Ketenimines from Isocyanides and Allyl Carbonates: Palladium-Catalyzed Synthesis of β,γ-Unsaturated Amides and Tetrazoles

Synthesis of Diversely Functionalized Oxindoles Enabled by Migratory Insertion of Isocyanide to a Transient σ-Alkylpalladium(II) Complex

(2016) Wangqing Kong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Migratory Insertion of Isocyanides for Synthesis of C-Phosphonoketenimines

(2016) Qiang Yang et al.   ACS Catalysis

Tuning the Reactivity of Isocyano Group: Synthesis of Imidazoles and Imidazoliums from Propargylamines and Isonitriles in the Presence of Multiple Catalysts

(2014) Shuo Tong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Sustainable Three-Component Synthesis of Isothioureas from Isocyanides, Thiosulfonates, and Amines

(2014) Pieter Mampuys et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-catalyzed selective aminoamidation and aminocyanation of alkenes using isonitrile as amide and cyanide sources

(2014) Huanfeng Jiang et al.   CHEMICAL COMMUNICATIONS

Palladium(0)-Catalyzed Single and Double Isonitrile Insertion: A Facile Synthesis of Benzofurans, Indoles, and Isatins

(2014) Gopal Chandru Senadi et al.   CHEMISTRY-A EUROPEAN JOURNAL

Palladium-Catalyzed Imidoylative Cyclization of α-Isocyanoacetamides: Efficient Access to C2-Diversified Oxazoles

(2014) Jian Wang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Silver-Catalyzed Cross-Coupling of Propargylic Alcohols with Isocyanides: An Atom-Economical Synthesis of 2,3-Allenamides

(2014) Jianquan Liu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Comparative Reactivity of Different Types of Stable Cyclic and Acyclic Mono- and Diamino Carbenes with Simple Organic Substrates

(2014) David Martin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Triple Role of Phenylselenonyl Group Enabled a One-Pot Synthesis of 1,3-Oxazinan-2-ones From α-Isocyanoacetates, Phenyl Vinyl Selenones, and Water

(2014) Thomas Buyck et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ligand-Controlled Regiodivergent Ni-Catalyzed Reductive Carboxylation of Allyl Esters with CO2

(2014) Toni Moragas et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Overcoming the limitations of directed C–H functionalizations of heterocycles

(2014) Yue-Jin Liu et al.   NATURE

Palladium-Catalyzed Tandem Intramolecular Oxy/Amino-Palladation/Isocyanide Insertion: Synthesis of α-Benzofuranyl/Indolylacetamides

(2014) Nuligonda Thirupathi et al.   ORGANIC LETTERS

Insertion of Isocyanides across the Pd–C Bond of Phosphinoquinoline Allyl Palladium Complexes Bearing η1- and η3-Coordinated Allyl Groups. A Synthetic and Mechanistic Study

(2014) L. Canovese et al.   ORGANOMETALLICS

Synthesis of 1,4-Benzoxazepine Derivativesviaa Novel Domino Aziridine Ring-Opening and Isocyanide-Insertion Reaction

(2013) Fei Ji et al.   ADVANCED SYNTHESIS & CATALYSIS

An Efficient Route to 3-Amidylindolesviaa Palladium- Catalyzed Tandem Reaction of 2-Alkynylanilines with Isocyanides

(2013) Guanyinsheng Qiu et al.   ADVANCED SYNTHESIS & CATALYSIS

Switchable Synthesis of 3-Cyanoindoles and 3-Amidylindolesviaa Palladium-Catalyzed Reaction ofN,N-Dimethyl-2-alkynylaniline with Isocyanide

(2013) Guanyinsheng Qiu et al.   ADVANCED SYNTHESIS & CATALYSIS

Zinc Bromide Promoted Coupling of Isonitriles with Carboxylic Acids To Form 2,4,5-Trisubstituted Oxazoles

(2013) Yann Odabachian et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Domino Catalysis: Palladium-Catalyzed Carbonylation of Allylic Alcohols to β,γ-Unsaturated Esters

(2013) Qiang Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Enantioselective Michael Addition of α-Aryl-α-Isocyanoacetates to Vinyl Selenone: Synthesis of α,α-Disubstituted α-Amino Acids and (+)- and (−)-Trigonoliimine A

(2013) Thomas Buyck et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Migratory Insertion of Isocyanides: An Emerging Platform in Cross-Coupling Chemistry

(2013) Tjøstil Vlaar et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of palmyrolide A and its cis-isomer and mechanistic insight into trans–cis isomerisation of the enamide macrocycle

(2013) Satish Chandra Philkhana et al.   CHEMICAL COMMUNICATIONS

Recent advances in isocyanide insertion chemistry

(2013) Guanyinsheng Qiu et al.   CHEMICAL SOCIETY REVIEWS

Unravelling the labyrinth of palladium-catalysed reactions involving isocyanides

(2013) Stuart Lang   CHEMICAL SOCIETY REVIEWS

Palladium-Catalyzed Multicomponent Synthesis of 2-Aryl-2-imidazolines from Aryl Halides and Diamines

(2013) Joanna V. Geden et al.   JOURNAL OF ORGANIC CHEMISTRY

Palladium-Catalyzed Carbonylative Sonogashira Coupling of Aryl Bromides via tert-Butyl Isocyanide Insertion

(2013) Ting Tang et al.   JOURNAL OF ORGANIC CHEMISTRY

Mechanistic Exploration of the Palladium-catalyzed Process for the Synthesis of Benzoxazoles and Benzothiazoles

(2013) Valentin N. Bochatay et al.   JOURNAL OF ORGANIC CHEMISTRY

Synthesis of Substituted Pyridines from Cascade [1 + 5] Cycloaddition of Isonitriles to N-Formylmethyl-Substituted Enamides, Aerobic Oxidative Aromatization, and Acyl Transfer Reaction

(2013) Chuan-Hu Lei et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd-Catalyzed One-Pot Synthesis of Polysubstituted Acrylamidines from Isocyanides, Diazo Compounds, and Imines

(2013) Xu Yan et al.   ORGANIC LETTERS

Synthesis of 3-Acyl-2-arylindole via Palladium-catalyzed Isocyanide Insertion and Oxypalladation of Alkyne

(2013) Takeshi Nanjo et al.   ORGANIC LETTERS

Sustainable Synthesis of Diverse Privileged Heterocycles by Palladium-Catalyzed Aerobic Oxidative Isocyanide Insertion

(2012) Tjøstil Vlaar et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The thriving chemistry of ketenimines

(2012) Ping Lu et al.   CHEMICAL SOCIETY REVIEWS

Recent Highlights in Ketenimine Chemistry

(2012) Mateo Alajarin et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Synthesis and Functionalization of 5-Substituted Tetrazoles

(2012) Jaroslav Roh et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Palladium-Catalyzed C(sp2)–H Cyanation Using Tertiary Amine Derived Isocyanide as a Cyano Source

(2012) Jiangling Peng et al.   ORGANIC LETTERS

Palladium-Catalyzed Cascade Process Consisting of Isocyanide Insertion and Benzylic C(sp3)–H Activation: Concise Synthesis of Indole Derivatives

(2012) Takeshi Nanjo et al.   ORGANIC LETTERS

Palladium-Assisted Regioselective C–H Cyanation of Heteroarenes Using Isonitrile as Cyanide Source

(2012) Shuguang Xu et al.   ORGANIC LETTERS

Renaissance of Organic Synthesis Using Isocyanides

(2011) Mamoru Tobisu et al.   CHEMISTRY LETTERS

Palladium-Catalyzed Amidation of N-Tosylhydrazones with Isocyanides

(2011) Fengtao Zhou et al.   CHEMISTRY-A EUROPEAN JOURNAL

Sulfonyl and Phosphoryl Azides: Going Further Beyond the Click Realm of Alkyl and Aryl Azides

(2011) Seok Hwan Kim et al.   Chemistry-An Asian Journal

Reaction of β-Lactam Carbenes with 2-Pyridyl Isonitriles: A One-Pot Synthesis of 2-Carbonyl-3-(pyridylamino)imidazo[1,2-a]pyridines Useful as Fluorescent Probes for Mercury Ion

(2011) Na Shao et al.   JOURNAL OF ORGANIC CHEMISTRY

Synthesis of Amides via Palladium-Catalyzed Amidation of Aryl Halides

(2011) Huanfeng Jiang et al.   ORGANIC LETTERS

Palladium-Catalyzed Intramolecular C(sp2)–H Amidination by Isonitrile Insertion Provides Direct Access to 4-Aminoquinazolines fromN-Arylamidines

(2011) Yong Wang et al.   ORGANIC LETTERS

Palladium-Catalyzed Denitrogenation Reaction of 1,2,3-Benzotriazin-4(3H)-ones Incorporating Isocyanides

(2011) Tomoya Miura et al.   ORGANIC LETTERS

Isocyanides in the Synthesis of Nitrogen Heterocycles

(2010) Alexander V. Lygin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Cyclocoupling of 2-Halobiaryls with Isocyanides via the Cleavage of Carbon−Hydrogen Bonds

(2010) Mamoru Tobisu et al.   JOURNAL OF ORGANIC CHEMISTRY

Zinc Chloride Promoted Formal Oxidative Coupling of Aromatic Aldehydes and Isocyanides to α-Ketoamides

(2010) Marinus Bouma et al.   JOURNAL OF ORGANIC CHEMISTRY

Palladium-catalyzed Decarboxylative [4+1] Cyclization of γ-Methylidene-δ-valerolactones with Isocyanides

(2009) Soyoung Park et al.   CHEMISTRY LETTERS

Copper-Catalyzed Multicomponent Reactions: Securing a Catalytic Route to Ketenimine Intermediates and their Reactivities

(2009) Eun Yoo et al.   CURRENT ORGANIC CHEMISTRY

Isocyanide-Based Two-Step Three-Component Keteneimine Formation

(2009) Didier Coffinier et al.   ORGANIC LETTERS

Migratory Insertion of Allyl Groups across the Pd−C Bond in Palladium(II) Isocyanide Complexes. The Fundamental Interplay between Temperature and Allyl Hapticity

(2009) Luciano Canovese et al.   ORGANOMETALLICS

Synthesis of α-Ketoamides by a Molecular-Sieves-Promoted Formal Oxidative Coupling of Aliphatic Aldehydes with Isocyanides

(2007) Jean-Marie Grassot et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION