Reactivity in the periphery of functionalised multiple bonds of heavier group 14 elements

From Silylone to an Isolable Monomeric Silicon Disulfide Complex

(2015) Yun Xiong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

SiSi Double Bonds: Synthesis of an NHC-Stabilized Disilavinylidene

(2015) Priyabrata Ghana et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

E-H Bond Activation of Ammonia and Water by a Geometrically Constrained Phosphorus(III) Compound

(2015) Thomas P. Robinson et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Reactivity of Amido-Digermynes, LGeGeL (L = Bulky Amide), toward Olefins and Related Molecules: Facile Reduction, C–H Activation, and Reversible Cycloaddition of Unsaturated Substrates

(2015) Terrance J. Hadlington et al.   ORGANOMETALLICS

Synthesis and Characterization of a 1,2-Digermabenzene

(2015) Takahiro Sasamori et al.   ORGANOMETALLICS

Synthesis of the First Homoleptic Trisilaallyl Chloride: ­3-Chloro-1, 1,2, 3,3-pentakis(2′,4′,6′-triisopropylphenyl)trisil-1-ene

(2015) Kai Abersfelder et al.   ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE

From Disilene (SiSi) to Phosphasilene (SiP) and Phosphacumulene (PCN)

(2014) Philipp Willmes et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

N-Heterocyclic Carbene Coordinated Neutral and Cationic Heavier Cyclopropylidenes

(2014) Anukul Jana et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

An N-Heterocyclic Silylene-Stabilized Digermanium(0) Complex

(2014) Yu-Liang Shan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Multiply Functionalized Base-Coordinated GeIICompound and Its Reversible Dimerization to the Digermene

(2014) Anukul Jana et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Dynamic Complexation of Copper(I) Chloride by Carbene-Stabilized Disilicon

(2014) Mingwei Chen et al.   CHEMISTRY-A EUROPEAN JOURNAL

Reactions of Diaryldibromodisilenes with N-Heterocyclic Carbenes: Formation of Formal Bis-NHC Adducts of Silyliumylidene Cations

(2014) Tomohiro Agou et al.   CHEMISTRY-A EUROPEAN JOURNAL

NHC-coordinated silagermenylidene functionalized in allylic position and its behaviour as a ligand

(2014) Anukul Jana et al.   DALTON TRANSACTIONS

Reaction Mechanisms of Small-Molecule Activation by Amidoditetrylynes R2N–EE–NR2 (E = Si, Ge, Sn)

(2014) Markus Hermann et al.   INORGANIC CHEMISTRY

N-Heterocyclic Carbene—Main-Group Chemistry: A Rapidly Evolving Field

(2014) Yuzhong Wang et al.   INORGANIC CHEMISTRY

Cationic Metallogermylene and Dicationic Dimetallodigermenes: Synthesis by Chloride Abstraction from N-Heterocyclic Carbene-Stabilized Chlorometallogermylenes

(2014) Koya Inomata et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Low Coordinate Germanium(II) and Tin(II) Hydride Complexes: Efficient Catalysts for the Hydroboration of Carbonyl Compounds

(2014) Terrance J. Hadlington et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Molecular Complex with a Formally Neutral Iron Germanide Motif (Fe2Ge2)

(2014) Anukul Jana et al.   ORGANOMETALLICS

Activation of H2by a Multiply Bonded Amido-Digermyne: Evidence for the Formation of a Hydrido-Germylene

(2013) Terrance J. Hadlington et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Reversible, Complete Cleavage of SiSi Double Bonds by Isocyanide Insertion

(2013) Moumita Majumdar et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

NHC-Stabilized Silagermenylidene: A Heavier Analogue of Vinylidene

(2013) Anukul Jana et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Dihydrodisilene Transition Metal Complex from an N-Heterocyclic Carbene-Stabilized Silylene Monohydride

(2013) Shigeyoshi Inoue et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Equilibrium between a cyclotrisilene and an isolable base adduct of a disilenyl silylene

(2013) Michael J. Cowley et al.   Nature Chemistry

Reaction Pathways for Addition of H2 to Amido-Ditetrylynes R2N–EE–NR2 (E = Si, Ge, Sn). A Theoretical Study

(2013) Markus Hermann et al.   ORGANOMETALLICS

Functionalized Cyclic Disilenes via Ring Expansion of Cyclotrisilenes with Isocyanides

(2013) Yu Ohmori et al.   ORGANOMETALLICS

Potential Protecting Group Strategy for Disila Analogues of Vinyllithiums: Synthesis and Reactivity of a 2,4,6-Trimethoxyphenyl-Substituted Disilene

(2013) Antje Meltzer et al.   ORGANOMETALLICS

Stable Complexes of Parent Digermene: An Inorganic Analogue of Ethylene

(2013) S. M. Ibrahim Al-Rafia et al.   ORGANOMETALLICS

Reversible Base Coordination to a Disilene

(2012) Kinga Leszczyńska et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Cp*Si+ cation as a stoichiometric source of silicon

(2012) Kinga Leszczyńska et al.   CHEMICAL COMMUNICATIONS

Transmetallation reactions of a lithium disilenide

(2012) Michael J. Cowley et al.   CHEMICAL COMMUNICATIONS

An N-heterocyclic carbene adduct of diatomic tin, :SnSn:

(2012) Cameron Jones et al.   CHEMICAL COMMUNICATIONS

Synthesis of Kinetically Stabilized 1,2-Dihydrodisilenes

(2012) Tomohiro Agou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The Role of Group 14 Element Hydrides in the Activation of C–H Bonds in Cyclic Olefins

(2012) Owen T. Summerscales et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A New Disilene with π-Accepting Groups from the Reaction of Disilyne RSi≡SiR (R = SiiPr[CH(SiMe3)2]) with Isocyanides

(2012) Katsuhiko Takeuchi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Trapping the Parent Inorganic Ethylenes H2SiGeH2 and H2SiSnH2 in the Form of Stable Adducts at Ambient Temperature

(2011) S. M. Ibrahim Al-Rafia et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent advances and actual challenges in late transition metal catalyzed hydrosilylation of olefins from an industrial point of view

(2011) Dennis Troegel et al.   COORDINATION CHEMISTRY REVIEWS

Carbene Stabilization of Highly Reactive Main-Group Molecules

(2011) Yuzhong Wang et al.   INORGANIC CHEMISTRY

Unusual Reactivity of a Disilyne with 4-Dimethylaminopyridine: Formation of an Intramolecularly N-Coordinated Silylene and Its Isomerization to a Zwitterionic Silyl Anion

(2011) Torahiko Yamaguchi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Room-Temperature Dissociation of 1,2-Dibromodisilenes to Bromosilylenes

(2011) Katsunori Suzuki et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

[[(Me3Si)2CH]2iPrSi(NHC)Si═Si(Me)SiiPr[CH(SiMe3)2]2]+: A Molecule with Disilenyl Cation Character

(2011) Torahiko Yamaguchi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

C–H Activation of Cycloalkenes by Dimetallynes (M = Ge, Sn) under Ambient Conditions

(2011) Owen T. Summerscales et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Digermyne with a Ge–Ge Single Bond That Activates Dihydrogen in the Solid State

(2011) Jiaye Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydroboration of Disilyne RSi≡SiR (R = SiiPr[CH(SiMe3)2]2), Giving Boryl-Substituted Disilenes

(2011) Katsuhiko Takeuchi et al.   ORGANOMETALLICS

Synthesis and Striking Reactivity of an Isolable Tetrasilyl-Substituted Trisilaallene

(2011) Hiroaki Tanaka et al.   ORGANOMETALLICS

A Planar Rhombic Charge-Separated Tetrasilacyclobutadiene

(2011) K. Suzuki et al.   SCIENCE

1,2-Dialkynyldisilenes: silicon analogues of (E)-enediyne

(2010) Takahiro Sato et al.   CHEMICAL COMMUNICATIONS

π-Bonding and the Lone Pair Effect in Multiple Bonds Involving Heavier Main Group Elements: Developments in the New Millennium

(2010) Roland C. Fischer et al.   CHEMICAL REVIEWS

The Versatile Chemistry of Disilenides: Disila Analogues of Vinyl Anions as Synthons in Low-valent Silicon Chemistry

(2010) David Scheschkewitz   CHEMISTRY LETTERS

Hydrosilylation of a Silicon(II) Hydride: Synthesis and Characterization of a Remarkable Silylsilylene

(2010) Shu-Hua Zhang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis, characterisation and complexation of phosphino disilenes

(2010) Marco Hartmann et al.   DALTON TRANSACTIONS

Reactivity of an aryl-substituted silicon–silicon triple bond: 1,2-disilabenzenes from the reactions of a 1,2-diaryldisilyne with alkynes

(2010) Joon Soo Han et al.   DALTON TRANSACTIONS

Silicon version of enamines: Amino-substituted disilenes by the reactions of the disilyne RSiSiR (R = SiiPr[CH(SiMe3)2]2) with amines

(2010) Katsuhiko Takeuchi et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Air-Stable, Room-Temperature Emissive Disilenes with π-Extended Aromatic Groups

(2010) Megumi Kobayashi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

AnN-Heterocyclic Carbene−Disilyne Complex and Its Reactivity toward ZnCl2

(2010) Torahiko Yamaguchi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Transfer of a Disilenyl Moiety to Aromatic Substrates and Lateral Functional Group Transformation in Aryl Disilenes

(2010) Jonathan Jeck et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Addition of methyllithium to disilyne RSiSiR (R = SiiPr[CH(SiMe3)2]), giving a disilenyllithium, and its unexpected isomerization to a disilacyclopropylsilyllithium

(2010) Torahiko Yamaguchi et al.   NEW JOURNAL OF CHEMISTRY

Synthesis and Structures of Low-Valent Alkynyl Tin and Germanium Complexes Supported by Terphenyl Ligands: Heavier Group 14 Element Enediyne Analogues†

(2010) Hao Lei et al.   ORGANOMETALLICS

Synthesis and structure of stable 1,2-diaryldisilyne

(2010) Takahiro Sasamori et al.   PURE AND APPLIED CHEMISTRY

A Tricyclic Aromatic Isomer of Hexasilabenzene

(2010) K. Abersfelder et al.   SCIENCE

Substituent effects in ditetrel alkyne analogues: multiple vs. single bonded isomers

(2010) Yang Peng et al.   Chemical Science

N-Heterocyclic Carbene Stabilized Digermanium(0)

(2009) Anastas Sidiropoulos et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis and Properties of Stable 1,2-Bis(metallocenyl)disilenes: Novel d–π Conjugated Systems with a Si=Si Double Bond

(2009) Akihiro Yuasa et al.   BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN

Anionic Reagents with Silicon-Containing Double Bonds

(2009) David Scheschkewitz   CHEMISTRY-A EUROPEAN JOURNAL

Divalent Silicon(0) Compounds

(2009) Nozomi Takagi et al.   CHEMISTRY-A EUROPEAN JOURNAL

Divalent E(0) Compounds (E=Si-Sn)

(2009) Nozomi Takagi et al.   CHEMISTRY-A EUROPEAN JOURNAL

Si3C2-Rings: From a Nonconjugated Trisilacyclopentadiene to an Aromatic Trisilacyclopentadienide and Cyclic Disilenide

(2009) Hiroyuki Yasuda et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Group 4 Metallocene Complexes of Disilenes, Digermenes, and a Silagermene

(2009) Michaela Zirngast et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Anthryl-Substituted Trialkyldisilene Showing Distinct Intramolecular Charge-Transfer Transition

(2009) Takeaki Iwamoto et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reversible Transformation of a Stable Monomeric Silicon(II) Compound into a Stable Disilene by Phase Transfer: Experimental and Theoretical Studies of the System {[(Me3Si)2N](Me5C5)Si }nwithn= 1,2

(2009) Peter Jutzi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Unusual Bonding in Trisilaallene and Related Heavy Allenes

(2009) Mitsuo Kira et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Addition of Amines and Hydroborane to the Disilyne RSi≡SiR (R = SiiPr[CH(SiMe3)2]2) Giving Amino- and Boryl-Substituted Disilenes

(2009) Katsuhiko Takeuchi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An (η3-Disilaallyl)lithium Derivative: Interconversion of π-Allyl-Type Bonding and η1Coordination to a Silyllithium Fragment

(2009) Hiroaki Tanaka et al.   ORGANOMETALLICS

Stannyl-substituted Disilenes and a Disilastannirane

(2009) Kai Abersfelder et al.   ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE

Addition of H2 to distannynes under ambient conditions

(2008) Yang Peng et al.   CHEMICAL COMMUNICATIONS

Cyclic polyenes of heavy group 14 elements: new generation ligands for transition-metal complexes

(2008) Vladimir Ya. Lee et al.   CHEMICAL SOCIETY REVIEWS

An Isolable Boryl-substituted Disilene from the Reaction of an sp2-type Silyl Anion with Haloboranes: Synthesis and Characterization

(2008) Shigeyoshi Inoue et al.   CHEMISTRY LETTERS

1,2-Disilacyclobut-2-enes: Donor-Free Four-Membered Cyclic Silenes from Reaction of Disilenides with Vinylbromides

(2008) Iulia Bejan et al.   CHEMISTRY-A EUROPEAN JOURNAL

Recent developments in the chemistry of low valent Group 14 hydrides

(2008) Eric Rivard et al.   DALTON TRANSACTIONS

Reactivity of the Disilyne RSiSiR (R = SiiPr[CH(SiMe3)2]2) toward Silylcyanide: Two Pathways To Form the Bis-Adduct [RSiSiR(CNSiMe3)2] with Some Silaketenimine Character and a 1,4-Diaza-2,3-disilabenzene Analogue

(2008) Katsuhiko Takeuchi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Syntheses of Trisila Analogues of Allyl Chlorides and Their Transformations to Chlorocyclotrisilanes, Cyclotrisilanides, and a Trisilaindane

(2008) Kai Abersfelder et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Isomeric Metamorphosis:  Si3E (E = S, Se, and Te) Bicyclo[1.1.0]butane and Cyclobutene

(2008) Vladimir Ya. Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Diarylstannylene Activation of Hydrogen or Ammonia with Arene Elimination

(2008) Yang Peng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis and Reactions of a Stable 1,2-Diaryl-1,2-dibromodisilene: A Precursor for Substituted Disilenes and a 1,2-Diaryldisilyne

(2008) Takahiro Sasamori et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

1,2-Bis(ferrocenyl)disilene: A Multistep Redox System with an SiSi Double Bond

(2008) Takahiro Sasamori et al.   ORGANOMETALLICS

A Stable Silicon(0) Compound with a Si=Si Double Bond

(2008) Y. Wang et al.   SCIENCE