Role of Asymmetric Autocatalysis in the Elucidation of Origins of Homochirality of Organic Compounds

Asymmetric autocatalysis. Chiral symmetry breaking and the origins of homochirality of organic molecules

(2019) Kenso SOAI   PROCEEDINGS OF THE JAPAN ACADEMY SERIES B-PHYSICAL AND BIOLOGICAL SCIENCES

A Quantification of the Soai Reaction

(2018) María E. Noble-Terán et al.   ChemCatChem

Asymmetric autocatalysis of pyrimidyl alkanol and related compounds. Self-replication, amplification of chirality and implication for the origin of biological enantioenriched chirality

(2018) Kenso Soai et al.   TETRAHEDRON

The self-disproportionation of enantiomers (SDE): a menace or an opportunity?

(2018) Jianlin Han et al.   Chemical Science

Reversal of the sense of enantioselectivity between 1- and 2-aza[6]helicenes used as chiral inducers of asymmetric autocatalysis

(2017) Arimasa Matsumoto et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Recycling in Asymmetric Catalysis

(2016) Christina Moberg   ACCOUNTS OF CHEMICAL RESEARCH

Achiral Inorganic Gypsum Acts as an Origin of Chirality through Its Enantiotopic Surface in Conjunction with Asymmetric Autocatalysis

(2016) Arimasa Matsumoto et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Induction by a Nitrogen14N/15N Isotopomer in Conjunction with Asymmetric Autocatalysis

(2016) Arimasa Matsumoto et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Elucidation of the Structures of Asymmetric Autocatalyst Based on X-ray Crystallography

(2016) Arimasa Matsumoto et al.   BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN

Point-to-Point Ultra-Remote Asymmetric Control with Flexible Linker

(2016) Tsuneomi Kawasaki et al.   CHEMISTRY-A EUROPEAN JOURNAL

Limits of the Classical Concept of Concentration

(2016) Marco Maioli et al.   JOURNAL OF PHYSICAL CHEMISTRY B

Determination of the absolute structure of the chiral crystal consisting of achiral dibutylhydroxytoluene and asymmetric autocatalysis triggered by this chiral crystal

(2016) Arimasa Matsumoto et al.   TETRAHEDRON-ASYMMETRY

Crystal Structure of the Isopropylzinc Alkoxide of Pyrimidyl Alkanol: Mechanistic Insights for Asymmetric Autocatalysis with Amplification of Enantiomeric Excess

(2015) Arimasa Matsumoto et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

On the Origin and Structure of the Recently Observed Acetal in the Soai Reaction

(2015) Ilya D. Gridnev et al.   BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN

Helical mesoporous silica as an inorganic heterogeneous chiral trigger for asymmetric autocatalysis with amplification of enantiomeric excess

(2015) Tsuneomi Kawasaki et al.   CHEMICAL COMMUNICATIONS

Asymmetric Autocatalysis Triggered by Chiral Crystal of Achiral Ethylenediamine Sulfate

(2015) Arimasa Matsumoto et al.   CHEMISTRY LETTERS

Attrition-induced spontaneous chiral amplification of the γ polymorphic modification of glycine

(2015) Arkadii V. Tarasevych et al.   CRYSTENGCOMM

Asymmetric induction by retgersite, nickel sulfate hexahydrate, in conjunction with asymmetric autocatalysis

(2015) Arimasa Matsumoto et al.   NEW JOURNAL OF CHEMISTRY

Asymmetric Autocatalysis of Pyrimidyl Alkanol and Its Application to the Study on the Origin of Homochirality

(2014) Kenso Soai et al.   ACCOUNTS OF CHEMICAL RESEARCH

Self-Replication and Amplification of Enantiomeric Excess of Chiral Multifunctionalized Large Molecules by Asymmetric Autocatalysis

(2014) Tsuneomi Kawasaki et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Origins of Homochirality Examined by Using Asymmetric Autocatalysis

(2014) Kenso Soai et al.   CHEMICAL RECORD

Asymmetric Autocatalysis Induced by Cinnabar: Observation of the Enantioselective Adsorption of a 5-Pyrimidyl Alkanol on the Crystal Surface

(2013) Hitoshi Shindo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Synthesis Induced by the Helical Molecular Arrangement in the Chiral Crystal of Achiral Tris(2-hydroxyethyl) 1,3,5-Benzenetricarboxylate in Conjunction with Asymmetric Autocatalysis

(2013) Tsuneomi Kawasaki et al.   CHEMISTRY LETTERS

Asymmetric autocatalysis triggered by oxygen isotopically chiral glycerin

(2013) Arimasa Matsumoto et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Colloquium: Homochirality: Symmetry breaking in systems driven far from equilibrium

(2013) Yukio Saito et al.   REVIEWS OF MODERN PHYSICS

Enantiodivergent formation of a chiral cytosine crystal by removal of crystal water from an achiral monohydrate crystal under reduced pressure

(2013) Hiroko Mineki et al.   TETRAHEDRON-ASYMMETRY

Observation of a Transient Intermediate in Soai’s Asymmetric Autocatalysis: Insights from 1H NMR Turnover in Real Time

(2012) Timo Gehring et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Absolute chirality of the γ-polymorph of glycine: correlation of the absolute structure with the optical rotation

(2012) Kazuhiko Ishikawa et al.   CHEMICAL COMMUNICATIONS

Asymmetric autocatalysis initiated by achiral nucleic acid base adenine: implications on the origin of homochirality of biomolecules

(2012) Hiroko Mineki et al.   CHEMICAL COMMUNICATIONS

Prediction of Soai Reaction Enantioselectivity Induced by Crystals of N-(2-Thienylcarbonyl)glycine

(2012) Damien J. Carter et al.   CRYSTAL GROWTH & DESIGN

Asymmetric Autocatalysis Triggered by Chiral Crystals Formed from Achiral Compounds and Chiral Isotopomers

(2012) Tsuneomi Kawasaki et al.   ISRAEL JOURNAL OF CHEMISTRY

Molecular chirality at surfaces

(2012) Karl-Heinz Ernst   PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS

Amplification of enantiomeric excess, mirror-image symmetry breaking and kinetic proofreading in Soai reaction models with different oligomeric orders

(2012) Jean-Claude Micheau et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Quantification of Sophisticated Equilibria in the Reaction Pool and Amplifying Catalytic Cycle of the Soai Reaction

(2012) Ilya D. Gridnev et al.   ACS Catalysis

Enantioselective CC Bond Formation as a Result of the Oriented Prochirality of an Achiral Aldehyde at the Single-Crystal Face upon Treatment with a Dialkyl Zinc Vapor

(2011) Tsuneomi Kawasaki et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Autocatalysis: Triggered by Chiral Isotopomer Arising from Oxygen Isotope Substitution

(2011) Tsuneomi Kawasaki et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Induction Arising from Enantiomerically Enriched Carbon-13 Isotopomers and Highly Sensitive Chiral Discrimination by Asymmetric Autocatalysis

(2011) Tsuneomi Kawasaki et al.   BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN

Crystalline Architectures as Templates of Relevance to the Origins of Homochirality

(2011) Isabelle Weissbuch et al.   CHEMICAL REVIEWS

Enantioselective Synthesis Induced by Compounds with Chirality Arising from Partially Deuterated Methyl Groups in Conjunction with Asymmetric Autocatalysis

(2011) Tsuneomi Kawasaki et al.   CHEMISTRY LETTERS

Putting the Mechanism of the Soai Reaction to the Test: DFT Study of the Role of Aldehyde and Dialkylzinc Structure

(2011) Gianfranco Ercolani et al.   JOURNAL OF ORGANIC CHEMISTRY

Mechanism-Based Chemical Understanding of Chiral Symmetry Breaking in the Soai Reaction. A Combined Probabilistic and Deterministic Description of Chemical Reactions

(2011) Éva Dóka et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Synthesis Induced by Chiral Crystal Composed ofdl-Serine in Conjunction with Asymmetric Autocatalysis

(2011) Tsuneomi Kawasaki et al.   ORGANIC LETTERS

An Autocatalytic Cycle Model of Asymmetric Amplification and Mirror-Symmetry Breaking in the Soai Reaction

(2010) Jean-Claude Micheau et al.   CHEMPHYSCHEM

A concise summary of experimental facts about the Soai reaction

(2010) Timo Gehring et al.   CHIRALITY

Generation of Absolute Controlled Crystal Chirality by the Removal of Crystal Water from Achiral Crystal of Nucleobase Cytosine

(2010) Tsuneomi Kawasaki et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Unusual Inverse Temperature Dependence on Reaction Rate in the Asymmetric Autocatalytic Alkylation of Pyrimidyl Aldehydes

(2010) Michela Quaranta et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

From Ostwald Ripening to Single Chirality

(2009) Wim L. Noorduin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nonlinear Effects in Asymmetric Catalysis

(2009) Tummanapalli Satyanarayana et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Data-Based Stochastic Approach to Absolute Asymmetric Synthesis by Autocatalysis

(2009) Béla Barabás et al.   BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN

Discrimination of cryptochirality in chiral isotactic polystyrene by asymmetric autocatalysis

(2009) Tsuneomi Kawasaki et al.   CHEMICAL COMMUNICATIONS

Asymmetric autocatalysis induced by meteoritic amino acids with hydrogen isotope chirality

(2009) Tsuneomi Kawasaki et al.   CHEMICAL COMMUNICATIONS

Frank Model and Spontaneous Emergence of Chirality in Closed Systems

(2009) Joaquim Crusats et al.   CHEMPHYSCHEM

Amplification of chirality as a pathway to biological homochirality

(2009) Tsuneomi Kawasaki et al.   JOURNAL OF FLUORINE CHEMISTRY

Complete chiral symmetry breaking of an amino acid derivative directed by circularly polarized light

(2009) Wim L. Noorduin et al.   Nature Chemistry

Asymmetric Autocatalysis Induced by Chiral Crystals of Achiral Tetraphenylethylenes

(2009) Tsuneomi Kawasaki et al.   ORIGINS OF LIFE AND EVOLUTION OF BIOSPHERES

Asymmetric Autocatalysis Triggered by Carbon Isotope (13C/12C) Chirality

(2009) T. Kawasaki et al.   SCIENCE

Unraveling the Mechanism of the Soai Asymmetric Autocatalytic Reaction by First-Principles Calculations: Induction and Amplification of Chirality by Self-Assembly of Hexamolecular Complexes

(2008) Luca Schiaffino et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Oscillatory Symmetry Breaking in the Soai Reaction

(2008) Károly Micskei et al.   JOURNAL OF PHYSICAL CHEMISTRY B

Enantioselective Synthesis Utilizing Enantiomorphous Organic Crystal of Achiral Benzils as a Source of Chirality in Asymmetric Autocatalysis

(2008) Tsuneomi Kawasaki et al.   ORGANIC LETTERS

Achiral Nucleobase Cytosine Acts as an Origin of Homochirality of Biomolecules in Conjunction with Asymmetric Autocatalysis

(2007) Tsuneomi Kawasaki et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION