Catalytic Generation of C1 Ammonium Enolates from Halides and CO for Asymmetric Cascade Reactions

Enantioselective α-Benzylation of Acyclic Esters Using π-Extended Electrophiles.

(2018) Kevin Schwarz et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Traversing Steric Limitations by Cooperative Lewis Base/Palladium Catalysis: An Enantioselective Synthesis of α-Branched Esters Using 2-Substituted Allyl Electrophiles

(2018) Kevin J. Schwarz et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Insights into the isothiourea-catalyzed asymmetric [4 + 2] annulation of phenylacetic acid with alkylidene pyrazolone

(2018) Qianqian Shi et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Palladium-Catalyzed Carbonylation of Aryl Chlorides to Electrophilic Aroyl-DMAP Salts

(2018) Pierre-Louis Lagueux-Tremblay et al.   ACS Catalysis

α-Quaternary Chiral Aldehydes from Styrenes, Allylic Alcohols, and Syngas via Multi-catalyst Relay Catalysis

(2018) Jing Meng et al.   Chem

The Chemistry of CO: Carbonylation

(2018) Jin-Bao Peng et al.   Chem

A Direct Synthesis of Isocytosine Analogues by Carbonylative Coupling of α-Chloro Ketones and Guanidines

(2017) Martina Capua et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Tandem Palladium and Isothiourea Relay Catalysis: Enantioselective Synthesis of α-Amino Acid Derivatives via Allylic Amination and [2,3]-Sigmatropic Rearrangement

(2017) Stéphanie S. M. Spoehrle et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A general approach to intermolecular carbonylation of arene C–H bonds to ketones through catalytic aroyl triflate formation

(2017) R. Garrison Kinney et al.   Nature Chemistry

Asymmetric [4 + 2] Annulation Reactions Catalyzed by a Robust, Immobilized Isothiourea

(2017) Shoulei Wang et al.   ACS Catalysis

Applications of Palladium-Catalyzed C–N Cross-Coupling Reactions

(2016) Paula Ruiz-Castillo et al.   CHEMICAL REVIEWS

Combinations of Aminocatalysts and Metal Catalysts: A Powerful Cooperative Approach in Selective Organic Synthesis

(2016) Samson Afewerki et al.   CHEMICAL REVIEWS

Palladium-Catalyzed, Multicomponent Approach to β-Lactams via Aryl Halide Carbonylation

(2016) Gerardo M. Torres et al.   JOURNAL OF ORGANIC CHEMISTRY

Uniting C1-Ammonium Enolates and Transition Metal Electrophiles via Cooperative Catalysis: The Direct Asymmetric α-Allylation of Aryl Acetic Acid Esters

(2016) Kevin J. Schwarz et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereodivergent Allylic Substitutions with Aryl Acetic Acid Esters by Synergistic Iridium and Lewis Base Catalysis

(2016) Xingyu Jiang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Catalytic Cascade Reactions for Constructing Diverse Scaffolds and Complex Molecules

(2015) Yao Wang et al.   ACCOUNTS OF CHEMICAL RESEARCH

Transition-Metal Catalysis and Organocatalysis: Where Can Progress Be Expected?

(2015) Qi-Lin Zhou   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Facile Net Cycloaddition Approach to Optically Active 1,5-Benzothiazepines

(2015) Yukihiro Fukata et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Orthogonal tandem catalysis

(2015) Tracy L. Lohr et al.   Nature Chemistry

Asymmetric Organocatalysis Combined with Metal Catalysis: Concept, Proof of Concept, and Beyond

(2014) Dian-Feng Chen et al.   ACCOUNTS OF CHEMICAL RESEARCH

N-Heterocyclic Carbene Catalyzed Cyclocondensation of α,β-Unsaturated Carboxylic Acids: Enantioselective Synthesis of Pyrrolidinone and Dihydropyridinone Derivatives

(2014) Xiang-Yu Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Organocatalytic Lewis base functionalisation of carboxylic acids, esters and anhydrides via C1-ammonium or azolium enolates

(2014) Louis C. Morrill et al.   CHEMICAL SOCIETY REVIEWS

Isothiourea-Catalyzed Asymmetric Synthesis of β-Lactams and β-Amino Esters from Arylacetic Acid Derivatives and N-Sulfonylaldimines

(2014) Siobhan R. Smith et al.   JOURNAL OF ORGANIC CHEMISTRY

Bifunctional N-Heterocyclic Carbene-Catalyzed Highly Enantioselective Synthesis of Spirocyclic Oxindolo-β-lactams

(2014) Han-Ming Zhang et al.   ORGANIC LETTERS

Isothiourea-Mediated One-Pot Synthesis of Functionalized Pyridines

(2013) Daniel G. Stark et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Palladium-Catalyzed Carbonylation Approach to Acid Chloride Synthesis

(2013) Jeffrey S. Quesnel et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

NHC-Catalyzed Ester Activation: Access to Sterically Congested Spirocyclic Oxindoles via Reaction of α-Aryl Esters and Unsaturated Imines

(2013) Yonggui Chi et al.   SYNLETT

Isothiourea-mediated asymmetric Michael-lactonisation of trifluoromethylenones: a synthetic and mechanistic study

(2013) Louis C. Morrill et al.   Chemical Science

Dihydropyridones: Catalytic Asymmetric Synthesis, N- to C-Sulfonyl Transfer, and Derivatizations

(2012) Carmen Simal et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Heterocycles via Palladium-Catalyzed Carbonylations

(2012) Xiao-Feng Wu et al.   CHEMICAL REVIEWS

Combining transition metal catalysis and organocatalysis – an update

(2012) Zhenting Du et al.   CHEMICAL SOCIETY REVIEWS

NHCs in Asymmetric Organocatalysis: Recent Advances in Azolium Enolate Generation and Reactivity

(2012) Andrew Smith et al.   SYNTHESIS-STUTTGART

Stereoselective synthesis of trans β-lactams via palladium/N-heterocyclic carbene-catalyzed carbonylative [2+2] cycloaddition

(2012) Pan Xie et al.   TETRAHEDRON LETTERS

Catalytic asymmetric α-amination of carboxylic acids using isothioureas

(2012) Louis C. Morrill et al.   Chemical Science

Synthesis, biochemical and molecular modelling studies of antiproliferative azetidinones causing microtubule disruption and mitotic catastrophe

(2011) Niamh M. O’Boyle et al.   EUROPEAN JOURNAL OF MEDICINAL CHEMISTRY

New Directions in Ketene Chemistry: The Land of Opportunity

(2011) Annette D. Allen et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Pd-Catalyzed Carbonylation of Diazo Compounds at Atmospheric Pressure: A Catalytic Approach to Ketenes

(2011) Zhenhua Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Organocatalytic Functionalization of Carboxylic Acids: Isothiourea-Catalyzed Asymmetric Intra- and Intermolecular Michael Addition−Lactonizations

(2011) Dorine Belmessieri et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective, Organocatalyzed, Intramolecular Aldol Lactonizations with Keto Acids Leading to Bi- and Tricyclic β-Lactones and Topology-Morphing Transformations

(2010) Carolyn A. Leverett et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Kinetic Resolution of Racemic α-Arylalkanoic Acids with Achiral Alcohols via the Asymmetric Esterification Using Carboxylic Anhydrides and Acyl-Transfer Catalysts

(2010) Isamu Shiina et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Organocatalytic cascade reactions as a new tool in total synthesis

(2010) Christoph Grondal et al.   Nature Chemistry

Catalytic, asymmetric reactions of ketenes and ketene enolates

(2009) Daniel H. Paull et al.   TETRAHEDRON

Lewis Base Catalysis in Organic Synthesis

(2008) Scott E. Denmark et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic, Asymmetric α-Fluorination of Acid Chlorides: Dual Metal−Ketene Enolate Activation

(2008) Daniel H. Paull et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The advent and development of organocatalysis

(2008) David W. C. MacMillan   NATURE