A general approach to intermolecular carbonylation of arene C–H bonds to ketones through catalytic aroyl triflate formation

Natural Product Synthesis via Palladium-Catalyzed Carbonylation

(2017) Yu Bai et al.   JOURNAL OF ORGANIC CHEMISTRY

CO- and HCl-free synthesis of acid chlorides from unsaturated hydrocarbons via shuttle catalysis

(2017) Xianjie Fang et al.   Nature Chemistry

Electrophilic Aromatic Substitution with Silicon Electrophiles: Catalytic Friedel-Crafts C−H Silylation

(2016) Susanne Bähr et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Sterically-controlled intermolecular Friedel–Crafts acylation with twisted amides via selective N–C cleavage under mild conditions

(2016) Yongmei Liu et al.   CHEMICAL COMMUNICATIONS

The medicinal chemist's toolbox for late stage functionalization of drug-like molecules

(2016) Tim Cernak et al.   CHEMICAL SOCIETY REVIEWS

Computational Study of the Palladium-Catalyzed Carbonylative Synthesis of Aromatic Acid Chlorides: The Synergistic Effect of Pt Bu3 and CO on Reductive Elimination

(2016) Jeffrey S. Quesnel et al.   CHEMISTRY-A EUROPEAN JOURNAL

Ag(I)-Catalyzed C–H Activation: The Role of the Ag(I) Salt in Pd/Ag-Mediated C–H Arylation of Electron-Deficient Arenes

(2016) Daniel Whitaker et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed, Site-Selective Direct Allylation of Aryl C–H Bonds by Silver-Mediated C–H Activation: A Synthetic and Mechanistic Investigation

(2016) Sarah Yunmi Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

High-Turnover Aromatic C–H Borylation Catalyzed by POCOP-Type Pincer Complexes of Iridium

(2016) Loren P. Press et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Charge-transfer-directed radical substitution enables para-selective C–H functionalization

(2016) Gregory B. Boursalian et al.   Nature Chemistry

Hexafluoro-2-propanol-Promoted Intermolecular Friedel–Crafts Acylation Reaction

(2016) Rakesh H. Vekariya et al.   ORGANIC LETTERS

Role of Silver Salts in Palladium-Catalyzed Arene and Heteroarene C–H Functionalization Reactions

(2016) Monica D. Lotz et al.   ORGANOMETALLICS

A general catalytic β-C–H carbonylation of aliphatic amines to β-lactams

(2016) Darren Willcox et al.   SCIENCE

Undirected, Homogeneous C–H Bond Functionalization: Challenges and Opportunities

(2016) John F. Hartwig et al.   ACS Central Science

C–H activation dependent Pd-catalyzed carbonylative coupling of (hetero)aryl bromides and polyfluoroarenes

(2015) Zhong Lian et al.   CHEMICAL COMMUNICATIONS

Transition-Metal-Catalyzed Direct Addition of Unactivated C–H Bonds to Polar Unsaturated Bonds

(2015) Lei Yang et al.   CHEMICAL REVIEWS

Oxidative Coupling between Two Hydrocarbons: An Update of Recent C–H Functionalizations

(2015) Chao Liu et al.   CHEMICAL REVIEWS

Acid Chloride Synthesis by the Palladium-Catalyzed Chlorocarbonylation of Aryl Bromides

(2015) Jeffrey S. Quesnel et al.   CHEMISTRY-A EUROPEAN JOURNAL

An Electrophilic Approach to the Palladium-Catalyzed Carbonylative C–H Functionalization of Heterocycles

(2015) Jevgenijs Tjutrins et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Evolution of C–H Bond Functionalization from Methane to Methodology

(2015) John F. Hartwig   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ligand-Enabled γ-C–H Olefination and Carbonylation: Construction of β-Quaternary Carbon Centers

(2014) Suhua Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cobalt-Catalyzed C–H Borylation

(2014) Jennifer V. Obligacion et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Palladium-Catalyzed Carbonylation Approach to Acid Chloride Synthesis

(2013) Jeffrey S. Quesnel et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Suzuki-Miyaura Cross-Coupling in Acylation Reactions, Scope and Recent Developments

(2013) Marco Blangetti et al.   MOLECULES

Pd-Catalyzed Direct Coupling of Indoles with Carbon Monoxide and Alkynes: Selective Synthesis of Linear α,β-Unsaturated Ketones

(2013) Fanlong Zeng et al.   ORGANIC LETTERS

σ-Bond Metathesis between M–X and RC(O)X′ (M = Pt, Pd; X, X′ = Cl, Br, I): Facile Determination of the Relative ΔG Values of the Oxidative Additions of RC(O)X to an M(0) Complex, Evidence by Density Functional Theory Calculations, and Synthetic Applications

(2013) Hitoshi Kuniyasu et al.   ORGANOMETALLICS

Beyond Directing Groups: Transition-Metal-Catalyzed CH Activation of Simple Arenes

(2012) Nadine Kuhl et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Oxidative Double CH Functionalization/Carbonylation for the Synthesis of Xanthones

(2012) Hua Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Fenofibrate

(2011) Gillian M. Keating   American Journal of Cardiovascular Drugs

Oxidative Carbonylation Reactions: Organometallic Compounds (RM) or Hydrocarbons (RH) as Nucleophiles

(2011) Qiang Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-catalyzed carbonylative coupling reactions between Ar–X and carbon nucleophiles

(2011) Xiao-Feng Wu et al.   CHEMICAL SOCIETY REVIEWS

Palladium-Catalyzed Carbonylative CH Activation of Heteroarenes

(2010) Xiao-Feng Wu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions

(2010) Thomas W. Lyons et al.   CHEMICAL REVIEWS

Overview of the Mechanistic Work on the Concerted Metallation–Deprotonation Pathway

(2010) David Lapointe et al.   CHEMISTRY LETTERS

Pd-catalysed carbonylations: versatile technology for discovery and process chemists

(2010) Ronald Grigg et al.   TETRAHEDRON

Palladium(II)-Catalyzed CH Activation/CC Cross-Coupling Reactions: Versatility and Practicality

(2009) Xiao Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed C−C Bond Formation via Heteroatom-Directed C−H Bond Activation

(2009) Denise A. Colby et al.   CHEMICAL REVIEWS

Multicatalytic Synthesis of α-Pyrrolidinyl Ketones via a Tandem Palladium(II)/Indium(III)-Catalyzed Aminochlorocarbonylation/Friedel−Crafts Acylation Reaction

(2009) Tim A. Cernak et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY