Forging Unsupported Metal-Boryl Bonds with Icosahedral Carboranes

Unprecedented flexibility of the 1,1′-bis(o-carborane) ligand: catalytically-active species stabilised by B-agostic B–H⇀Ru interactions

(2016) Laura E. Riley et al.   DALTON TRANSACTIONS

Facile Insertion of Rh and Ir into a Boron–Phenyl Bond, Leading to Boryl/Bis(phosphine) PBP Pincer Complexes

(2016) Wei-Chun Shih et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metal- and Ligand-Centered Reactivity of meta-Carboranyl-Backbone Pincer Complexes of Rhodium

(2016) Bennett J. Eleazer et al.   ORGANOMETALLICS

Defect-Tolerant Aligned Dipoles within Two-Dimensional Plastic Lattices

(2015) John C. Thomas et al.   ACS Nano

Palladium-Catalyzed Regioselective Diarylation of o -Carboranes By Direct Cage B−H Activation

(2015) Yangjian Quan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Direct Dialkenylation of Cage BH Bonds in o -Carboranes through Cross-Coupling Reactions

(2015) Hairong Lyu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Regioselective Intramolecular Coupling of o-Carborane with Aromatics via Direct Cage B–H Activation

(2015) Yangjian Quan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Pincer Iridium Complexes Bearing a Boron Atom and iPr-Substituted Phosphorus Atoms: Application to Catalytic Transfer Dehydrogenation of Alkanes

(2015) Keita Tanoue et al.   ORGANOMETALLICS

Reactions of the 21st Century: Two Decades of Innovative Catalyst Design for Palladium-Catalyzed Cross-Couplings

(2015) Peter G. Gildner et al.   ORGANOMETALLICS

Recent advances in transition metal-mediated functionalization of o-carboranes

(2015) Zaozao Qiu   TETRAHEDRON LETTERS

Structure and reactivity of [(L·Pd) n ·(1,5-cyclooctadiene)] ( n = 1–2) complexes bearing biaryl phosphine ligands

(2014) Hong Geun Lee et al.   INORGANICA CHIMICA ACTA

Iridium Catalyzed Regioselective Cage Boron Alkenylation of o-Carboranes via Direct Cage B–H Activation

(2014) Yangjian Quan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Boryl–Metal Bonds Facilitate Cobalt/Nickel-Catalyzed Olefin Hydrogenation

(2014) Tzu-Pin Lin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Arrested B–H Activation en Route to Installation of a PBP Pincer Ligand on Ruthenium and Osmium

(2014) Anthony F. Hill et al.   ORGANOMETALLICS

Methods to produce B–C, B–P, B–N and B–S bonds in boron clusters

(2013) David Olid et al.   CHEMICAL SOCIETY REVIEWS

B-Mercaptocarboranes: A New Synthetic Route

(2013) Kuanysh Z. Kabytaev et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

New ligand platforms featuring boron-rich clusters as organomimetic substituents

(2013) Alexander M. Spokoyny   PURE AND APPLIED CHEMISTRY

Isolation of a PBP-Pincer Rhodium Complex Stabilized by an Intermolecular CH σ Coordination as the Fourth Ligand

(2012) Maki Hasegawa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Regioselective B-Cyclometalation of a Bulky o-Carboranyl Phosphine and the Unexpected Formation of a Dirhodium(II) Complex

(2012) Natalie Fey et al.   ORGANOMETALLICS

Intramolecular Metal–Metal Bond Rearrangement in a Pt2PdHg Heterometallic Cluster Forming a HgI–PdICovalent Bond

(2011) Aya Hosokawa et al.   ORGANOMETALLICS

Electron-Precise Coordination Modes of Boron-Centered Ligands

(2010) Holger Braunschweig et al.   CHEMICAL REVIEWS

Novel Approach to Aminocarboranes by Mild Amidation of Selected Iodo-carboranes

(2010) Yulia Sevryugina et al.   INORGANIC CHEMISTRY

Boryl ligands and their roles in metal-catalysed borylation reactions

(2009) Li Dang et al.   CHEMICAL COMMUNICATIONS

Syntheses of PBP Pincer Iridium Complexes: A Supporting Boryl Ligand

(2009) Yasutomo Segawa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Carborane-Based Pincers: Synthesis and Structure of SeBSe and SBS Pd(II) Complexes

(2009) Alexander M. Spokoyny et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Diphenylphosphino- or Dicyclohexylphosphino-Tethered Boryl Pincer Ligands: Syntheses of PBP Iridium(III) Complexes and Their Conversion to Iridium−Ethylene Complexes

(2009) Yasutomo Segawa et al.   ORGANOMETALLICS

Biaryl Phosphane Ligands in Palladium-Catalyzed Amination

(2008) David S. Surry et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Covalent radii revisited

(2008) Beatriz Cordero et al.   DALTON TRANSACTIONS

A Highly Active Catalyst for Pd-Catalyzed Amination Reactions: Cross-Coupling Reactions Using Aryl Mesylates and the Highly Selective Monoarylation of Primary Amines Using Aryl Chlorides

(2008) Brett P. Fors et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Amidation of 9-Iodo-m-carborane and 2-Iodo-p-carborane at a Boron Atom

(2008) Sergey N. Mukhin et al.   ORGANOMETALLICS