Defluorinative C(sp 3 )−P Bond Construction for the Synthesis of Phosphorylation gem ‐Difluoroalkenes under Catalyst‐ and Oxidant‐Free Conditions

Photoredox Defluorinative Alkylation of 1‐Trifluoromethyl Alkenes and 1,3‐Butadienes with 1,4‐Dihydropyridines as Alkylation Reagents

(2019) Haoguo Chen et al.   Asian Journal of Organic Chemistry

Transition Metal-Mediated and -Catalyzed C-F Bond Activation via Fluorine Elimination

(2018) Takeshi Fujita et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Picking one out of three: selective single C-F activation in trifluoromethyl groups

(2018) Florian Jaroschik   CHEMISTRY-A EUROPEAN JOURNAL

Silver-Catalyzed Radical Arylphosphorylation of Unactivated Alkenes: Synthesis of 3-Phosphonoalkyl Indolines

(2018) Deqiang Liang et al.   JOURNAL OF ORGANIC CHEMISTRY

Cobalt-Catalyzed Oxidative C(sp3)–H Phosphonylation for α-Aminophosphonates via C(sp3)–H/P(O)–H Coupling

(2018) Binzhou Lin et al.   JOURNAL OF ORGANIC CHEMISTRY

Enantioselective Copper-Catalyzed Defluoroalkylation Using Arylboronate-Activated Alkyl Grignard Reagents

(2018) Minyan Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Redox-Neutral Photocatalytic Cyclopropanation via Radical/Polar Crossover

(2018) James P. Phelan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Eosin Y-catalyzed, visible-light-promoted carbophosphinylation of allylic alcohols via a radical neophyl rearrangement

(2018) Yao Yin et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Visible-light-induced tandem phosphorylation cyclization of vinyl azides under mild conditions

(2018) Yonghong Li et al.   Organic Chemistry Frontiers

Cu-Catalyzed tertiary alkylation of α-(trifluoromethyl)styrenes with tertiary alkylmagnesium reagents

(2018) Wenpeng Dai et al.   Organic Chemistry Frontiers

Visible Light-Mediated Trifluoromethylation of Fluorinated Alkenes via C−F Bond Cleavage

(2018) Liu-Hai Wu et al.   ADVANCED SYNTHESIS & CATALYSIS

Activation of C–F bonds α to C–C multiple bonds

(2018) Jean-Denys Hamel et al.   CHEMICAL COMMUNICATIONS

Synthesis of gem-Difluoroalkenes via Nickel-Catalyzed Allylic Defluorinative Reductive Cross-Coupling

(2018) Yun Lan et al.   ACS Catalysis

A photocatalytic decarboxylative/defluorinative [4+3] annulation of o-hydroxyphenylacetic acids and trifluoromethyl alkenes: synthesis of fluorinated dihydrobenzoxepines

(2018) Haoguo Chen et al.   Organic Chemistry Frontiers

Metal-Free Access to (E/Z )-α-Fluorovinyl Phosphorus Compounds from gem -Difluorostyrenes

(2018) Yingyuan Peng et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Copper-catalyzed synthesis of gem-difluoroallylboronates from α-trifluoromethyl alkenes and B2pin2

(2018) Xianghu Zhao et al.   TETRAHEDRON LETTERS

Synthesis of gem-Difluoroalkenes via Nickel-Catalyzed Reductive C–F and C–O Bond Cleavage

(2018) Zhiyang Lin et al.   ACS Catalysis

The C–OH/P–H dehydrative cross-coupling for the construction of the P–C bond under metal-free conditions

(2017) Peizhong Xie et al.   GREEN CHEMISTRY

Silver-Catalyzed Radical-Involved Cascade Cyclization of Diphenylphosphine with Cinnamamides: Access to 2-Phosphinoyl-3H-pyrrolo[1,2-a]indoles

(2017) Jian Xu et al.   ORGANIC LETTERS

Phosphinoyl Radical Initiated Vicinal Cyanophosphinoylation of Alkenes

(2017) Pei-Zhi Zhang et al.   ORGANIC LETTERS

Recent progress toward organophosphorus compounds based on phosphorus-centered radical difunctionalizations

(2017) Yuzhen Gao et al.   PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS

Photoredox Catalysis in Organophosphorus Chemistry

(2017) Kai Luo et al.   Asian Journal of Organic Chemistry

Copper-catalyzed aerobic oxidative coupling of ketones with P(O)–H compounds leading to β-ketophosphine oxides

(2017) Qiang Fu et al.   Organic Chemistry Frontiers

Phosphorylation of Glycine Derivatives via Copper(I)-Catalyzed Csp 3 −H Bond Functionalization

(2016) Huizhen Zhi et al.   ADVANCED SYNTHESIS & CATALYSIS

Phosphonate Biochemistry

(2016) Geoff P. Horsman et al.   CHEMICAL REVIEWS

Synthesis of Functionalized gem-Difluoroalkenes via a Photocatalytic Decarboxylative/Defluorinative Reaction

(2016) Tiebo Xiao et al.   JOURNAL OF ORGANIC CHEMISTRY

Silver(I)-Mediated Phosphorylation/Cyclization Cascade of N-Cyanamide Alkenes for Divergent Access to Quinazolinones and Dihydroisoquinolinones

(2016) Jing Zheng et al.   ORGANIC LETTERS

Visible-Light-Induced Cascade Reaction of Isocyanides and N-Arylacrylamides with Diphenylphosphine Oxide via Radical C–P and C–C Bond Formation

(2016) Chun-Xiao Li et al.   ORGANIC LETTERS

The singlet excited state of BODIPY promoted aerobic cross-dehydrogenative-coupling reactions under visible light

(2015) Xu-Zhe Wang et al.   CHEMICAL COMMUNICATIONS

Recent advances in sulfur- and phosphorous-centered radical reactions for the formation of S–C and P–C bonds

(2015) Xiang-Qiang Pan et al.   TETRAHEDRON

Efficient visible light-mediated cross-dehydrogenative coupling reactions of tertiary amines catalyzed by a polymer-immobilized iridium-based photocatalyst

(2014) Woo-Jin Yoo et al.   GREEN CHEMISTRY

Direct Radical Acetoxyphosphorylation of Styrenes Mediated by Manganese(III)

(2014) Shao-Fang Zhou et al.   JOURNAL OF ORGANIC CHEMISTRY

Phosphinate Chemistry in the 21st Century: A Viable Alternative to the Use of Phosphorus Trichloride in Organophosphorus Synthesis.

(2013) Jean-Luc Montchamp   ACCOUNTS OF CHEMICAL RESEARCH

A Robust Palladium(II)-Porphyrin Complex as Catalyst for Visible Light Induced Oxidative CH Functionalization

(2013) Wai-Pong To et al.   CHEMISTRY-A EUROPEAN JOURNAL

Hydrophosphinylation of unactivated alkenes with secondary phosphine oxides under visible-light photocatalysis

(2013) Woo-Jin Yoo et al.   GREEN CHEMISTRY

Highly efficient visible-light-induced aerobic oxidative C–C, C–P coupling from C–H bonds catalyzed by a gold(iii)-complex

(2013) Qicai Xue et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

New Strategies for Transition-Metal-Catalyzed C-P Bond Formation

(2013) Shang-Dong Yang et al.   SYNLETT

A Scalable, Efficient Gold-Catalyzed Oxidative Phosphonation of sp3 CH Bonds using Air as Sustainable Oxidant

(2012) Jin Xie et al.   ADVANCED SYNTHESIS & CATALYSIS

Substitution of Two Fluorine Atoms in a Trifluoromethyl Group: Regioselective Synthesis of 3-Fluoropyrazoles

(2012) Kohei Fuchibe et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Light-Mediated Heterogeneous Cross Dehydrogenative Coupling Reactions: Metal Oxides as Efficient, Recyclable, Photoredox Catalysts in CC Bond-Forming Reactions

(2012) Magnus Rueping et al.   CHEMISTRY-A EUROPEAN JOURNAL

Photoredox catalyzed C–P bond forming reactions—visible light mediated oxidative phosphonylations of amines

(2011) Magnus Rueping et al.   CHEMICAL COMMUNICATIONS

Synthesis and Metal-Catalyzed Reactions of gem-Dihalovinyl Systems

(2011) Giorgio Chelucci   CHEMICAL REVIEWS

Direct Conversion of Benzylic and Allylic Alcohols to Phosphonates

(2011) Rocky J. Barney et al.   JOURNAL OF ORGANIC CHEMISTRY

Synthetic Methods for Heterocycles and Carbocycles Bearing Fluorinated One-Carbon Units (=CF2, CHF2, or CF3): Intramolecular Reaction of 2-Trifluoromethyl-1-alkenes

(2011) Junji Ichikawa   JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN

Lewis Acid-Mediated Michaelis−Arbuzov Reaction at Room Temperature: A Facile Preparation of Arylmethyl/Heteroarylmethyl Phosphonates

(2011) Ganesan Gobi Rajeshwaran et al.   ORGANIC LETTERS

Eosin Y Catalyzed Visible Light Oxidative C–C and C–P bond Formation

(2011) Durga Prasad Hari et al.   ORGANIC LETTERS

Arylation of Styrenes with Aryliron Complexes [CpFe(CO)2Ar]

(2010) Shigeo Yasuda et al.   ORGANOMETALLICS

Iron-catalyzed dehydrogenative phosphonation of N,N-dimethylanilines

(2009) Wei Han et al.   CHEMICAL COMMUNICATIONS

Copper-catalyzed aerobic phosphonation of sp3 C–H bonds

(2009) Olivier Baslé et al.   CHEMICAL COMMUNICATIONS

C−F Bond Activation in Organic Synthesis

(2009) Hideki Amii et al.   CHEMICAL REVIEWS

Synthesis ofgem-Difluoroalkenes via β-Fluoride Elimination of Organorhodium(I)

(2008) Tomoya Miura et al.   CHEMISTRY LETTERS

Glyphosate: a once-in-a-century herbicide

(2008) Stephen O Duke et al.   PEST MANAGEMENT SCIENCE