From Ruthenium to Iron and Manganese-A Mechanistic View on Challenges and Design Principles of Base-Metal Hydrogenation Catalysts

Mono- N -methylation of anilines with methanol catalyzed by a manganese pincer-complex

(2017) Antoine Bruneau-Voisine et al.   JOURNAL OF CATALYSIS

Manganese-Catalyzed Aminomethylation of Aromatic Compounds with Methanol as a Sustainable C1 Building Block

(2017) Matthias Mastalir et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Transfer Hydrogenation of Carbonyl Derivatives Catalyzed by an Inexpensive Phosphine-Free Manganese Precatalyst

(2017) Antoine Bruneau-Voisine et al.   ORGANIC LETTERS

Selective Iron-Catalyzed Deaminative Hydrogenation of Amides

(2017) Upul Jayarathne et al.   ORGANOMETALLICS

Bio-Inspired Mn(I) Complexes for the Hydrogenation of CO2 to Formate and Formamide

(2017) Abhishek Dubey et al.   ACS Catalysis

Metal–Ligand Bifunctional Catalysis: The “Accepted” Mechanism, the Issue of Concertedness, and the Function of the Ligand in Catalytic Cycles Involving Hydrogen Atoms

(2017) Pavel A. Dub et al.   ACS Catalysis

Hydrogenation of Esters to Alcohols Catalyzed by Defined Manganese Pincer Complexes

(2016) Saravanakumar Elangovan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Unprecedented iron-catalyzed selective hydrogenation of activated amides to amines and alcohols

(2016) Jai Anand Garg et al.   CHEMICAL COMMUNICATIONS

Thermodynamic Hydricity of Transition Metal Hydrides

(2016) Eric S. Wiedner et al.   CHEMICAL REVIEWS

Sustainable Synthesis of Quinolines and Pyrimidines Catalyzed by Manganese PNP Pincer Complexes

(2016) Matthias Mastalir et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron-catalysed tritiation of pharmaceuticals

(2016) Renyuan Pony Yu et al.   NATURE

Selective Hydrogenation of Amides to Amines and Alcohols Catalyzed by Improved Iron Pincer Complexes

(2016) Felix Schneck et al.   ORGANOMETALLICS

Recent Advances in Iron- and Cobalt-Complex-Catalyzed Tandem/Consecutive Processes Involving Hydrogenation

(2016) Jean-Luc Renaud et al.   SYNTHESIS-STUTTGART

Iron-Catalyzed Homogeneous Hydrogenation of Alkenes under Mild Conditions by a Stepwise, Bifunctional Mechanism

(2016) Ruibo Xu et al.   ACS Catalysis

Iron-Catalyzed Hydrogenation of Amides to Alcohols and Amines

(2016) Nomaan M. Rezayee et al.   ACS Catalysis

Distinctive Reaction Pathways at Base Metals in High-Spin Organometallic Catalysts

(2015) Patrick L. Holland   ACCOUNTS OF CHEMICAL RESEARCH

Iron-, Cobalt-, and Nickel-Catalyzed Asymmetric Transfer Hydrogenation and Asymmetric Hydrogenation of Ketones

(2015) Yan-Yun Li et al.   ACCOUNTS OF CHEMICAL RESEARCH

Exploiting Metal–Ligand Bifunctional Reactions in the Design of Iron Asymmetric Hydrogenation Catalysts

(2015) Robert H. Morris   ACCOUNTS OF CHEMICAL RESEARCH

Iron- and Cobalt-Catalyzed Alkene Hydrogenation: Catalysis with Both Redox-Active and Strong Field Ligands

(2015) Paul J. Chirik   ACCOUNTS OF CHEMICAL RESEARCH

Hydrogenation and Dehydrogenation Iron Pincer Catalysts Capable of Metal–Ligand Cooperation by Aromatization/Dearomatization

