4.6 Article

Preparation of Zn0.5Cd0.5S@Ni-Glycerate composite for photocatalytic water reduction

期刊

出版社

ELSEVIER SCI LTD
DOI: 10.1016/j.mssp.2019.104703

关键词

Semiconductor; Organometallic compound; Photocatalyst; Hydrogen production

资金

  1. National Natural Science Foundation of China [21663027, 21808189]
  2. Program for the Young Innovative Talents of Longyuan
  3. Program for Innovative Research Team [NWNU-LKQN-15-2]

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Large specific surface is beneficial to improve the performance of catalyst in the application of water photolysis. In this work, we designed and successfully prepared the metal compound Ni-Glycerate with a large specific surface area, and combined it with Zn0.5Cd0.5S to form Zn0.5Cd0.5S@Ni-Glycerate core-shell structure nano-composites. It was revealed that the introduction of nickel-glycerate can promote the separation of photoinduced charges and accelerate the photocatalytic water decomposition reaction. The optimized H-2 production rate on Zn0.5Cd0.5S@Nickel-glycerate (3%) can reach 2800 mu mol/h/0.1 g, about 6 times that of pure Zn0.5Cd0.5S. This work indicates that the sulfide-metal organic complex can play a synergistic role in the entire photocatalytic reaction.

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