Diastereo- and Enantioselective 1,4-Difunctionalization of Borylenynes by Catalytic Conjunctive Cross-Coupling

Preparation of Chiral Allenes through Pd-Catalyzed Intermolecular Hydroamination of Conjugated Enynes: Enantioselective Synthesis Enabled by Catalyst Design

(2019) Nathan J. Adamson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper Hydride Catalyzed Enantioselective Synthesis of Axially Chiral 1,3-Disubstituted Allenes

(2019) Liela Bayeh-Romero et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd-Catalyzed Enantioselective Heck Reaction of Aryl Triflates and Alkynes

(2019) Chenghao Zhu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Organocatalytic Formation of Chiral Trisubstituted Allenes and Chiral Furan Derivatives

(2018) Pernille H. Poulsen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Elucidating the Role of the Boronic Esters in the Suzuki–Miyaura Reaction: Structural, Kinetic, and Computational Investigations

(2018) Andy A. Thomas et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Synthesis of Trisubstituted Allenyl–B(pin) Compounds by Phosphine–Cu-Catalyzed 1,3-Enyne Hydroboration. Insights Regarding Stereochemical Integrity of Cu–Allenyl Intermediates

(2018) Youming Huang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Construction of Tertiary Boronic Esters by Conjunctive Cross-Coupling

(2018) Jesse A. Myhill et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Diastereoselective and Enantioselective Conjunctive Cross-Coupling Enabled by Boron Ligand Design

(2018) Jesse A. Myhill et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Structural, Kinetic, and Computational Characterization of the Elusive Arylpalladium(II)boronate Complexes in the Suzuki–Miyaura Reaction

(2017) Andy A. Thomas et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Conjunctive Cross-Coupling of Bis(alkenyl)borates: A General Synthesis of Chiral Allylboron Reagents

(2017) Emma K. Edelstein et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd-Catalyzed Conjunctive Cross-Coupling between Grignard-Derived Boron “Ate” Complexes and C(sp2) Halides or Triflates: NaOTf as a Grignard Activator and Halide Scavenger

(2017) Gabriel J. Lovinger et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ni-Catalyzed Enantioselective Conjunctive Coupling with C(sp3) Electrophiles: A Radical-Ionic Mechanistic Dichotomy

(2017) Gabriel J. Lovinger et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent advances in catalytic asymmetric synthesis of allenes

(2017) Wen-Dao Chu et al.   Catalysis Science & Technology

Chiral Allenes via Alkynylogous Mukaiyama Aldol Reaction

(2016) Aurélien Tap et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Synthesis of Trisubstituted Allenes via Cu(I)-Catalyzed Coupling of Diazoalkanes with Terminal Alkynes

(2016) Wen-Dao Chu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pre-transmetalation intermediates in the Suzuki-Miyaura reaction revealed: The missing link

(2016) A. A. Thomas et al.   SCIENCE

Chirality transfer in metal-catalysed intermolecular addition reactions involving allenes

(2016) José Miguel Alonso et al.   Organic Chemistry Frontiers

Direct Synthesis of Chiral Allenoates from the Asymmetric CH Insertion of α-Diazoesters into Terminal Alkynes

(2015) Yu Tang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

General CuBr2-catalyzed highly enantioselective approach for optically active allenols from terminal alkynols

(2015) Xin Huang et al.   CHEMICAL COMMUNICATIONS

Synthesis of Highly Substituted Racemic and Enantioenriched Allenylsilanes via Copper-Catalyzed Hydrosilylation of (Z)-2-Alken-4-ynoates with Silylboronate

(2015) Min Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic conjunctive cross-coupling enabled by metal-induced metallate rearrangement

(2015) L. Zhang et al.   SCIENCE

Recent applications of chiral allenes in axial-to-central chirality transfer reactions

(2015) Robynne K. Neff et al.   TETRAHEDRON

Conquering three-carbon axial chirality of allenes

(2014) Juntao Ye et al.   Organic Chemistry Frontiers

Combining NHC-Cu and Brønsted Base Catalysis: Enantioselective Allylic Substitution/Conjugate Additions with Alkynylaluminum Reagents and Stereospecific Isomerization of the Products to Trisubstituted Allenes

(2013) Jennifer A. Dabrowski et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Room-Temperature Catalytic Asymmetric Synthesis of Allenes with ECNU-Phos

(2013) Yuli Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Organocatalytic Enantioselective Synthesis of 2,3-Allenoates by Intermolecular Addition of Nitroalkanes to Activated Enynes

(2013) Hui Qian et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Phase-transfer-catalysed asymmetric synthesis of tetrasubstituted allenes

(2013) Takuya Hashimoto et al.   Nature Chemistry

Allenes in Catalytic Asymmetric Synthesis and Natural Product Syntheses

(2012) Shichao Yu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

How easy are the syntheses of allenes?

(2011) Shichao Yu et al.   CHEMICAL COMMUNICATIONS

Enantioselective Bromolactonization of Conjugated (Z)-Enynes

(2010) Wei Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electrophilic Addition and Cyclization Reactions of Allenes

(2009) Shengming Ma   ACCOUNTS OF CHEMICAL RESEARCH

An Efficient Synthesis of 2,5-Dihydrofuran-Fused Bicyclic Skeletons via the Pd(II)-Catalyzed Tandem-Cyclization Reaction of 1,ω-Bisallenols

(2009) Youqian Deng et al.   ORGANIC LETTERS

Catalytic enantioselective synthesis of axially chiral allenes

(2009) Masamichi Ogasawara   TETRAHEDRON-ASYMMETRY

Golden opportunities in catalysis

(2008) Norbert Krause et al.   PURE AND APPLIED CHEMISTRY

PdCl2/NaI-Catalyzed Homodimeric Coupling-Cyclization Reaction of 2,3-Allenols:  An Efficient Synthesis of 4-(1‘,3‘-Dien-2‘-yl)-2,5-dihydrofuran Derivatives

(2007) Youqian Deng et al.   JOURNAL OF ORGANIC CHEMISTRY