New Syntheses and Properties of Some Axial and Helical Isomers of Organic Compounds

The rotameric (R*,S*)- and (R*,R*)-biaryl-3,3′-diphthalides of polyphenylene series

(2019) Tagir A. Yangirov et al.   TETRAHEDRON

Effective Synthetic Method and Rotameric Isomerization of 2,4-Dioxo-1,2,3,4-Tetrahydropyrimidine-5-Maleopimarate

(2018) I. M. Sakhautdinov et al.   CHEMISTRY OF NATURAL COMPOUNDS

Structure-based discovery of cytotoxic dimeric tetrahydroxanthones as potential topoisomerase I inhibitors from a marine-derived fungus

(2018) Guangwei Wu et al.   EUROPEAN JOURNAL OF MEDICINAL CHEMISTRY

2-Bromo[6]helicene as a Key Intermediate for [6]Helicene Functionalization

(2018) Martin Jakubec et al.   JOURNAL OF ORGANIC CHEMISTRY

Hexa-peri-hexabenzo[7]helicene: Homogeneously π-Extended Helicene as a Primary Substructure of Helically Twisted Chiral Graphenes

(2018) Yusuke Nakakuki et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Exocyclic Double Bond in Benzo-Fused Nitrogen Heterocycles: Methods of Introduction and Syntheses with Its Participation

(2018) R. R. Gataullin   RUSSIAN JOURNAL OF ORGANIC CHEMISTRY

Bioactive compounds from the scale insect fungus Conoideocrella tenuis BCC 44534

(2018) Siriporn Saepua et al.   TETRAHEDRON

Chan-Lam cross-coupling reaction based on the Cu 2 S/TMEDA system

(2018) Kateřina Janíková et al.   TETRAHEDRON

Catalyst-Controlled Stereoselective Synthesis of Atropisomers

(2018) Bouthayna Zilate et al.   ACS Catalysis

Bioactive carbazole and quinoline alkaloids from Clausena dunniana

(2018) Nankai Cao et al.   PHYTOCHEMISTRY

A Photoswitchable Heteroditopic Ion-Pair Receptor

(2018) Zoran Kokan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Carbo[6]helicene Derivatives Grafted with Amino or Aminoester Substituents from Enantiopure [6]Helicenyl Boronates

(2017) Nora Hellou et al.   JOURNAL OF ORGANIC CHEMISTRY

Laterally π-Extended Dithia[6]helicenes with Heptagons: Saddle-Helix Hybrid Molecules

(2017) Takao Fujikawa et al.   JOURNAL OF ORGANIC CHEMISTRY

Organocatalytic synthesis of axially chiral atropisomers

(2017) P. Renzi   ORGANIC & BIOMOLECULAR CHEMISTRY

Helically Chiral 1-Sulfur-Functionalized [6]Helicene: Synthesis, Optical Resolution, and Functionalization

(2017) Tetsuya Tsujihara et al.   ORGANIC LETTERS

Diastereoselective α-Alkylation of Metallo Enamines Generated from N–C Axially Chiral Mebroqualone Derivatives

(2017) Mizuki Matsuoka et al.   ORGANIC LETTERS

Configurational Stability of [5]Helicenes

(2017) Prince Ravat et al.   ORGANIC LETTERS

(α-Diimine)nickel Complexes That Contain Menthyl Substituents: Synthesis, Conformational Behavior, and Olefin Polymerization Catalysis

(2017) Feng Zhai et al.   ORGANOMETALLICS

Chlorin conjugates containing 2,6-diisobornylphenol fragments

(2017) D. V. Belykh et al.   RUSSIAN JOURNAL OF ORGANIC CHEMISTRY

Total Synthesis of (+)-Mintlactone and (–)-Isomintlactone via SmI2-Induced Radical Cyclization

(2017) Dian He et al.   SYNLETT

Synthesis of Unsymmetrical Aza[7]helicenes by One-Pot Wittig–Heck and Photodehydrogenation Sequence

(2017) Ashutosh Bedekar et al.   SYNLETT

5,6,7,8-Tetrahydronaphthalen-1-amine as Precursor for Thiazolidi­nones and Benzothiazepinones: Synthesis and Atropisomeric Relationship

(2017) Wilson Cunico et al.   SYNTHESIS-STUTTGART

Axially Chiral Shape-Persistent Encapsulating Agents

(2017) María Magdalena Cid et al.   SYNTHESIS-STUTTGART

Synthesis of Helical Quinone Derivatives by Oxidative Coupling of Substituted 2-Hydroxybenzo[c]phenanthrenes

(2017) Michinori Karikomi et al.   SYNTHESIS-STUTTGART

Michael Addition of Oxindoles to N-(2-tert-Butylphenyl)maleimides: Efficient Desymmetrization for the Synthesis of Atropisomeric Succinimides with Quaternary and Tertiary Stereocenters

