How cations affect the electric double layer and the rates and selectivity of electrocatalytic processes

Exponential Scaling of Water Exchange Rates with Ion Interaction Strength from the Perspective of Dynamic Facilitation Theory

(2019) Richard C Remsing et al.   JOURNAL OF PHYSICAL CHEMISTRY A

Electrochemical CO Reduction: A property of the electrochemical interface

(2019) Alexander Bagger et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Fluorescent reconstitution on deposition of PM2.5 in lung and extrapulmonary organs

(2019) Donghai Li et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Toward an Atomic-Scale Understanding of Electrochemical Interface Structure and Dynamics

(2019) Olaf M. Magnussen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Probing Electric Double Layer Composition via in-Situ Vibrational Spectroscopy and Molecular Simulations

(2019) Jonathan H. Raberg et al.   Journal of Physical Chemistry Letters

Monovalent and Divalent Cations at the α-Al2O3(0001)/Water Interface: How Cation Identity Affects Interfacial Ordering and Vibrational Dynamics

(2019) Stefan M. Piontek et al.   Journal of Physical Chemistry C

Absence of diffuse double layer effect on the vibrational properties and oxidation of chemisorbed carbon monoxide on a Pt(111) electrode

(2018) Marta C. Figueiredo et al.   ELECTROCHIMICA ACTA

Elucidating Surface Restructuring-Induced Catalytic Reactivity of Cobalt Phosphide Nanoparticles under Electrochemical Conditions

(2018) Zishan Wu et al.   Journal of Physical Chemistry C

Effect of Halide Anions on the Structure and Dynamics of Water Next to an Alumina (0001) Surface

(2018) Aashish Tuladhar et al.   Journal of Physical Chemistry C

Layering and Ordering in Electrochemical Double Layers

(2018) Yihua Liu et al.   Journal of Physical Chemistry Letters

Quaternary Ammonium Cation Specific Adsorption on Platinum Electrodes: A Combined Experimental and Density Functional Theory Study

(2018) I. T. McCrum et al.   JOURNAL OF THE ELECTROCHEMICAL SOCIETY

Correlation of surface site formation to nanoisland growth in the electrochemical roughening of Pt(111)

(2018) Leon Jacobse et al.   NATURE MATERIALS

Analysis of the conformational properties of amine ligands at the gold/water interface with QM, MM and QM/MM simulations

(2018) Dongyue Liang et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Elucidating the Roles of Electric Fields in Catalysis: A Perspective

(2018) Fanglin Che et al.   ACS Catalysis

Alkali Metal Cation Effects in Structuring Pt, Rh, and Au Surfaces through Cathodic Corrosion

(2018) Thomas J. P. Hersbach et al.   ACS Applied Materials & Interfaces

Effect of Particle Shape and Electrolyte Cation on CO Adsorption to Copper Oxide Nanoparticle Electrocatalysts

(2018) Matthew M. Sartin et al.   Journal of Physical Chemistry C

CO2 Reduction Catalysts on Gold Electrode Surfaces Influenced by Large Electric Fields

(2018) Melissa L. Clark et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cation-dependent restructure of the electric double layer on CO-covered Pt electrodes: Difference between hydrophilic and hydrophobic cations

(2017) Akira Yamakata et al.   JOURNAL OF ELECTROANALYTICAL CHEMISTRY

Interfacial Structure and Electric Field Probed by in Situ Electrochemical Vibrational Stark Effect Spectroscopy and Computational Modeling

(2017) Aimin Ge et al.   Journal of Physical Chemistry C

Direct Spectroscopic Measurement of Interfacial Electric Fields near an Electrode under Polarizing or Current-Carrying Conditions

(2017) Joel G. Patrow et al.   Journal of Physical Chemistry C

Spectroscopic Observation of Reversible Surface Reconstruction of Copper Electrodes under CO2 Reduction

(2017) Charuni M. Gunathunge et al.   Journal of Physical Chemistry C

Electrochemical Capacitance of CO-Terminated Pt(111) Dominated by the CO–Solvent Gap

(2017) Ravishankar Sundararaman et al.   Journal of Physical Chemistry Letters

Ultrasensitivity of Water Exchange Kinetics to the Size of Metal Ion

(2017) Yuno Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Solvation Reaction Field at the Interface Measured by Vibrational Sum Frequency Generation Spectroscopy

