Palladium-Borane Cooperation: Evidence for an Anionic Pathway and Its Application to Catalytic Hydro-/Deutero-dechlorination

Rhodium Complexes Bearing PAlP Pincer Ligands

(2018) Naofumi Hara et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

General and Practical Potassium Methoxide/Disilane-Mediated Dehalogenative Deuteration of (Hetero)Arylhalides

(2018) Xin Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Selective ortho C–H Activation of Pyridines Directed by Lewis Acidic Boron of PBP Pincer Iridium Complexes

(2017) Wei-Chun Shih et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stable Dihydrogen Complexes of Cobalt(−I) Suggest an Inverse trans-Influence of Lewis Acidic Group 13 Metalloligands

(2017) Matthew V. Vollmer et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Unmasking the Catalytic Activity of a Platinum Complex with a Lewis Acidic, Non-innocent Antimony Ligand

(2017) Di You et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis, Structure, and Catalysis of Palladium Complexes Bearing a Group 13 Metalloligand: Remarkable Effect of an Aluminum-Metalloligand in Hydrosilylation of CO2

(2017) Jun Takaya et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Aluminabenzene–Rh and −Ir Complexes: Synthesis, Structure, and Application toward Catalytic C–H Borylation

(2017) Taichi Nakamura et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

T-Shaped Gold→Stiborane Complexes as Carbophilic Catalysts: Influence of the Peripheral Substituents

(2017) Srobona Sen et al.   ORGANOMETALLICS

Coordination- and Redox-Noninnocent Behavior of Ambiphilic Ligands Containing Antimony

(2016) J. Stuart Jones et al.   ACCOUNTS OF CHEMICAL RESEARCH

A T-shape diphosphinoborane palladium(0) complex

(2016) Patrick Steinhoff et al.   Beilstein Journal of Organic Chemistry

Functional group migrations between boron and metal centres within transition metal–borane and –boryl complexes and cleavage of H–H, E–H and E–E′ bonds

(2016) Gareth R. Owen   CHEMICAL COMMUNICATIONS

Cooperative Catalysis of Combined Systems of Transition-Metal Complexes with Lewis Acids: Theoretical Understanding

(2016) Wei Guan et al.   CHEMICAL RECORD

Main Group Lewis Acid-Mediated Transformations of Transition-Metal Hydride Complexes

(2016) Ayan Maity et al.   CHEMICAL REVIEWS

Complexes of ambiphilic ligands: reactivity and catalytic applications

(2016) Ghenwa Bouhadir et al.   CHEMICAL SOCIETY REVIEWS

Activation of an Au−Cl Bond by a Pendent SbIIILewis Acid: Impact on Structure and Catalytic Activity

(2016) J. Stuart Jones et al.   CHEMISTRY-A EUROPEAN JOURNAL

Deuterodechlorination of Aryl/Heteroaryl Chlorides Catalyzed by a Palladium/Unsymmetrical NHC System

(2016) Masami Kuriyama et al.   JOURNAL OF ORGANIC CHEMISTRY

A Significant but Constrained Geometry Pt→Al Interaction: Fixation of CO2 and CS2, Activation of H2 and PhCONH2

(2016) Marc Devillard et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Alkali Metal Hydridotriphenylborates [(L)M][HBPh3] (M = Li, Na, K): Chemoselective Catalysts for Carbonyl and CO2 Hydroboration

(2016) Debabrata Mukherjee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Deuterated drugs draw heavier backing

(2016) Asher Mullard   NATURE REVIEWS DRUG DISCOVERY

Catalytic selective deuteration of halo(hetero)arenes

(2016) Manojkumar Janni et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

General H2 Activation Modes for Lewis Acid–Transition Metal Bifunctional Catalysts

(2016) Yinwu Li et al.   ACS Catalysis

Activation of a Hydroamination Gold Catalyst by Oxidation of a Redox-Noninnocent Chlorostibine Z-Ligand

(2015) Haifeng Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Evidence for the Formation of Anionic Zerovalent Group 10 Complexes as Highly Reactive Intermediates

(2015) Alexander Seyboldt et al.   ORGANOMETALLICS

Synthesis and Reactivity of Palladium Complexes Featuring a Diphosphinoborane Ligand

(2015) Tobias Schindler et al.   ORGANOMETALLICS

Cooperation between Transition Metals and Lewis Acids: A Way To Activate H2and HE bonds

