Direct Synthesis of Boron-Protected Alkenyl- and Alkylborons via Copper-Catalyzed Formal Hydroboration of Alkynes and Alkenes

A masked diboron in Cu-catalysed borylation reaction: highly regioselective formal hydroboration of alkynes for synthesis of branched alkenylborons

(2014) Hiroto Yoshida et al.   CHEMICAL COMMUNICATIONS

Synthesis of most polyene natural product motifs using just 12 building blocks and one coupling reaction

(2014) Eric M. Woerly et al.   Nature Chemistry

Highly Stereoselective Synthesis of (Borylmethyl)cyclopropylamines by Copper-Catalyzed Aminoboration of Methylenecyclopropanes

(2014) Ryosuke Sakae et al.   ORGANIC LETTERS

Silver-Catalyzed Highly Regioselective Formal Hydroboration of Alkynes

(2014) Hiroto Yoshida et al.   ORGANIC LETTERS

Methoxy-Functionalized N-Heterocyclic Carbenes

(2014) David J. Nelson et al.   ORGANOMETALLICS

Three-Component Carboboration of Alkenes under Copper Catalysis

(2014) Hiroto Yoshida et al.   SYNTHESIS-STUTTGART

Regioselective transformation of alkynes catalyzed by a copper hydride or boryl copper species

(2014) Tetsuaki Fujihara et al.   Catalysis Science & Technology

Copper-Catalyzed Borylation of α-Alkoxy Allenes with Bis(pinacolato)diboron: Efficient Synthesis of 2-Boryl 1,3-Butadienes

(2013) Kazuhiko Semba et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-catalyzed distannylation of alkynes

(2013) Hiroto Yoshida et al.   CHEMICAL COMMUNICATIONS

Highly Selective Copper-Catalyzed Hydroboration of Allenes and 1,3-Dienes

(2013) Kazuhiko Semba et al.   CHEMISTRY-A EUROPEAN JOURNAL

Regioselective and Stereospecific Copper-Catalyzed Aminoboration of Styrenes with Bis(pinacolato)diboron and O-Benzoyl-N,N-dialkylhydroxylamines

(2013) Naoki Matsuda et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper(I)-Catalyzed Borylative exo-Cyclization of Alkenyl Halides Containing Unactivated Double Bond

(2013) Koji Kubota et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Three-Component Carboboration of Alkynes and Alkenes

(2013) Hiroto Yoshida et al.   ORGANIC LETTERS

NHC–Cu-Catalyzed Protoboration of Monosubstituted Allenes. Ligand-Controlled Site Selectivity, Application to Synthesis and Mechanism

(2013) Fanke Meng et al.   ORGANIC LETTERS

(1-Bromovinyl)-MIDA boronate: a readily accessible and highly versatile building block for small molecule synthesis

(2013) Eric M. Woerly et al.   TETRAHEDRON

Copper(I)-Catalyzed Boron Addition Reactions of Alkynes with Diboron Reagents

(2013) Jaesook Yun   Asian Journal of Organic Chemistry

Ligand Controlled Highly Selective Copper-Catalyzed Borylcuprations of Allenes with Bis(pinacolato)diboron

(2012) Weiming Yuan et al.   ADVANCED SYNTHESIS & CATALYSIS

A General Solution for the 2-Pyridyl Problem

(2012) Graham R. Dick et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Highly Regio- and Stereoselective Directed Hydroboration of Unsymmetrical Internal Alkynes: Controlling Regioselectivity by Choice of Catalytic Species

(2012) Kazuhiko Semba et al.   CHEMISTRY-A EUROPEAN JOURNAL

Copper-Catalyzed Three-Component Borylstannylation of Alkynes

(2012) Yuki Takemoto et al.   CHEMISTRY-A EUROPEAN JOURNAL

Regiocontrolled CuI-Catalyzed Borylation of Propargylic-Functionalized Internal Alkynes

(2012) Abraham L. Moure et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

CuCl–K2CO3-catalyzed highly selective borylcupration of internal alkynes – ligand effect

(2012) Weiming Yuan et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Regioselective Catalytic Hydroboration of Propargylic Species Using Cu(I)-NHC Complexes

(2012) Jin Kyoon Park et al.   ORGANIC LETTERS

Copper-Catalyzed Double Borylation of Silylacetylenes: Highly Regio- and Stereoselective Synthesis of Syn-Vicinal Diboronates

(2012) Ho-Young Jung et al.   ORGANIC LETTERS

Total Synthesis of Synechoxanthin through Iterative Cross-Coupling

(2011) Seiko Fujii et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Borylation Reactions of Alkynes and Arynes

(2011) Hiroto Yoshida et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly regio- and stereoselective synthesis of alkenylboronic esters by copper-catalyzed boron additions to disubstituted alkynes

(2011) Hye Ryung Kim et al.   CHEMICAL COMMUNICATIONS

Influence of a Very BulkyN-Heterocyclic Carbene in Gold-Mediated Catalysis

(2011) Adrián Gómez-Suárez et al.   ORGANOMETALLICS

(Z)-(2-Bromovinyl)-MIDA boronate: a readily accessible and highly versatile building block for small molecule synthesis

(2011) Eric M. Woerly et al.   TETRAHEDRON

A Simple and General Platform for Generating Stereochemically Complex Polyene Frameworks by Iterative Cross-Coupling

(2010) Suk Joong Lee et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-catalyzed Dehydroborylation of Styrenes with Naphthalene-1,8-diaminatoborane [(dan)BH]: New Synthesis of Masked β-Borylstyrenes as New Phenylene–Vinylene Cross-coupling Modules

(2010) Noriyuki Iwadate et al.   CHEMISTRY LETTERS

Stereoretentive Suzuki−Miyaura Coupling of Haloallenes Enables Fully Stereocontrolled Access to (−)-Peridinin

(2010) Eric M. Woerly et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereospecific Synthesis of Cyclobutylboronates through Copper(I)-Catalyzed Reaction of Homoallylic Sulfonates and a Diboron Derivative

(2010) Hajime Ito et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Differentially Protected Diboron for Regioselective Diboration of Alkynes: Internal-Selective Cross-Coupling of 1-Alkene-1,2-diboronic Acid Derivatives

(2010) Noriyuki Iwadate et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

General Method for Synthesis of 2-HeterocyclicN-Methyliminodiacetic Acid Boronates

(2010) Graham R. Dick et al.   ORGANIC LETTERS

Ethynyl MIDA boronate: a readily accessible and highly versatile building block for small molecule synthesis

(2010) Justin R. Struble et al.   TETRAHEDRON

IPr* an easily accessible highly hindered N-heterocyclic carbene

(2009) Guillaume Berthon-Gelloz et al.   DALTON TRANSACTIONS

A General Solution for Unstable Boronic Acids: Slow-Release Cross-Coupling from Air-Stable MIDA Boronates

(2009) David M. Knapp et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of B-Protected β-Styrylboronic Acids via Iridium-Catalyzed Hydroboration of Alkynes with 1,8-Naphthalenediaminatoborane Leading to Iterative Synthesis of Oligo(phenylenevinylene)s

(2009) Noriyuki Iwadate et al.   ORGANIC LETTERS

Synthesis of Optically Active Boron-Silicon Bifunctional Cyclopropane Derivatives through Enantioselective Copper(I)-Catalyzed Reaction of Allylic Carbonates with a Diboron Derivative

(2008) Hajime Ito et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-catalyzed addition of diboron reagents to α,β-acetylenic esters: efficient synthesis of β-boryl-α,β-ethylenic esters

(2008) Ji-Eon Lee et al.   CHEMICAL COMMUNICATIONS

Synthesis of masked haloareneboronic acids via iridium-catalyzed aromatic C–H borylation with 1,8-naphthalenediaminatoborane (danBH)

(2008) Noriyuki Iwadate et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Multistep Synthesis of Complex Boronic Acids from Simple MIDA Boronates

(2008) Eric P. Gillis et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Differentially Protected Benzenediboronic Acids:  Divalent Cross-Coupling Modules for the Efficient Synthesis of Boron-Substituted Oligoarenes

(2008) Hiroyoshi Noguchi et al.   ORGANIC LETTERS

Vinyl MIDA boronate: a readily accessible and highly versatile building block for small molecule synthesis

(2008) Brice E. Uno et al.   TETRAHEDRON

Simple, Efficient, and Modular Syntheses of Polyene Natural Products via Iterative Cross-Coupling

(2007) Suk Joong Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY