Dehydrogenative Silylation of Alkenes for the Synthesis of Substituted Allylsilanes by Photoredox, Hydrogen-Atom Transfer, and Cobalt Catalysis

Selective Oxidative [4+2] Imine/Alkene Annulation with H2 Liberation Induced by Photo-Oxidation

(2018) Xia Hu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Dual C(sp3 )−H Bond Functionalization of N-Heterocycles through Sequential Visible-Light Photocatalyzed Dehydrogenation/[2+2] Cycloaddition Reactions

(2018) Guo-Qiang Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Alkene functionalization for the stereospecific synthesis of substituted aziridines by visible-light photoredox catalysis

(2018) Wan-Lei Yu et al.   CHEMICAL COMMUNICATIONS

Thirty Years of (TMS)3SiH: A Milestone in Radical-Based Synthetic Chemistry

(2018) Chryssostomos Chatgilialoglu et al.   CHEMICAL REVIEWS

Photoredox-Induced Intramolecular 1,5-H Transfer Reaction of Aryl Iodides for the Synthesis of Spirocyclic γ-Lactams

(2018) Jian-Qiang Chen et al.   ORGANIC LETTERS

Photoinduced oxidative activation of electron-rich arenes: alkenylation with H2 evolution under external oxidant-free conditions

(2018) Xia Hu et al.   Chemical Science

Catalytic dehydrogenative decarboxyolefination of carboxylic acids

(2018) Xiang Sun et al.   Nature Chemistry

Photocatalytic Activation of Less Reactive Bonds and Their Functionalization via Hydrogen-Evolution Cross-Couplings

(2018) Bin Chen et al.   ACCOUNTS OF CHEMICAL RESEARCH

Photo-induced Decarboxylative Heck-Type Coupling of Unactivated Aliphatic Acids and Terminal Alkenes in the Absence of Sacrificial Hydrogen Acceptors

(2018) Hui Cao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Decarboxylative Elimination of N-Acyl Amino Acids via Photoredox/Cobalt Dual Catalysis

(2018) Kaitie C. Cartwright et al.   ACS Catalysis

Direct Aldehyde C–H Arylation and Alkylation via the Combination of Nickel, Hydrogen Atom Transfer, and Photoredox Catalysis

(2017) Xiaheng Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Selective sp3 C–H alkylation via polarity-match-based cross-coupling

(2017) Chip Le et al.   NATURE

Photo-induced oxidant-free oxidative C–H/N–H cross-coupling between arenes and azoles

(2017) Linbin Niu et al.   Nature Communications

Visible-Light-Induced External Oxidant-Free Oxidative Phosphonylation of C(sp2)–H Bonds

(2017) Linbin Niu et al.   ACS Catalysis

Photocatalytic Dehydrogenative Cross-Coupling of Alkenes with Alcohols or Azoles without External Oxidant

(2016) Hong Yi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Visible-light induced oxidant-free oxidative cross-coupling for constructing allylic sulfones from olefins and sulfinic acids

(2016) Guoting Zhang et al.   CHEMICAL COMMUNICATIONS

Photoredox Catalysis in Organic Chemistry

(2016) Megan H. Shaw et al.   JOURNAL OF ORGANIC CHEMISTRY

Anti-Markovnikov Oxidation of β-Alkyl Styrenes with H2O as the Terminal Oxidant

(2016) Guoting Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Photocatalytic Hydrogen-Evolution Cross-Couplings: Benzene C–H Amination and Hydroxylation

(2016) Yi-Wen Zheng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Native functionality in triple catalytic cross-coupling: sp3 C-H bonds as latent nucleophiles

(2016) M. H. Shaw et al.   SCIENCE

Donor–Acceptor Fluorophores for Visible-Light-Promoted Organic Synthesis: Photoredox/Ni Dual Catalytic C(sp3)–C(sp2) Cross-Coupling

(2016) Jian Luo et al.   ACS Catalysis

An Oxidant-Free Strategy for Indole Synthesis via Intramolecular C–C Bond Construction under Visible Light Irradiation: Cross-Coupling Hydrogen Evolution Reaction