(2014) Marc Devillard et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Air-Stable Cationic Gold(I) Catalyst Featuring a Z-Type Ligand: Promoting Enyne Cyclizations

(2014) Fuyuhiko Inagaki et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Novel zwitterionic complexes arising from the coordination of an ambiphilic phosphorus–aluminum ligand to gold

(2014) Marc Devillard et al.   CHEMICAL COMMUNICATIONS

Platinum Complexes of a Borane-Appended Analogue of 1,1′-Bis(diphenylphosphino)ferrocene: Flexible Borane Coordination Modes and in situ Vinylborane Formation

(2014) Bradley E. Cowie et al.   CHEMISTRY-A EUROPEAN JOURNAL

Cooperative Transition Metal/Lewis Acid Bond-Activation Reactions by a Bidentate (Boryl)iminomethane Complex: A Significant Metal–Borane Interaction Promoted by a Small Bite-Angle LZ Chelate

(2014) Brandon R. Barnett et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A d10Ni-(H2) Adduct as an Intermediate in HH Oxidative Addition across a NiB Bond

(2013) W. Hill Harman et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent Developments in the Coordination Chemistry of Multidentate Ligands Featuring a Boron Moiety

(2013) Hajime Kameo et al.   Chemistry-An Asian Journal

Using Deuterium in Drug Discovery: Leaving the Label in the Drug

(2013) Thomas G. Gant   JOURNAL OF MEDICINAL CHEMISTRY

Catalytic conversion of nitrogen to ammonia by an iron model complex

(2013) John S. Anderson et al.   NATURE

Heterolytic H2 Cleavage and Catalytic Hydrogenation by an Iron Metallaboratrane

(2013) Henry Fong et al.   ORGANOMETALLICS

Facile Si–H bond activation and hydrosilylation catalysis mediated by a nickel–borane complex

(2013) Samantha N. MacMillan et al.   Chemical Science

Hydrogen atom storage upon Z-class borane ligand functions: an alternative approach to ligand cooperation

(2012) Gareth R. Owen   CHEMICAL SOCIETY REVIEWS

Reversible H2 Addition across a Nickel–Borane Unit as a Promising Strategy for Catalysis

(2012) W. Hill Harman et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Rhodaboratranes Bearing Phosphine-Tethered Boranes: Evaluation of the Metal–Boron Interaction

(2012) Hajime Kameo et al.   ORGANOMETALLICS

Synthesis of a Rhodium Complex Featuring the Rh–H–B Linkage via a Hydride Migration from Rhodium to Borane: Study on the Electronic Deviation Induced by the Presence of the Boron Moiety

(2012) Hajime Kameo et al.   ORGANOMETALLICS

Acyclic boron-containing π-ligand complexes: η2- and η3-coordination modes

(2011) David J. H. Emslie et al.   DALTON TRANSACTIONS

Metal–Alane Adducts with Zero-Valent Nickel, Cobalt, and Iron

(2011) P. Alex Rudd et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

N2Functionalization at Iron Metallaboratranes

(2011) Marc-Etienne Moret et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

σ-Acceptor, Z-type ligands for transition metals

(2010) Abderrahmane Amgoune et al.   CHEMICAL COMMUNICATIONS

Double addition of H2to transition metal–borane complexes: a ‘hydride shuttle’ process between boron and transition metal centres

(2010) Nikolaos Tsoureas et al.   CHEMICAL COMMUNICATIONS

Electron-Precise Coordination Modes of Boron-Centered Ligands

(2010) Holger Braunschweig et al.   CHEMICAL REVIEWS

Homogeneous CO Hydrogenation: Dihydrogen Activation Involves a Frustrated Lewis Pair Instead of a Platinum Complex

(2010) Alexander J. M. Miller et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper(I) Complexes derived from Mono- and Diphosphino-Boranes: Cu→B Interactions Supported by Arene Coordination

(2009) M. Sircoglou et al.   INORGANIC CHEMISTRY

Multidentate ligand systems featuring dual functionality

(2008) Istemi Kuzu et al.   DALTON TRANSACTIONS

Covalent radii revisited

(2008) Beatriz Cordero et al.   DALTON TRANSACTIONS

Coordination Chemistry of Neutral (Ln)-Z Amphoteric and Ambiphilic Ligands

(2008) Frédéric-Georges Fontaine et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Unlocking the metallaboratrane cage: reversible B–H activation in platinaboratranes

(2007) Ian R. Crossley et al.   DALTON TRANSACTIONS