An Update on Formic Acid Dehydrogenation by Homogeneous Catalysis

PN3(P)-Pincer Complexes: Cooperative Catalysis and Beyond

(2019) Huaifeng Li et al.   ACS Catalysis

Fuelling the hydrogen economy: Scale-up of an integrated formic acid-to-power system

(2019) Robbert van Putten et al.   INTERNATIONAL JOURNAL OF HYDROGEN ENERGY

Catalytic Dehydrogenation of Formic Acid with Ruthenium-PNP-Pincer Complexes: Comparing N-Methylated and NH-Ligands

(2019) Anastasiya Agapova et al.   ChemCatChem

Cobalt‐Catalyzed Aqueous Dehydrogenation of Formic Acid

(2019) Wei Zhou et al.   CHEMISTRY-A EUROPEAN JOURNAL

Computationally guided design of a new Rh catalyst for selective formic acid dehydrogenation: Validation with caution

(2019) Chao Guan et al.   INTERNATIONAL JOURNAL OF HYDROGEN ENERGY

Solvent effects on high-pressure hydrogen gas generation by dehydrogenation of formic acid using ruthenium complexes

(2019) Masayuki Iguchi et al.   INTERNATIONAL JOURNAL OF HYDROGEN ENERGY

Synergistic Cu2 Catalysts for Formic Acid Dehydrogenation

(2019) Takayuki Nakajima et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Towards Hydrogen Storage through an Efficient Ruthenium-Catalyzed Dehydrogenation of Formic Acid

(2018) Zhuo Xin et al.   ChemSusChem

Mechanistic Considerations on Homogeneously Catalyzed Formic Acid Dehydrogenation

(2018) Manuel Iglesias et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Hydrogen generation from formic acid decomposition on a highly efficient iridium catalyst bearing a diaminoglyoxime ligand

(2018) Sheng-Mei Lu et al.   GREEN CHEMISTRY

Homogeneous catalytic formic acid dehydrogenation in aqueous solution using ruthenium arene phosphine catalysts

(2018) Gabor Laurenczy et al.   ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE

Single-site ruthenium pincer complex knitted in porous organic polymers for green dehydrogenation of formic acid in aqueous medium

(2018) Kuo-Wei Huang et al.   ChemSusChem

Highly Efficient Base-Free Dehydrogenation of Formic Acid at Low Temperature

(2018) Christoph Prichatz et al.   ChemSusChem

Conversion of CO2 from air into formate using amines and phosphorus-nitrogen PN3P-Ru(ii) pincer complexes

(2018) Chao Guan et al.   GREEN CHEMISTRY

Development of Effective Catalysts for Hydrogen Storage Technology Using Formic Acid

(2018) Naoya Onishi et al.   Advanced Energy Materials

Carbon Dioxide Hydrogenation and Formic Acid Dehydrogenation Catalyzed by Iridium Complexes Bearing Pyridyl-pyrazole Ligands: Effect of an Electron-donating Substituent on the Pyrazole Ring on the Catalytic Activity and Durability

(2018) Naoya Onishi et al.   ADVANCED SYNTHESIS & CATALYSIS

Base-Free Dehydrogenation of Aqueous and Neat Formic Acid with Iridium(III) Cp*(dipyridylamine) Catalysts

(2018) Shengdong Wang et al.   ChemSusChem

Formic Acid Dehydrogenation by Ruthenium Catalyst - Computational and Kinetic Analysis with the Energy Span Model

(2018) Alexander Frenklah et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Versatile Rh- and Ir-Based Catalysts for CO2 Hydrogenation, Formic Acid Dehydrogenation, and Transfer Hydrogenation of Quinolines

(2018) Jairo Fidalgo et al.   INORGANIC CHEMISTRY

Structural analysis of transient reaction intermediate in formic acid dehydrogenation catalysis using two-dimensional IR spectroscopy

(2018) Yufan Zhang et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Iridium and Ruthenium Complexes of N-Heterocyclic Carbene- and Pyridinol-Derived Chelates as Catalysts for Aqueous Carbon Dioxide Hydrogenation and Formic Acid Dehydrogenation: The Role of the Alkali Metal

(2017) Sopheavy Siek et al.   ORGANOMETALLICS

A Bifunctional Iridium Catalyst Modified for Persistent Hydrogen Generation from Formic Acid: Understanding Deactivation via Cyclometalation of a 1,2-Diphenylethylenediamine Motif