(2016) Cheng-Juan Wu et al.   ACS Catalysis

Decatungstate-Photocatalyzed Si−H/C−H Activation in Silyl Hydrides: Hydrosilylation of Electron-Poor Alkenes

(2015) Hisham Qrareya et al.   ChemCatChem

External Oxidant-Free Oxidative Cross-Coupling: A Photoredox Cobalt-Catalyzed Aromatic C–H Thiolation for Constructing C–S Bonds

(2015) Guoting Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cobalt-Catalyzed Cross-Dehydrogenative Coupling Reaction in Water by Visible Light

(2015) Cheng-Juan Wu et al.   ORGANIC LETTERS

O-H hydrogen bonding promotes H-atom transfer from   C-H bonds for C-alkylation of alcohols

(2015) J. L. Jeffrey et al.   SCIENCE

Acceptorless dehydrogenation of small molecules through cooperative base metal catalysis

(2015) Julian G. West et al.   Nature Communications

Visible Light Catalysis Assisted Site-Specific Functionalization of Amino Acid Derivatives by C–H Bond Activation without Oxidant: Cross-Coupling Hydrogen Evolution Reaction

(2015) Xue-Wang Gao et al.   ACS Catalysis

Mechanistic Insights into the Interface-Directed Transformation of Thiols into Disulfides and Molecular Hydrogen by Visible-Light Irradiation of Quantum Dots

(2014) Xu-Bing Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Dual Catalysis Sees the Light: Combining Photoredox with Organo-, Acid, and Transition-Metal Catalysis

(2014) Matthew N. Hopkinson et al.   CHEMISTRY-A EUROPEAN JOURNAL

Rational Design of a Second Generation Catalyst for Preparation of Allylsilanes Using the Silyl-Heck Reaction

(2014) Jesse R. McAtee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Bis(imino)pyridine Cobalt-Catalyzed Dehydrogenative Silylation of Alkenes: Scope, Mechanism, and Origins of Selective Allylsilane Formation

(2014) Crisita Carmen Hojilla Atienza et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridium-Catalyzed, Diastereoselective Dehydrogenative Silylation of Terminal Alkenes with (TMSO)2MeSiH

(2013) Chen Cheng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Visible Light Photoredox Catalysis with Transition Metal Complexes: Applications in Organic Synthesis

(2013) Christopher K. Prier et al.   CHEMICAL REVIEWS

A Cascade Cross-Coupling Hydrogen Evolution Reaction by Visible Light Catalysis

(2013) Qing-Yuan Meng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Preparation of Allyl and Vinyl Silanes by the Palladium-Catalyzed Silylation of Terminal Olefins: A Silyl-Heck Reaction

(2012) Jesse R. McAtee et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Visible-Light Photoredox Catalysis

(2012) Jun Xuan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Visible light mediated homo- and heterocoupling of benzyl alcohols and benzyl amines on polycrystalline cadmium sulfide

(2012) Tatiana Mitkina et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Cobalt-Catalyzed Coupling of Alkyl Iodides with Alkenes: Deprotonation of Hydridocobalt Enables Turnover

(2011) Matthias E. Weiss et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Splitting Water with Cobalt

(2011) Vincent Artero et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Selective Dehydrogenative Silylation–Hydrogenation Reaction of Divinyldisiloxane with Hydrosilane Catalyzed by an Iron Complex

(2011) Roman N. Naumov et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydrogen Evolution Catalyzed by Cobaloximes

(2009) Jillian L. Dempsey et al.   ACCOUNTS OF CHEMICAL RESEARCH

Highly Selective Dehydrogenative Silylation of Alkenes Catalyzed by Rhenium Complexes

(2009) Yanfeng Jiang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Visible Light-Driven Hydrogen Production from Aqueous Protons Catalyzed by Molecular Cobaloxime Catalysts

(2009) Pingwu Du et al.   INORGANIC CHEMISTRY

Making Hydrogen from Water Using a Homogeneous System Without Noble Metals

(2009) Theodore Lazarides et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY