway?

(2014) Guixiang Zeng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Reversible Intermolecular E–H Oxidative Addition to a Geometrically Deformed and Structurally Dynamic Phosphorous Triamide

(2014) Wei Zhao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metal-Free σ-Bond Metathesis in Ammonia Activation by a Diazadiphosphapentalene

(2014) Jingjing Cui et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Intermolecular N–H Oxidative Addition of Ammonia, Alkylamines, and Arylamines to a Planar σ3-Phosphorus Compound via an Entropy-Controlled Electrophilic Mechanism

(2014) Sean M. McCarthy et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Lewis acidity of boron compounds

(2013) Igor B. Sivaev et al.   COORDINATION CHEMISTRY REVIEWS

Synthesis and Characterization of N-[2-P(i-Pr)2-4-methylphenyl]2– (PNP) Pincer Tin(IV) and Tin(II) Complexes

(2012) Jens Henning et al.   INORGANIC CHEMISTRY

Main Group Redox Catalysis: Reversible PIII/PV Redox Cycling at a Phosphorus Platform

(2012) Nicole L. Dunn et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Appel reactions

(2012) Henri A. van Kalkeren et al.   PURE AND APPLIED CHEMISTRY

Preparation of RSn(I)–Sn(I)R with Two Unsymmetrically Coordinated Sn(I) Atoms and Subsequent Gentle Activation of P4

(2011) Shabana Khan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Monomeric Organoantimony(I) and Organobismuth(I) Compounds Stabilized by an NCN Chelating Ligand: Syntheses and Structures

(2010) Petr Šimon et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Main-group elements as transition metals

(2010) Philip P. Power   NATURE

H2Activation by a (PNP)Ir(C6H5) Complex via the Dearomatization/Aromatization Process of the PNP Ligand: A Computational Study

(2009) Guixiang Zeng et al.   INORGANIC CHEMISTRY

Fifty years of the VSEPR model

(2007) R.J. Gillespie   COORDINATION CHEMISTRY REVIEWS