(2017) Asuka Matsunami et al.   ACS Catalysis

Ir(III)-PC(sp3)P Bifunctional Catalysts for Production of H2 by Dehydrogenation of Formic Acid: Experimental and Theoretical Study

(2017) Shirel Cohen et al.   ACS Catalysis

A Bipyridine-Based Conjugated Microporous Polymer for the Ir-Catalyzed Dehydrogenation of Formic Acid

(2017) Cornelia Broicher et al.   ACS Catalysis

Dehydrogenation of Formic Acid over a Homogeneous Ru-TPPTS Catalyst: Unwanted CO Production and Its Successful Removal by PROX

(2017) Vera Henricks et al.   Catalysts

Recent progress for reversible homogeneous catalytic hydrogen storage in formic acid and in methanol

(2017) Naoya Onishi et al.   COORDINATION CHEMISTRY REVIEWS

Formic acid as a hydrogen storage material – development of homogeneous catalysts for selective hydrogen release

(2016) Dörthe Mellmann et al.   CHEMICAL SOCIETY REVIEWS

Computational Study of Formic Acid Dehydrogenation Catalyzed by AlIII -Bis(imino)pyridine

(2016) Qian-Qian Lu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Selective Hydrogen Generation from Formic Acid with Well-Defined Complexes of Ruthenium and Phosphorus-Nitrogen PN3 -Pincer Ligand

(2016) Yupeng Pan et al.   Chemistry-An Asian Journal

Efficient Hydrogen Storage and Production Using a Catalyst with an Imidazoline-Based, Proton-Responsive Ligand

(2016) Lin Wang et al.   ChemSusChem

Development of an Iridium-Based Catalyst for High-Pressure Evolution of Hydrogen from Formic Acid

(2016) Masayuki Iguchi et al.   ChemSusChem

Nickel-catalyzed release of H2 from formic acid and a new method for the synthesis of zerovalent Ni(PMe3)4

(2016) Michelle C. Neary et al.   DALTON TRANSACTIONS

Dehydrogenation of Formic Acid Catalyzed by a Ruthenium Complex with an N,N′-Diimine Ligand

(2016) Chao Guan et al.   INORGANIC CHEMISTRY

Selective Formic Acid Dehydrogenation Catalyzed by Fe-PNP Pincer Complexes Based on the 2,6-Diaminopyridine Scaffold

(2016) Irene Mellone et al.   ORGANOMETALLICS

A prolific catalyst for dehydrogenation of neat formic acid

(2016) Jeff Joseph A. Celaje et al.   Nature Communications

DFT Study on the Mechanism of Formic Acid Decomposition by a Well-Defined Bifunctional Cyclometalated Iridium(III) Catalyst: Self-Assisted Concerted Dehydrogenation via Long-Range Intermolecular Hydrogen Migration

(2016) Jingjing Li et al.   ACS Catalysis

Iridium-Catalyzed Continuous Hydrogen Generation from Formic Acid and Its Subsequent Utilization in a Fuel Cell: Toward a Carbon Neutral Chemical Energy Storage

(2016) Miklos Czaun et al.   ACS Catalysis

Reversible cyclometalation at RhI as a motif for metal–ligand bifunctional bond activation and base-free formic acid dehydrogenation

(2016) L. S. Jongbloed et al.   Catalysis Science & Technology

Direction to practical production of hydrogen by formic acid dehydrogenation with Cp*Ir complexes bearing imidazoline ligands

(2016) Naoya Onishi et al.   Catalysis Science & Technology

Hydrogen energy future with formic acid: a renewable chemical hydrogen storage system

(2016) Ashish Kumar Singh et al.   Catalysis Science & Technology

Formic Acid as a Hydrogen Energy Carrier

(2016) Jörg Eppinger et al.   ACS Energy Letters

Hydrogenation and Dehydrogenation Iron Pincer Catalysts Capable of Metal–Ligand Cooperation by Aromatization/Dearomatization

(2015) Thomas Zell et al.   ACCOUNTS OF CHEMICAL RESEARCH

A Viable Hydrogen Storage and Release System Based on Cesium Formate and Bicarbonate Salts: Mechanistic Insights into the Hydrogen Release Step

(2015) Katerina Sordakis et al.   ChemCatChem

Simple Continuous High-Pressure Hydrogen Production and Separation System from Formic Acid under Mild Temperatures

