期刊
ACS CATALYSIS
卷 8, 期 12, 页码 11801-11806出版社
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.8b03282
关键词
decarboxylative elimination; enamides; enecarbamates; photoredox/cobalt dual catalysis
资金
- National Science Foundation [CHE-1800147]
- Kansas Bioscience Authority Rising Star program
- NSF Academic Research Infrastructure Grant [9512331]
- NIH Shared Instrumentation Grant [S10RR024664]
- NSF Major Research Instrumentation Grant [0320648]
- NSF-MRI grant [CHE-0923449]
- Div Of Biological Infrastructure
- Direct For Biological Sciences [9512331] Funding Source: National Science Foundation
A dual-catalytic strategy for the synthesis of enamides and enecarbamates directly from easily accessible and inexpensive amino acids has been realized. This mild and efficient protocol makes use of an organic photoredox catalyst and a cobaloxime catalyst to achieve decarboxylative elimination using hydrogen evolution to drive the oxidation. Thus, the reaction occurs without a stoichiometric oxidant or the forcing conditions previously employed in attempts to achieve similar eliminations.
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