(2017) Giorgio Bencivenni et al.   SYNTHESIS-STUTTGART

Reactivity of Grubbs–Hoveyda II Complexes Including Extended N-Heterocyclic Carbenes with a Bicyclic Camphor-Based Framework

(2017) René Wilhelm et al.   SYNTHESIS-STUTTGART

Synthesis, chiral resolution and optical properties of amphiphilic oxa[9]helicene derivatives

(2017) Mohammad Shahabuddin et al.   TETRAHEDRON LETTERS

Tale of Twisted Molecules. Atropselective Photoreactions: Taming Light Induced Asymmetric Transformations through Non-biaryl Atropisomers

(2016) Elango Kumarasamy et al.   ACCOUNTS OF CHEMICAL RESEARCH

Triptycene-Based Chiral Macrocyclic Hosts for Highly Enantioselective Recognition of Chiral Guests Containing a Trimethylamino Group

(2016) Geng-Wu Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The role of atropisomers on the photo-reactivity and fatigue of diarylethene-based metal–organic frameworks

(2016) Ian M. Walton et al.   NEW JOURNAL OF CHEMISTRY

Krishnadimer A, an Axially Chiral Non-biaryl Natural Product: Discovery and Biomimetic Synthesis

(2016) Wan Shan Li et al.   ORGANIC LETTERS

The Preorganization of Atropisomers to Increase Target Selectivity

(2016) Jeffrey Gustafson et al.   SYNLETT

Recent Advances in Bromination of Aromatic and Heteroaromatic Compounds

(2016) Leonid Voskressensky et al.   SYNTHESIS-STUTTGART

Enantioselective synthesis of N–C axially chiral indoles through chiral palladium-catalyzed 5-endo-hydroaminocyclization

(2016) Yudai Morimoto et al.   TETRAHEDRON

Isolation, resolution and biological evaluation of pestalachlorides E and F containing both point and axial chirality

(2016) Qian Xing et al.   RSC Advances

Aromatic Amide-Derived Non-Biaryl Atropisomers as Highly Efficient Ligands in Silver-Catalyzed Asymmetric Cycloaddition Reactions

(2015) Xing-Feng Bai et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nonbiaryl and Heterobiaryl Atropisomers: Molecular Templates with Promise for Atropselective Chemical Transformations

(2015) Elango Kumarasamy et al.   CHEMICAL REVIEWS

Synthesis and Atropisomerism of Cascaded Tetraphenylporphyrin-[60]Fullerene Hybrids

(2015) Sebastian Schlundt et al.   CHEMISTRY-A EUROPEAN JOURNAL

A twist of nature – the significance of atropisomers in biological systems

(2015) Jamie E. Smyth et al.   NATURAL PRODUCT REPORTS

Asymmetric synthesis of axially chiral anilides by Pd-catalyzed allylic substitutions with P/olefin ligands

(2015) Yilin Liu et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Stereoselective Synthesis of 1,4-Diols by a Tandem Allylboration–Allenylboration Sequence

(2015) Tony S. N. Zhao et al.   ORGANIC LETTERS

Isolation of Atropisomers of N-Benzoylated Pyrroles and Imidazoles

(2015) Hideyo Takahashi et al.   SYNTHESIS-STUTTGART

Synthesis, Properties, and Enantiomerization Behavior of Axially Chiral Phenolic Derivatives of 8-(Naphth-1-yl)quinoline and Comparison to 7,7′-Dihydroxy-8,8′-biquinolyl and 1,1′-Bi-2-naphthol

(2015) Paul Blakemore et al.   SYNTHESIS-STUTTGART

Recent applications of chiral allenes in axial-to-central chirality transfer reactions

(2015) Robynne K. Neff et al.   TETRAHEDRON

Racemization-free synthesis of atropisomeric 1-phenylpyrrole based diamines using diphenylphosphoryl azide

(2015) Ferenc Faigl et al.   TETRAHEDRON-ASYMMETRY

Asymmetric synthesis of heteroaryl atropisomers via a gold-catalyzed cycloisomerization–amination cascade reaction

(2014) Rui Guo et al.   CHEMICAL COMMUNICATIONS

Our Expedition in Eight-Membered Ring Compounds: From Planar Dehydrocyclooctenes to Tub-Shaped Chiral Tetraphenylenes

(2014) Jian-Wei Han et al.   CHEMICAL RECORD

Photochemistry of Atropisomers: Non-biaryl Atropisomers for Stereospecific Phototransformations

(2014) Anthony Clay et al.   CHEMISTRY LETTERS

Silicon-Based Bulky Group-Induced Remote Control and Conformational Preference in the Synthesis and Application of Isolable Atropisomeric Amides with Secondary Alcohol or Amine Moieties

(2014) Xing-Feng Bai et al.   Chemistry-An Asian Journal

Salvianolic acids T and U: A pair of atropisomeric trimeric caffeic acids derivatives from root of Salvia miltiorrhiza

(2014) Wei Li et al.   FITOTERAPIA

Benzo[a]azulenediones and 10,10′-Bibenzo[a]azulene

(2014) Rolf Sigrist et al.   HELVETICA CHIMICA ACTA

Antiviral Atropisomers: Conformational Energy Surfaces by NMR for Host-Directed Myxovirus Blockers

(2014) Craig Grimmer et al.   Journal of Chemical Information and Modeling

Chiral derivatives of 1,2-benzenedisulfonimide as efficient Brønsted acid catalysts in the Strecker reaction

(2014) Margherita Barbero et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

A Complete Gear System in N-Benzoyl-Carbazole Derivatives

(2014) Hidetsugu Tabata et al.   ORGANIC LETTERS

Asymmetric Synthesis of Atropisomeric Compounds with an N‒C Chiral Axis

(2014) Isao Takahashi et al.   ORGANIC PREPARATIONS AND PROCEDURES INTERNATIONAL

The Atropomer Composition of Iopromide as an Indicator for Assessment of the Quality of its Substance and Medincal Formulations

(2014) R. G. Glushkov* et al.   PHARMACEUTICAL CHEMISTRY JOURNAL

Asymmetric synthesis of host-directed inhibitors of myxoviruses

(2013) Terry W Moore et al.   Beilstein Journal of Organic Chemistry

Synthesis and antitumor activity evaluation of maleopimaric acid N-aryl imide atropisomers

(2013) Gui-yang Yao et al.   BIOORGANIC & MEDICINAL CHEMISTRY LETTERS

Intramolecular Paternò–Büchi reaction of atropisomeric α-oxoamides in solution and in the solid-state

(2013) Ramya Raghunathan et al.   CHEMICAL COMMUNICATIONS

Axial-to-central chirality transfer in cyclization processes

(2013) Damien Campolo et al.   CHEMICAL SOCIETY REVIEWS

Conformation and Atropisomeric Properties of Indometacin Derivatives

(2013) Shintaro Wakamatsu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Biological Stereoselectivity of Atropisomeric Natural Products and Drugs

(2013) Arie Zask et al.   CHIRALITY

Wilcox Molecular Torsion Balance with Rigid Side Arm and Separable Atropisomers for Investigating CH−π Interactions

(2013) Brijesh Bhayana   JOURNAL OF ORGANIC CHEMISTRY

Rotational Isomers of N-Methyl-N-arylacetamides and Their Derived Enolates: Implications for Asymmetric Hartwig Oxindole Cyclizations

(2013) Jérémie Mandel et al.   JOURNAL OF ORGANIC CHEMISTRY

Point-to-Axial Chirality Transfer—A New Probe for “Sensing” the Absolute Configurations of Monoamines

(2013) Mercy Anyika et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Protonation-controlled axial chirality in maleopimaric imides

(2013) Guiyang Yao et al.   NEW JOURNAL OF CHEMISTRY

Synthesis and reactions of N-acetyl- and N-(2-chloroacetyl)-N-[(2E)-1-methylbut-2-en-1-yl]-2-iodoanilines

(2013) D. A. Skladchikov et al.   RUSSIAN JOURNAL OF GENERAL CHEMISTRY

Synthesis of N-acetyl-3,3a,4,8b- and -1,3a,4,8b-tetrahydrocyclopenta[b]indoles from N- and 2-(cyclopent-2-en-1-yl)anilines

(2013) D. A. Skladchikov et al.   RUSSIAN JOURNAL OF ORGANIC CHEMISTRY

Synthesis, structure, and heck cyclization of the syn- and anti-atropisomers of N-acyl-N-(4-methyl-3,6-dihydro-2H-pyran-3-yl)-2-iodo-4,6-dimethylaniline

(2013) D. A. Skladchikov et al.   RUSSIAN JOURNAL OF ORGANIC CHEMISTRY

Marilines A-C: Novel Phthalimidines from the Sponge-Derived Fungus Stachylidium sp.