(2017) Shayne A. Sorenson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Structure- and Potential-Dependent Cation Effects on CO Reduction at Copper Single-Crystal Electrodes

(2017) Elena Pérez-Gallent et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Promoter Effects of Alkali Metal Cations on the Electrochemical Reduction of Carbon Dioxide

(2017) Joaquin Resasco et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Understanding the Influence of [EMIM]Cl on the Suppression of the Hydrogen Evolution Reaction on Transition Metal Electrodes

(2017) Jeremy T. Feaster et al.   LANGMUIR

Orientational ordering of water in extended hydration shells of cations is ion-specific and is correlated directly with viscosity and hydration free energy

(2017) Yixing Chen et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Probing promoting effects of alkali cations on the reduction of CO at the aqueous electrolyte/copper interface

(2017) Charuni M. Gunathunge et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Surface enhanced spectroscopic investigations of adsorption of cations on electrochemical interfaces

(2017) M. Dunwell et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Microscopic dynamics of charge separation at the aqueous electrochemical interface

(2017) John A. Kattirtzi et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Improved CO2 Electroreduction Performance on Plasma-Activated Cu Catalysts via Electrolyte Design: Halide Effect

(2017) Dunfeng Gao et al.   ACS Catalysis

Nanoporous Copper Films by Additive-Controlled Electrodeposition: CO2 Reduction Catalysis

(2017) Thao T. H. Hoang et al.   ACS Catalysis

Interfacial water reorganization as a pH-dependent descriptor of the hydrogen evolution rate on platinum electrodes

(2017) Isis Ledezma-Yanez et al.   Nature Energy

Double layer effects in electrocatalysis: The oxygen reduction reaction and ethanol oxidation reaction on Au(1 1 1), Pt(1 1 1) and Ir(1 1 1) in alkaline media containing Na and Li cations

(2016) Pietro P. Lopes et al.   CATALYSIS TODAY

New Information on the Ion-Identity-Dependent Structure of Stern Layer Revealed by Sum Frequency Generation Vibrational Spectroscopy

(2016) Kaitlin A. Lovering et al.   Journal of Physical Chemistry C

Cation–Hydroxide–Water Coadsorption Inhibits the Alkaline Hydrogen Oxidation Reaction

(2016) Hoon Taek Chung et al.   Journal of Physical Chemistry Letters

The Formation Time of Ti–O• and Ti–O•–Ti Radicals at the n-SrTiO3/Aqueous Interface during Photocatalytic Water Oxidation

(2016) Xihan Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydrolysis of Electrolyte Cations Enhances the Electrochemical Reduction of CO2 over Ag and Cu

(2016) Meenesh R. Singh et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The Impact of Specifically Adsorbed Ions on the Copper-Catalyzed Electroreduction of CO2

(2016) Sneha A. Akhade et al.   JOURNAL OF THE ELECTROCHEMICAL SOCIETY

Enhanced electrocatalytic CO2 reduction via field-induced reagent concentration

(2016) Min Liu et al.   NATURE

Terahertz echoes reveal the inhomogeneity of aqueous salt solutions

(2016) Andrey Shalit et al.   Nature Chemistry

A surface-enhanced infrared absorption spectroscopic study of pH dependent water adsorption on Au

(2016) Marco Dunwell et al.   SURFACE SCIENCE

Unravelling the electrochemical double layer by direct probing of the solid/liquid interface

(2016) Marco Favaro et al.   Nature Communications

Tuning the Catalytic Activity and Selectivity of Cu for CO2 Electroreduction in the Presence of Halides

(2016) Ana Sofia Varela et al.   ACS Catalysis

Electric Field Effects in Electrochemical CO2 Reduction

(2016) Leanne D. Chen et al.   ACS Catalysis

First Principles Simulations of Cyclic Voltammograms on Stepped Pt(553) and Pt(533) Electrode Surfaces

(2016) Ian T. McCrum et al.   ChemElectroChem

High Selectivity for Ethylene from Carbon Dioxide Reduction over Copper Nanocube Electrocatalysts

(2015) F. Sloan Roberts et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The role of non-covalent interactions on CO bulk oxidation on Pt single crystal electrodes in alkaline electrolytes

(2015) Kensaku Kodama et al.   ELECTROCHIMICA ACTA

Theoretical Study of EMIM+ Adsorption on Silver Electrode Surfaces

(2015) Makoto Urushihara et al.   Journal of Physical Chemistry C

pH and Alkali Cation Effects on the Pt Cyclic Voltammogram Explained Using Density Functional Theory

(2015) Ian T. McCrum et al.   Journal of Physical Chemistry C

Frustrated Solvation Structures Can Enhance Electron Transfer Rates

(2015) Richard C. Remsing et al.   Journal of Physical Chemistry Letters

Effects of electrolyte, catalyst, and membrane composition and operating conditions on the performance of solar-driven electrochemical reduction of carbon dioxide

(2015) Meenesh R. Singh et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Influence of beryllium cations on the electrochemical oxidation of methanol on stepped platinum surfaces in alkaline solution

(2015) Gonzalo García et al.   SURFACE SCIENCE

The electric double layer at a rutile TiO2water interface modelled using density functional theory based molecular dynamics simulation

(2014) J Cheng et al.   JOURNAL OF PHYSICS-CONDENSED MATTER

Counterion Effect on Interfacial Water at Charged Interfaces and Its Relevance to the Hofmeister Series

(2014) Satoshi Nihonyanagi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The Evolution of the Polycrystalline Copper Surface, First to Cu(111) and Then to Cu(100), at a Fixed CO2RR Potential: A Study by Operando EC-STM

(2014) Youn-Geun Kim et al.   LANGMUIR

Structure of Water at Charged Interfaces: A Molecular Dynamics Study

(2014) Shalaka Dewan et al.   LANGMUIR

Alkali cation specific adsorption onto fcc(111) transition metal electrodes

(2014) J. N. Mills et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

The structure of interfacial water on gold electrodes studied by x-ray absorption spectroscopy

(2014) J.-J. Velasco-Velez et al.   SCIENCE

Extreme electric fields power catalysis in the active site of ketosteroid isomerase

(2014) Stephen D. Fried et al.   SCIENCE

The effect of the alkali metal cation on the electrocatalytic oxidation of formate on platinum

(2014) Bruno A. F. Previdello et al.   RSC Advances

Direct observation of ionic structure at solid-liquid interfaces: a deep look into the Stern Layer

(2014) Igor Siretanu et al.   Scientific Reports

Hydration structure of salt solutions from ab initio molecular dynamics

(2013) Arindam Bankura et al.   JOURNAL OF CHEMICAL PHYSICS

Experimental Correlation Between Interfacial Water Structure and Mineral Reactivity

(2013) Shalaka Dewan et al.   Journal of Physical Chemistry Letters

Real-Time Observation of the Destruction of Hydration Shells under Electrochemical Force

(2013) Akira Yamakata et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydration of metal surfaces can be dynamically heterogeneous and hydrophobic

(2013) David T. Limmer et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Theory of multiple proton–electron transfer reactions and its implications for electrocatalysis

(2013) Marc T. M. Koper   Chemical Science

Water dissociation on well-defined platinum surfaces: The electrochemical perspective

(2012) Maria J.T.C. van der Niet et al.   CATALYSIS TODAY

Structure of water layers on hydrogen-covered Pt electrodes

(2012) Tanglaw Roman et al.   CATALYSIS TODAY

The influence of non-covalent interactions on the hydrogen peroxide electrochemistry on platinum in alkaline electrolytes

(2012) Ioannis Katsounaros et al.   CHEMICAL COMMUNICATIONS

The Solvation Structure of Na+ and K+ in Liquid Water Determined from High Level ab Initio Molecular Dynamics Simulations

(2012) Christopher N. Rowley et al.   Journal of Chemical Theory and Computation

Competitive Anion/Water and Cation/Water Interactions at Electrified Copper/Electrolyte Interfaces Probed by in Situ X-ray Diffraction

(2012) Hubert Keller et al.   Journal of Physical Chemistry C

The Effects of Hofmeister Cations at Negatively Charged Hydrophilic Surfaces

(2012) Sarah C. Flores et al.   Journal of Physical Chemistry C

Hydrogen Bonding and OH-Stretch Spectroscopy in Water: Hexamer (Cage), Liquid Surface, Liquid, and Ice

(2012) C. J. Tainter et al.   Journal of Physical Chemistry Letters

Effect of Cations on the Electrochemical Conversion of CO2to CO

(2012) Michael R. Thorson et al.   JOURNAL OF THE ELECTROCHEMICAL SOCIETY

The Effect of Noncovalent Interactions on the HOR, ORR, and HER on Ru, Ir, and Ru0.50Ir0.50 Metal Surfaces in Alkaline Environments

(2012) N. Danilovic et al.   Electrocatalysis

Cathodic Corrosion: A Quick, Clean, and Versatile Method for the Synthesis of Metallic Nanoparticles

(2011) Alexei I. Yanson et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The impact of the alkali cation on the mechanism of the electro-oxidation of ethylene glycol on Pt

(2011) Elton Sitta et al.   CHEMICAL COMMUNICATIONS

Outer Helmholtz Plane of the Electrical Double Layer Formed at the Solid Electrode-Liquid Interface

(2011) Masashi Nakamura et al.   CHEMPHYSCHEM

The structure of the electrochemical double layer: Ag(111) in alkaline electrolyte

(2011) Christopher A. Lucas et al.   ELECTROCHEMISTRY COMMUNICATIONS

A Study of the Hydration of the Alkali Metal Ions in Aqueous Solution

(2011) Johan Mähler et al.   INORGANIC CHEMISTRY

Effects of Li+, K+, and Ba2+ Cations on the ORR at Model and High Surface Area Pt and Au Surfaces in Alkaline Solutions

(2011) D. Strmcnik et al.   Journal of Physical Chemistry Letters

Structure of the electrical double layer on Ag(100): Promotive effect of cationic species on Br adlayer formation

(2011) Masashi Nakamura et al.   PHYSICAL REVIEW B

Enhancing Hydrogen Evolution Activity in Water Splitting by Tailoring Li+-Ni(OH)2-Pt Interfaces

(2011) R. Subbaraman et al.   SCIENCE

First-principles study of the water structure on flat and stepped gold surfaces

(2011) Xiaohang Lin et al.   SURFACE SCIENCE

Characterization of Water Structure on Silver Electrode Surfaces by SERS with Two-Dimensional Correlation Spectroscopy

(2010) Renato C. Ambrosio et al.   ANALYTICAL CHEMISTRY

Simulating Monovalent and Divalent Ions in Aqueous Solution Using a Drude Polarizable Force Field

(2010) Haibo Yu et al.   Journal of Chemical Theory and Computation

Promotion of the Oxidation of Carbon Monoxide at Stepped Platinum Single-Crystal Electrodes in Alkaline Media by Lithium and Beryllium Cations

(2010) Chantal Stoffelsma et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Water Hydrogen Bond Structure near Highly Charged Interfaces Is Not Like Ice

(2010) Satoshi Nihonyanagi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enhanced electrocatalysis of the oxygen reduction reaction based on patterning of platinum surfaces with cyanide

(2010) Dusan Strmcnik et al.   Nature Chemistry

Thermodynamic evidence for K+–SO42− ion pair formation on Pt(111). New insight into cation specific adsorption

(2010) Nuria Garcia-Araez et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Hydrated metal ions in aqueous solution: How regular are their structures?

(2010) Ingmar Persson   PURE AND APPLIED CHEMISTRY

Cooperativity in Ion Hydration

(2010) K. J. Tielrooij et al.   SCIENCE

Effect of Ions on the Structure of Water: Structure Making and Breaking

(2009) Yizhak Marcus   CHEMICAL REVIEWS

Water Structure at the Air−Aqueous Interface of Divalent Cation and Nitrate Solutions†

(2009) Man Xu et al.   JOURNAL OF PHYSICAL CHEMISTRY B

Structures of Water Molecules at the Interfaces of Aqueous Salt Solutions and Silica: Cation Effects

(2009) Zheng Yang et al.   Journal of Physical Chemistry C

Reconstruction of Cu(100) Electrode Surfaces during Hydrogen Evolution

(2009) Hisayoshi Matsushima et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The role of non-covalent interactions in electrocatalytic fuel-cell reactions on platinum

(2009) D. Strmcnik et al.   Nature Chemistry

Structural Dynamics of Aqueous Salt Solutions

(2008) H. J. Bakker   CHEMICAL REVIEWS

Vibrational Response of Hydrogen-Bonded Interfacial Water is Dominated by Intramolecular Coupling

(2008) Maria Sovago et al.   PHYSICAL REVIEW LETTERS