(2015) Thomas Zell et al.   ACCOUNTS OF CHEMICAL RESEARCH

Iron Catalysis in Organic Synthesis

(2015) Ingmar Bauer et al.   CHEMICAL REVIEWS

CO2 Hydrogenation to Formate and Methanol as an Alternative to Photo- and Electrochemical CO2 Reduction

(2015) Wan-Hui Wang et al.   CHEMICAL REVIEWS

Iron-catalyzed olefin hydrogenation at 1 bar H2 with a FeCl3–LiAlH4 catalyst

(2015) Tim N. Gieshoff et al.   GREEN CHEMISTRY

When iron met phosphines: a happy marriage for reduction catalysis

(2015) Luis C. Misal Castro et al.   GREEN CHEMISTRY

Highly efficient, general hydrogenation of aldehydes catalyzed by PNP iron pincer complexes

(2015) Thomas Zell et al.   Catalysis Science & Technology

Iron Cyclopentadienone Complexes: Discovery, Properties, and Catalytic Reactivity

(2014) Adrien Quintard et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Unprecedented Iron-Catalyzed Ester Hydrogenation. Mild, Selective, and Efficient Hydrogenation of Trifluoroacetic Esters to Alcohols Catalyzed by an Iron Pincer Complex

(2014) Thomas Zell et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Hydrogenation of Esters to Alcohols with a Well-Defined Iron Complex

(2014) Svenja Werkmeister et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Substitutional Lability of Diphosphine Ligands in Tetrahedral Iron(II) Chloro Complexes

(2014) Robert Langer et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Hydricity of an Fe–H Species and Catalytic CO2 Hydrogenation

(2014) Henry Fong et al.   INORGANIC CHEMISTRY

Iron-Based Catalysts for the Hydrogenation of Esters to Alcohols

(2014) Sumit Chakraborty et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron(II) Complexes Containing Unsymmetrical P–N–P′ Pincer Ligands for the Catalytic Asymmetric Hydrogenation of Ketones and Imines

(2014) Paraskevi O. Lagaditis et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Unravelling the Mechanism of the Asymmetric Hydrogenation of Acetophenone by [RuX2(diphosphine)(1,2-diamine)] Catalysts

(2014) Pavel A. Dub et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Estimating the Acidity of Transition Metal Hydride and Dihydrogen Complexes by Adding Ligand Acidity Constants

(2014) Robert H. Morris   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Iron P-N-P′ and P-NH-P′ Asymmetric Hydrogenation Catalysts

(2014) Jessica F. Sonnenberg et al.   ORGANOMETALLICS

Well-Defined Iron Catalysts for the Acceptorless Reversible Dehydrogenation-Hydrogenation of Alcohols and Ketones

(2014) Sumit Chakraborty et al.   ACS Catalysis

Photosensitive iron(II)-based CO-releasing molecules (CORMs) with vicinal amino and diphenylphosphino substituted chelating ligands

(2013) Taghreed M.A. Jazzazi et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Quantum Chemical Calculations with the Inclusion of Nonspecific and Specific Solvation: Asymmetric Transfer Hydrogenation with Bifunctional Ruthenium Catalysts

(2013) Pavel A. Dub et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Amine(imine)diphosphine Iron Catalysts for Asymmetric Transfer Hydrogenation of Ketones and Imines

(2013) W. Zuo et al.   SCIENCE

Evidence for Iron Nanoparticles Catalyzing the Rapid Dehydrogenation of Ammonia-Borane

(2013) Jessica F. Sonnenberg et al.   ACS Catalysis

Iron Borohydride Pincer Complexes for the Efficient Hydrogenation of Ketones under Mild, Base-Free Conditions: Synthesis and Mechanistic Insight

(2012) Robert Langer et al.   CHEMISTRY-A EUROPEAN JOURNAL

Thermodynamic and Kinetic Hydricity of Ruthenium(II) Hydride Complexes

(2012) Yasuo Matsubara et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron Nanoparticles Catalyzing the Asymmetric Transfer Hydrogenation of Ketones

(2012) Jessica F. Sonnenberg et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Spectroscopic and DFT Study of Ferraaziridine Complexes Formed in the Transfer Hydrogenation of Acetophenone Catalyzed Using trans-[Fe(CO)(NCMe)(PPh2C6H4CH═NCH2−)2-κ4P,N,N,P](BF4)2

(2012) Demyan E. Prokopchuk et al.   ORGANOMETALLICS

High-Activity Iron Catalysts for the Hydrogenation of Hindered, Unfunctionalized Alkenes

(2012) Renyuan Pony Yu et al.   ACS Catalysis

Efficient Hydrogenation of Ketones Catalyzed by an Iron Pincer Complex

(2011) Robert Langer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Low-Pressure Hydrogenation of Carbon Dioxide Catalyzed by an Iron Pincer Complex Exhibiting Noble Metal Activity

(2011) Robert Langer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis, Electronic Structure, and Catalytic Activity of Reduced Bis(aldimino)pyridine Iron Compounds: Experimental Evidence for Ligand Participation

(2011) Sarah K. Russell et al.   INORGANIC CHEMISTRY

Experimental Investigations of a Partial Ru–O Bond during the Metal–Ligand Bifunctional Addition in Noyori-Type Enantioselective Ketone Hydrogenation

(2011) Satoshi Takebayashi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Hydrogenation of Esters. Development of an Efficient Catalyst and Processes for Synthesising (R)-1,2-Propanediol and 2-(l-Menthoxy)ethanol

(2011) Wataru Kuriyama et al.   ORGANIC PROCESS RESEARCH & DEVELOPMENT

Thermodynamics of the Metal–Hydrogen Bonds in (η5-C5H5)M(CO)2H (M = Fe, Ru, Os)

(2011) Deven P. Estes et al.   ORGANOMETALLICS

A Well-Defined Iron Catalyst for the Reduction of Bicarbonates and Carbon Dioxide to Formates, Alkyl Formates, and Formamides

(2010) Christopher Federsel et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Radical Ligands Confer Nobility on Base-Metal Catalysts

(2010) P. J. Chirik et al.   SCIENCE

Template Synthesis of Iron(II) Complexes Containing Tridentate P−N−S, P−N−P, P−N−N, and Tetradentate P−N−N−P Ligands

(2009) Paraskevi O. Lagaditis et al.   INORGANIC CHEMISTRY

Cyclopentadienone Iron Alcohol Complexes: Synthesis, Reactivity, and Implications for the Mechanism of Iron-Catalyzed Hydrogenation of Aldehydes

(2009) Charles P. Casey et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Facile Bifunctional Addition of Lactones and Esters at Low Temperatures. The First Intermediates in Lactone/Ester Hydrogenations

(2009) Satoshi Takebayashi et al.   ORGANOMETALLICS

A Multilateral Mechanistic Study into Asymmetric Transfer Hydrogenation in Water

(2008) Xiaofeng Wu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis and Characterization of Iron(II) Complexes with Tetradentate Diiminodiphosphine or Diaminodiphosphine Ligands as Precatalysts for the Hydrogenation of Acetophenone

(2008) Christine Sui-Seng et al.   INORGANIC CHEMISTRY

Direct Observations of the Metal−Ligand Bifunctional Addition Step in an Enantioselective Ketone Hydrogenation

(2008) Robin J. Hamilton et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Functional Group Tolerance and Substrate Scope in Bis(imino)pyridine Iron Catalyzed Alkene Hydrogenation

(2008) Ryan J. Trovitch et al.   ORGANOMETALLICS

Highly Efficient Catalyst Systems Using Iron Complexes with a Tetradentate PNNP Ligand for the Asymmetric Hydrogenation of Polar Bonds

(2007) Christine Sui-Seng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION