期刊
CHEMICAL RECORD
卷 16, 期 6, 页码 2623-2643出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/tcr.201600084
关键词
asymmetric catalysis; hydrogenation; reaction mechanisms; supported catalysts; tethered catalyst; transition metals
资金
- UK Technology Strategy Board (TSB)
- Engineering and Physical Sciences Research Council [EP/F019424/1, EP/D031168/1, 1351352] Funding Source: researchfish
- EPSRC [EP/D031168/1, EP/F019424/1] Funding Source: UKRI
In this account, we describe the design, synthesis and applications of tethered versions of the Ru(II)/N-tosyl-1,2-diphenylethylene-1,2-diamine (TsDPEN) class of catalyst that are commonly used for asymmetric transfer hydrogenation and asymmetric hydrogenation of ketones and imines. The review covers key aspects of the reaction mechanisms and examples of applications, including industrial applications to pharmaceutically important target molecules. In addition, closely related catalysts based on Rh(III) and Ir(III) are also described.
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