(2015) Masayuki Iguchi et al.   ChemCatChem

CO2 Hydrogenation to Formate and Methanol as an Alternative to Photo- and Electrochemical CO2 Reduction

(2015) Wan-Hui Wang et al.   CHEMICAL REVIEWS

Enhanced Hydrogen Generation from Formic Acid by Half-Sandwich Iridium(III) Complexes with Metal/NH Bifunctionality: A Pronounced Switch from Transfer Hydrogenation

(2015) Asuka Matsunami et al.   CHEMISTRY-A EUROPEAN JOURNAL

Unprecedentedly High Formic Acid Dehydrogenation Activity on an Iridium Complex with anN,N′-Diimine Ligand in Water

(2015) Zhijun Wang et al.   CHEMISTRY-A EUROPEAN JOURNAL

A new class of PN3-pincer ligands for metal–ligand cooperative catalysis

(2015) Huaifeng Li et al.   COORDINATION CHEMISTRY REVIEWS

Efficient Cp*Ir Catalysts with Imidazoline Ligands for CO2Hydrogenation

(2015) Shaoan Xu et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Immobilizing Highly Catalytically Active Noble Metal Nanoparticles on Reduced Graphene Oxide: A Non-Noble Metal Sacrificial Approach

(2015) Yao Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dehydrogenation of formic acid by Ir–bisMETAMORPhos complexes: experimental and computational insight into the role of a cooperative ligand

(2015) Sander Oldenhof et al.   Chemical Science

Iron(II) Complexes of the Linear rac-Tetraphos-1 Ligand as Efficient Homogeneous Catalysts for Sodium Bicarbonate Hydrogenation and Formic Acid Dehydrogenation

(2015) Federica Bertini et al.   ACS Catalysis

Interconversion of Formic Acid and Carbon Dioxide by Proton-Responsive, Half-Sandwich Cp*IrIII Complexes: A Computational Mechanistic Investigation

(2015) Mehmed Z. Ertem et al.   ACS Catalysis

Highly Efficient Reversible Hydrogenation of Carbon Dioxide to Formates Using a Ruthenium PNP-Pincer Catalyst

(2014) Georgy A. Filonenko et al.   ChemCatChem

Formic Acid Dehydrogenation Catalysed by Tris(TPPTS) Ruthenium Species: Mechanism of the Initial “Fast” Cycle

(2014) Arnaud Thevenon et al.   ChemCatChem

Exploring the Reactivity of Nickel Pincer Complexes in the Decomposition of Formic Acid to CO2/H2and the Hydrogenation of NaHCO3to HCOONa

(2014) Stephan Enthaler et al.   ChemCatChem

Base-Free Non-Noble-Metal-Catalyzed Hydrogen Generation from Formic Acid: Scope and Mechanistic Insights

(2014) Dörthe Mellmann et al.   CHEMISTRY-A EUROPEAN JOURNAL

Formic Acid Dehydrogenation with Bioinspired Iridium Complexes: A Kinetic Isotope Effect Study and Mechanistic Insight

(2014) Wan-Hui Wang et al.   ChemSusChem

Lewis Acid-Assisted Formic Acid Dehydrogenation Using a Pincer-Supported Iron Catalyst

(2014) Elizabeth A. Bielinski et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

B-Doped Pd Catalyst: Boosting Room-Temperature Hydrogen Production from Formic Acid–Formate Solutions

(2014) Kun Jiang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Computational Studies Explain the Importance of Two Different Substituents on the Chelating Bis(amido) Ligand for Transfer Hydrogenation by Bifunctional Cp*Rh(III) Catalysts

(2014) Ainara Nova et al.   ORGANOMETALLICS

Aluminium–ligand cooperation promotes selective dehydrogenation of formic acid to H2 and CO2

(2014) T. W. Myers et al.   Chemical Science

Reversible CO2 binding triggered by metal–ligand cooperation in a rhenium(i) PNP pincer-type complex and the reaction with dihydrogen

(2014) Matthias Vogt et al.   Chemical Science

Hydrogen Production by Selective Dehydrogenation of HCOOH Catalyzed by Ru-Biaryl Sulfonated Phosphines in Aqueous Solution

(2014) Antonella Guerriero et al.   ACS Catalysis

A new Cu-based system for formic acid dehydrogenation

(2014) Nicola Scotti et al.   RSC Advances

An Efficient CoAuPd/C Catalyst for Hydrogen Generation from Formic Acid at Room Temperature

