The Stabilization Effect of π-Backdonation Ligands on the Catalytic Reactivities of Amido-Ene(amido) Iron Catalysts in the Asymmetric Transfer Hydrogenation of Ketones

Asymmetric Transfer Hydrogenation with a Bifunctional Iron(II) Hydride: Experiment Meets Computation

(2019) Lorena De Luca et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

From Ruthenium to Iron and Manganese-A Mechanistic View on Challenges and Design Principles of Base-Metal Hydrogenation Catalysts

(2018) Thomas Zell et al.   ChemCatChem

Catalytic (de)hydrogenation promoted by non-precious metals – Co, Fe and Mn: recent advances in an emerging field

(2018) Georgy A. Filonenko et al.   CHEMICAL SOCIETY REVIEWS

Base-free Asymmetric Transfer Hydrogenation of 1,2-Di- and Monoketones Catalyzed by a Chiral Iron(II) Hydride

(2018) Lorena De Luca et al.   CHIMIA

Iron Catalysis in Reduction and Hydrometalation Reactions

(2018) Duo Wei et al.   CHEMICAL REVIEWS

Asymmetric Transfer Hydrogenation of Ketones with Well-Defined Manganese(I) PNN and PNNP Complexes

(2018) Karl Z. Demmans et al.   ORGANOMETALLICS

Asymmetric Transfer Hydrogenation of Ketones Using New Iron(II) (P-NH-N-P′) Catalysts: Changing the Steric and Electronic Properties at Phosphorus P′

(2017) Samantha A. M. Smith et al.   ISRAEL JOURNAL OF CHEMISTRY

From imine to amine: an unexpected left turn. Cis-β iron(ii) PNNP′ precatalysts for the asymmetric transfer hydrogenation of acetophenone

(2017) Karl Z. Demmans et al.   Chemical Science

Selective Hydrogenation of Nitriles to Secondary Imines Catalyzed by an Iron Pincer Complex

(2017) Subrata Chakraborty et al.   ACS Catalysis

PNP-Pincer-Type Phosphaalkene Complexes of Late Transition Metals

(2016) Fumiyuki Ozawa et al.   CHEMICAL RECORD

The mechanism of enantioselective ketone reduction with Noyori and Noyori–Ikariya bifunctional catalysts

(2016) Pavel A. Dub et al.   DALTON TRANSACTIONS

Electronic Structures of the [Fe(N2)(SiPiPr3)]+1/0/–1 Electron Transfer Series: A Counterintuitive Correlation between Isomer Shifts and Oxidation States

(2016) Shengfa Ye et al.   INORGANIC CHEMISTRY

Selective Hydrogenation of Amides to Amines and Alcohols Catalyzed by Improved Iron Pincer Complexes

(2016) Felix Schneck et al.   ORGANOMETALLICS

Iron(II)/(NH)2P2 Macrocycles: Modular, Highly Enantioselective Transfer Hydrogenation Catalysts

(2016) Raphael Bigler et al.   ACS Catalysis

Hydrogenation and Dehydrogenation Iron Pincer Catalysts Capable of Metal–Ligand Cooperation by Aromatization/Dearomatization

(2015) Thomas Zell et al.   ACCOUNTS OF CHEMICAL RESEARCH

Highly Enantioselective Transfer Hydrogenation of Ketones with Chiral (NH)2P2Macrocyclic Iron(II) Complexes

(2015) Raphael Bigler et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

How Innocent are Potentially Redox Non-Innocent Ligands? Electronic Structure and Metal Oxidation States in Iron-PNN Complexes as a Representative Case Study

(2015) Burkhard Butschke et al.   INORGANIC CHEMISTRY

Osmium(II)–Bis(dihydrogen) Complexes Containing Caryl,CNHC–Chelate Ligands: Preparation, Bonding Situation, and Acidity

(2015) Tamara Bolaño et al.   ORGANOMETALLICS

Chemoselective Hydrogenation and Transfer Hydrogenation of Aldehydes Catalyzed by Iron(II) PONOP Pincer Complexes

(2015) Simona Mazza et al.   ORGANOMETALLICS

Details of the Mechanism of the Asymmetric Transfer Hydrogenation of Acetophenone Using the Amine(imine)diphosphine Iron Precatalyst: The Base Effect and The Enantiodetermining Step

(2015) Weiwei Zuo et al.   ACS Catalysis

Iron-Based Catalysts for the Hydrogenation of Esters to Alcohols

(2014) Sumit Chakraborty et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron Catalyzed Asymmetric Hydrogenation of Ketones

(2014) Yanyun Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Lewis Acid-Assisted Formic Acid Dehydrogenation Using a Pincer-Supported Iron Catalyst

(2014) Elizabeth A. Bielinski et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Estimating the Acidity of Transition Metal Hydride and Dihydrogen Complexes by Adding Ligand Acidity Constants

(2014) Robert H. Morris   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Efficient Hydrogenation of Ketones and Aldehydes Catalyzed by Well-Defined Iron(II) PNP Pincer Complexes: Evidence for an Insertion Mechanism

(2014) Nikolaus Gorgas et al.   ORGANOMETALLICS

Abundant Metals Give Precious Hydrogenation Performance

(2013) R. M. Bullock   SCIENCE

Amine(imine)diphosphine Iron Catalysts for Asymmetric Transfer Hydrogenation of Ketones and Imines

(2013) W. Zuo et al.   SCIENCE

Iron-Catalyzed Highly Enantioselective Reduction of Aromatic Ketones with Chiral P2N4-Type Macrocycles

(2012) Shenluan Yu et al.   ADVANCED SYNTHESIS & CATALYSIS

Iron Borohydride Pincer Complexes for the Efficient Hydrogenation of Ketones under Mild, Base-Free Conditions: Synthesis and Mechanistic Insight

(2012) Robert Langer et al.   CHEMISTRY-A EUROPEAN JOURNAL

EPR, Resonance Raman, and DFT Calculations on Thiolate- and Imidazole-Bound Iron(III) Porphyrin Complexes: Role of the Axial Ligand in Tuning the Electronic Structure

(2012) Pradip Kumar Das et al.   INORGANIC CHEMISTRY

The Mechanism of Efficient Asymmetric Transfer Hydrogenation of Acetophenone Using an Iron(II) Complex Containing an (S,S)-Ph2PCH2CH═NCHPhCHPhN═CHCH2PPh2 Ligand: Partial Ligand Reduction Is the Key

(2012) Alexandre A. Mikhailine et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Oxidative Addition of Carbon–Carbon Bonds with a Redox-Active Bis(imino)pyridine Iron Complex

(2012) Jonathan M. Darmon et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Inner-Sphere Activation, Outer-Sphere Catalysis: Theoretical Study on the Mechanism of Transfer Hydrogenation of Ketones Using Iron(II) PNNP Eneamido Complexes

(2012) Demyan E. Prokopchuk et al.   ORGANOMETALLICS

Developing Synthetic Approaches with Non-Innocent Metalloligands: Easy Access to IrI/Pd0 and IrI/Pd0/IrI Cores

(2011) Cristina Tejel et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Efficient Hydrogenation of Ketones Catalyzed by an Iron Pincer Complex

(2011) Robert Langer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Harnessing Redox-Active Ligands for Low-Barrier Radical Addition at Oxorhenium Complexes

(2011) Cameron A. Lippert et al.   INORGANIC CHEMISTRY

Density Functional Theory Calculations on the Mononuclear Non-Heme Iron Active Site of Hmd Hydrogenase: Role of the Internal Ligands in Tuning External Ligand Binding and Driving H2Heterolysis

(2010) Abhishek Dey   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The Unusual Electronic Structure of Dinitrosyl Iron Complexes

(2010) Shengfa Ye et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Radical Ligands Confer Nobility on Base-Metal Catalysts

(2010) P. J. Chirik et al.   SCIENCE

Deprotonation Induced Ligand-to-Metal Electron Transfer: Synthesis of a Mixed-Valence Rh(−I,I) Dinuclear Compound and Its Reaction with Dioxygen

(2008) Cristina Tejel et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Efficient Catalyst Systems Using Iron Complexes with a Tetradentate PNNP Ligand for the Asymmetric Hydrogenation of Polar Bonds

(2007) Christine Sui-Seng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION