Lewis Acid Catalyzed Transfer Hydromethallylation for the Construction of Quaternary Carbon Centers

Quaternary Centers via Ni-Catalyzed Cross-Coupling of Tertiary Carboxylic Acids and Aryl Zinc Reagents

(2019) Phil S. Baran et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Transfer Hydrocyanation of α- and α,β-Substituted Styrenes Catalyzed by Boron Lewis Acids

(2019) Patrizio Orecchia et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Hydroalkylation of Olefins To Form Quaternary Carbons

(2019) Samantha A. Green et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

(CDC)-Rhodium-Catalyzed Hydroallylation of Vinylarenes and 1,3-Dienes with Allyl Trifluoroborates.

(2019) Justin S. Marcum et al.   ACS Catalysis

Organic synthesis provides opportunities to transform drug discovery

(2018) David C. Blakemore et al.   Nature Chemistry

Fe(III)-Catalyzed Hydroallylation of Unactivated Alkenes with Morita–Baylis–Hillman Adducts

(2018) Jifeng Qi et al.   ORGANIC LETTERS

B(C6F5)3: Catalyst or Initiator? Insights from Computational Studies into Surrogate Silicon Chemistry

(2018) Subhrashis Banerjee et al.   ACS Catalysis

Iron–Nickel Dual-Catalysis: A New Engine for Olefin Functionalization and the Formation of Quaternary Centers

(2018) Samantha A. Green et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Quaternary stereocentres via an enantioconvergent catalytic SN1 reaction

(2018) Alison E. Wendlandt et al.   NATURE

Catalytic Stereoselective SN 1-Type Reactions Promoted by Chiral Phosphoric Acids as Brønsted Acid Catalysts

(2018) Andrea Gualandi et al.   Asian Journal of Organic Chemistry

Forging C(sp3)–C(sp3) Bonds with Carbon-Centered Radicals in the Synthesis of Complex Molecules

(2018) Spencer P. Pitre et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metal-Free Transfer Hydroiodination of C–C Multiple Bonds

(2018) Weiqiang Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Zn-Mediated Fragmentation of Tertiary Alkyl Oxalates Enabling Formation of Alkylated and Arylated Quaternary Carbon Centers

(2018) Yang Ye et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic enantioconvergent coupling of secondary and tertiary electrophiles with olefins

(2018) Zhaobin Wang et al.   NATURE

Chromium-catalyzed para-selective formation of quaternary carbon centers by alkylation of benzamide derivatives

(2018) Pei Liu et al.   Nature Communications

Tris(pentafluorophenyl)borane and Beyond: Modern Advances in Borylation Chemistry

(2017) James R. Lawson et al.   INORGANIC CHEMISTRY

Enabling the Cross-Coupling of Tertiary Organoboron Nucleophiles through Radical-Mediated Alkyl Transfer

(2017) David N. Primer et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Transition metal–catalyzed alkyl-alkyl bond formation: Another dimension in cross-coupling chemistry

(2017) Junwon Choi et al.   SCIENCE

Direct allylation of benzyl alcohols, diarylmethanols, and triarylmethanols mediated by XtalFluor-E

(2017) Thomas Lebleu et al.   TETRAHEDRON LETTERS

Cyclohexa-1,4-dienes in transition-metal-free ionic transfer processes

(2017) Sebastian Keess et al.   Chemical Science

Nickel-Catalyzed Barton Decarboxylation and Giese Reactions: A Practical Take on Classic Transforms

(2016) Tian Qin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The catalytic enantioselective synthesis of tetrahydroquinolines containing all-carbon quaternary stereocenters via the formation of aza-ortho-xylylene with 1,2-dihydroquinoline as a precursor

(2016) Guangxun Li et al.   CHEMICAL COMMUNICATIONS

The Propargyl Rearrangement to Functionalised Allyl-Boron and Borocation Compounds