(2012) Celso Almeida et al.   CHEMISTRY-A EUROPEAN JOURNAL

Cover Picture: Atropisomerism in a Belt-Persistent Nanohoop Molecule: Rotational Restriction Forced by Macrocyclic Ring Strain (Chem. Asian J. 7/2012)

(2012) Shunpei Hitosugi et al.   Chemistry-An Asian Journal

Isocyanurates with Planar Chirality: Design, Optical Resolution, and Isomerization

(2012) Hidetoshi Goto et al.   CHIRALITY

Palladium-catalyzed reactions of halogen derivatives of N,N-dimethyl-1-phenylethanamine with arylboronic acids as a novel approach to the synthesis of biaryls with central and axial chirality

(2012) I. N. Shishkina et al.   DOKLADY CHEMISTRY

Axially Chiral Macrocyclic E-Alkene Bearing Bisazole Component Formed by Sequential C–H Homocoupling and Ring-Closing Metathesis

(2012) Shotaro Nishio et al.   ORGANIC LETTERS

Synthesis of 1-{4a,6-dimethyl-4a,9a-dihydropyrano-[3,4-b]indol-9(1H)-yl}ethanone

(2012) D. A. Skladchikov et al.   RUSSIAN JOURNAL OF ORGANIC CHEMISTRY

Discovery of atrop fixed alkoxy-aminobenzhydrol derivatives: Novel, highly potent and orally efficacious squalene synthase inhibitors

(2011) Masanori Ichikawa et al.   BIOORGANIC & MEDICINAL CHEMISTRY

Covalent locking and unlocking of an atropisomeric molecular switch

(2011) Yong S. Chong et al.   CHEMICAL COMMUNICATIONS

Stereochemical vocabulary for structures that are chiral but not asymmetric: History, analysis, and proposal for a rational terminology

(2011) Joseph Gal   CHIRALITY

Synthesis and Stereochemical Determination of Complestatin A and B (Neuroprotectin A and B)

(2011) Steven P. Breazzano et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly effective chiral phosphorus amidite–olefin ligands for palladium-catalyzed asymmetric allylic substitutions

(2011) Zhaoqun Liu et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Atropisomerism Observed in Indometacin Derivatives

(2011) Hideyo Takahashi et al.   ORGANIC LETTERS

Stereoisomerism in the series of isoindole-based quaternary salts

(2011) O. V. Gordienko et al.   RUSSIAN JOURNAL OF ORGANIC CHEMISTRY

Axial chirality of N,N′-disubstituted 3,4-ethylenedioxythiophene-2,5-dicarboxamides

(2011) Ivana Stolić et al.   STRUCTURAL CHEMISTRY

Bottom-up synthesis of finite models of helical (n,m)-single-wall carbon nanotubes

(2011) Shunpei Hitosugi et al.   Nature Communications

Dendronizing and Metalating trans-2 C60 Tetraaryl Porphyrins-A Versatile Approach Toward Water-Soluble Donor-Acceptor Conjugates

(2010) Michaela Ruppert et al.   CHEMISTRY-A EUROPEAN JOURNAL

Generation and amplification of optical activity of axially chiral N-(1-naphthyl)-2(1H)-pyrimidinethione by crystallization

(2010) Masami Sakamoto et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Atropisomeric small molecule Bcl-2 ligands: Determination of bioactive conformation

(2009) John Porter et al.   BIOORGANIC & MEDICINAL CHEMISTRY LETTERS

Atropisomerism of α,β-Unsaturated Amidines: Stereoselective Synthesis by Catalytic Cascade Reaction and Optical Resolution

(2009) Naoya Shindoh et al.   CHEMISTRY-A EUROPEAN JOURNAL

Molecular playdough: conformationally programmable molecular receptors based on restricted rotation

(2009) Roger D. Rasberry et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Transformations of the extra ring in pheophorbide a methyl ester in the reaction with N,N,N′,N′-tetramethylmethanediamine

(2009) D. V. Belykh et al.   RUSSIAN JOURNAL OF ORGANIC CHEMISTRY

Synthesis and evaluation of Apogossypol atropisomers as potential Bcl-xL antagonists

(2008) Jun Wei et al.   CANCER LETTERS

Stereostructural behaviour of N–N atropisomers: Two conglomerate crystallisations and a crystallisation-induced deracemisation

(2008) Richard J. Arthur et al.   CRYSTENGCOMM

N,N′-Diarylureas: A New Family of Atropisomers Exhibiting Highly Diastereoselective Reactivity

(2008) Jonathan Clayden et al.   JOURNAL OF ORGANIC CHEMISTRY

Oxidation kinetics of Zn-5,15 bis(ortho-methoxyphenyl)-2,3,7,8,12,13,17,18-octamethylporphyrin with organic peroxides in o-xylene

(2008) O. R. Simonova et al.   RUSSIAN JOURNAL OF GENERAL CHEMISTRY

3,3′-bis(dipyrrolylmethenes) as new chelating ligands: Synthesis and spectral properties

(2008) G. B. Guseva et al.   RUSSIAN JOURNAL OF GENERAL CHEMISTRY

Stereoselective synthesis of separable amide rotamers using π-allyl-Pd catalyst and their thermodynamic behavior

(2008) Nobutaka Ototake et al.   TETRAHEDRON LETTERS