(2013) Zhi-Li Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Monodisperse AgPd Alloy Nanoparticles and Their Superior Catalysis for the Dehydrogenation of Formic Acid

(2013) Sen Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chemical Equilibria in Formic Acid/Amine-CO2Cycles under Isochoric Conditions using a Ruthenium(II) 1,2-Bis(diphenylphosphino)ethane Catalyst

(2013) Katerina Sordakis et al.   ChemCatChem

Ruthenium(II)-Catalyzed Hydrogen Generation from Formic Acid using Cationic, Ammoniomethyl-Substituted Triarylphosphine Ligands

(2013) Weijia Gan et al.   ChemCatChem

Efficient Hydrogen Liberation from Formic Acid Catalyzed by a Well-Defined Iron Pincer Complex under Mild Conditions

(2013) Thomas Zell et al.   CHEMISTRY-A EUROPEAN JOURNAL

Base-Free Production of H2by Dehydrogenation of Formic Acid Using An Iridium-bisMETAMORPhos Complex

(2013) Sander Oldenhof et al.   CHEMISTRY-A EUROPEAN JOURNAL

Towards a Practical Setup for Hydrogen Production from Formic Acid

(2013) Peter Sponholz et al.   ChemSusChem

Sodium hydroxide-assisted growth of uniform Pd nanoparticles on nanoporous carbon MSC-30 for efficient and complete dehydrogenation of formic acid under ambient conditions

(2013) Qi-Long Zhu et al.   Chemical Science

Pd and Pd–Ag Nanoparticles within a Macroreticular Basic Resin: An Efficient Catalyst for Hydrogen Production from Formic Acid Decomposition

(2013) Kohsuke Mori et al.   ACS Catalysis

Formic Acid As a Hydrogen Storage Medium: Ruthenium-Catalyzed Generation of Hydrogen from Formic Acid in Emulsions

(2013) Miklos Czaun et al.   ACS Catalysis

Efficient H2generation from formic acid using azole complexes in water

(2013) Yuichi Manaka et al.   Catalysis Science & Technology

Interconversion of CO2 and formic acid by bio-inspired Ir complexes with pendent bases

(2012) Etsuko Fujita et al.   BIOCHIMICA ET BIOPHYSICA ACTA-BIOENERGETICS

Highly Efficient D2 Generation by Dehydrogenation of Formic Acid in D2O through H+/D+ Exchange on an Iridium Catalyst: Application to the Synthesis of Deuterated Compounds by Transfer Deuterogenation

(2012) Wan-Hui Wang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Formic acid dehydrogenation catalysed by ruthenium complexes bearing the tripodal ligands triphos and NP3

(2012) Irene Mellone et al.   DALTON TRANSACTIONS

Second-coordination-sphere and electronic effects enhance iridium(iii)-catalyzed homogeneous hydrogenation of carbon dioxide in water near ambient temperature and pressure

(2012) Wan-Hui Wang et al.   Energy & Environmental Science

Catalytic interconversion between hydrogen and formic acid at ambient temperature and pressure

(2012) Yuta Maenaka et al.   Energy & Environmental Science

Formic acid as a hydrogen source – recent developments and future trends

(2012) Martin Grasemann et al.   Energy & Environmental Science

Liquid-phase chemical hydrogen storage materials

(2012) Mahendra Yadav et al.   Energy & Environmental Science

Efficient Subnanometric Gold-Catalyzed Hydrogen Generation via Formic Acid Decomposition under Ambient Conditions

(2012) Qing-Yuan Bi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reversible hydrogen storage using CO2 and a proton-switchable iridium catalyst in aqueous media under mild temperatures and pressures

(2012) Jonathan F. Hull et al.   Nature Chemistry

Long-range metal–ligand bifunctional catalysis: cyclometallated iridium catalysts for the mild and rapid dehydrogenation of formic acid

(2012) Jonathan H. Barnard et al.   Chemical Science

The Rise of the Iron Age in Hydrogen Evolution?

(2011) Stephan Enthaler et al.   ChemCatChem

Interconversion between Formic Acid and H2/CO2 using Rhodium and Ruthenium Catalysts for CO2 Fixation and H2 Storage

(2011) Yuichiro Himeda et al.   ChemSusChem

Catalytic mechanisms of hydrogen evolution with homogeneous and heterogeneous catalysts

(2011) Shunichi Fukuzumi et al.   Energy & Environmental Science

Synergistic Catalysis of Metal–Organic Framework-Immobilized Au–Pd Nanoparticles in Dehydrogenation of Formic Acid for Chemical Hydrogen Storage

(2011) Xiaojun Gu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydrogen production from formic acid decomposition at room temperature using a Ag–Pd core–shell nanocatalyst

(2011) Karaked Tedsree et al.   Nature Nanotechnology

Mechanistic Studies on the Reversible Hydrogenation of Carbon Dioxide Catalyzed by an Ir-PNP Complex

(2011) Ryo Tanaka et al.   ORGANOMETALLICS

Efficient Dehydrogenation of Formic Acid Using an Iron Catalyst

(2011) A. Boddien et al.   SCIENCE

ortho-Metalation of Iron(0) Tribenzylphosphine Complexes: Homogeneous Catalysts for the Generation of Hydrogen from Formic Acid

(2010) Albert Boddien et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Novel PdAu@Au/C Core−Shell Catalyst: Superior Activity and Selectivity in Formic Acid Decomposition for Hydrogen Generation

(2010) Yunjie Huang et al.   CHEMISTRY OF MATERIALS

The Hydrogen Issue

(2010) Nicola Armaroli et al.   ChemSusChem

Carbon dioxide and formic acid—the couple for environmental-friendly hydrogen storage?

(2010) Stephan Enthaler et al.   Energy & Environmental Science

Platinum Complex Catalyzed Decomposition of Formic Acid

(2010) Timo Paul Rieckborn et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

A hydrogen standard for future energy accounting?

(2010) Patrick Moriarty et al.   INTERNATIONAL JOURNAL OF HYDROGEN ENERGY

Unusually Large Tunneling Effect on Highly Efficient Generation of Hydrogen and Hydrogen Isotopes in pH-Selective Decomposition of Formic Acid Catalyzed by a Heterodinuclear Iridium−Ruthenium Complex in Water

(2010) Shunichi Fukuzumi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron-Catalyzed Hydrogen Production from Formic Acid

(2010) Albert Boddien et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Generation of Hydrogen from Formic acid and its Derivatives: Useful Hydrogen Storage Materials

(2010) Björn Loges et al.   TOPICS IN CATALYSIS

Continuous Hydrogen Generation from Formic Acid: Highly Active and Stable Ruthenium Catalysts

(2009) Albert Boddien et al.   ADVANCED SYNTHESIS & CATALYSIS

Hydrogen generation from formic acid and alcohols using homogeneous catalysts

(2009) Tarn C. Johnson et al.   CHEMICAL SOCIETY REVIEWS

Selective Formic Acid Decomposition for High-Pressure Hydrogen Generation: A Mechanistic Study

(2009) Céline Fellay et al.   CHEMISTRY-A EUROPEAN JOURNAL

Highly efficient hydrogen evolution by decomposition of formic acid using an iridium catalyst with 4,4′-dihydroxy-2,2′-bipyridine

(2009) Yuichiro Himeda   GREEN CHEMISTRY

Insights into Hydrogen Generation from Formic Acid Using Ruthenium Complexes

(2009) David J. Morris et al.   ORGANOMETALLICS

Improved hydrogen generation from formic acid

(2009) Henrik Junge et al.   TETRAHEDRON LETTERS

Controlled Generation of Hydrogen from Formic Acid Amine Adducts at Room Temperature and Application in H2/O2Fuel Cells

(2008) Björn Loges et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Viable Hydrogen-Storage System Based On Selective Formic Acid Decomposition with a Ruthenium Catalyst

(2008) Céline Fellay et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

High-quality hydrogen from the catalyzed decomposition of formic acid by Pd–Au/C and Pd–Ag/C

(2008) Xiaochun Zhou et al.   CHEMICAL COMMUNICATIONS

Hydrogen Generation at Ambient Conditions: Application in Fuel Cells

(2008) Albert Boddien et al.   ChemSusChem

Efficient Catalytic Decomposition of Formic Acid for the Selective Generation of H2and H/D Exchange with a Water-Soluble Rhodium Complex in Aqueous Solution

(2008) Shunichi Fukuzumi et al.   ChemSusChem

Bioinspired Energy Conversion Systems for Hydrogen Production and Storage

(2008) Shunichi Fukuzumi   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Hydrogen's role in an uncertain energy future

(2008) P MORIARTY et al.   INTERNATIONAL JOURNAL OF HYDROGEN ENERGY