(2016) Lewis C. Wilkins et al.   CHEMISTRY-A EUROPEAN JOURNAL

3-tert -Butyl-Substituted Cyclohexa-1,4-dienes as Isobutane Equivalents in the B(C6 F5 )3 -Catalyzed Transfer Hydro-tert -Butylation of Alkenes

(2016) Sebastian Keess et al.   CHEMISTRY-A EUROPEAN JOURNAL

Stereospecific Cross Couplings To Set Benzylic, All-Carbon Quaternary Stereocenters in High Enantiopurity

(2016) Qi Zhou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Transfer Hydrosilylation

(2015) Martin Oestreich   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

B(C6F5)3-Catalyzed Transfer of Dihydrogen from One Unsaturated Hydrocarbon to Another

(2015) Indranil Chatterjee et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cobalt-Catalyzed Allylation of Heterobicyclic Alkenes: Ligand-Induced Divergent Reactivities

(2015) Yuan Huang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A unified survey of Si–H and H–H bond activation catalysed by electron-deficient boranes

(2015) Martin Oestreich et al.   CHEMICAL SOCIETY REVIEWS

Nickel-Catalyzed Reductive Coupling of Aryl Bromides with Tertiary Alkyl Halides

(2015) Xuan Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Formal SiH4 chemistry using stable and easy-to-handle surrogates

(2015) Antoine Simonneau et al.   Nature Chemistry

PhI(OCOCF3)2-catalyzed nucleophilic substitution of aromatic propargyl alcohols

(2015) Shiue-Shien Weng et al.   TETRAHEDRON

A Mild Lewis-Acid-Catalyzed Method for Head-to-Tail Dimerization or Cyclization oftert-Alcohols

(2015) Bokka Venkat Ramulu et al.   Asian Journal of Organic Chemistry

Catalytic enantioselective synthesis of quaternary carbon stereocentres

(2014) Kyle W. Quasdorf et al.   NATURE

Catalytic functionalization of tertiary alcohols to fully substituted carbon centres

(2014) Long Chen et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

3-Silylated Cyclohexa-1,4-dienes as Precursors for Gaseous Hydrosilanes: The B(C6F5)3-Catalyzed Transfer Hydrosilylation of Alkenes

(2013) Antoine Simonneau et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Contemporary Carbocation Chemistry: Applications in Organic Synthesis

(2013) Rajasekhar Reddy Naredla et al.   CHEMICAL REVIEWS

Nickel-Catalyzed Carbon–Carbon Bond-Forming Reactions of Unactivated Tertiary Alkyl Halides: Suzuki Arylations

(2013) Susan L. Zultanski et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Activation of Alkynes with B(C6F5)3 – Boron Allylation Reagents Derived from Propargyl Esters

(2013) Max M. Hansmann et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

CH Activation of Isobutylene Using Frustrated Lewis Pairs: Aluminum and Boron σ-Allyl Complexes

(2012) Gabriel Ménard et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis and preliminary biological study of bisindolylmethanes accessed by an acid-catalyzed hydroarylation of vinyl indoles

(2012) Tejas P. Pathak et al.   TETRAHEDRON

Superacid-catalyzed Friedel–Crafts cyclization of unactivated alkenes

(2012) Sara A. Bonderoff et al.   TETRAHEDRON LETTERS

Nickel-Catalyzed Cross-Coupling of Aryl Bromides with Tertiary Grignard Reagents Utilizing Donor-Functionalized N-Heterocyclic Carbenes (NHCs)

(2011) Claudia Lohre et al.   CHEMISTRY-A EUROPEAN JOURNAL

Enantioselective Construction of All-Carbon Quaternary Centers by Branch-Selective Pd-Catalyzed Allyl–Allyl Cross-Coupling

(2011) Ping Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Kumada Cross-Coupling Reactions of Tertiary Alkylmagnesium Halides and Aryl Bromides/Triflates

(2011) Amruta Joshi-Pangu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Simple and Efficient Metal-free Hydroarylation and Hydroalkylation Using Strongly Acidic Ion-exchange Resin

(2008) Biswanath Das et al.   CHEMISTRY LETTERS