Rh(iii)-catalyzed C–H activation/cycloaddition of benzamides and methylenecyclopropanes: divergence in ring formation

Rhodium(III)-Catalyzed CC Coupling between Arenes and Aziridines by CH Activation

(2013) Xingwei Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mild Rhodium(III)-Catalyzed Cyclization of Amides with α,β-Unsaturated Aldehydes and Ketones to Azepinones: Application to the Synthesis of the Homoprotoberberine Framework

(2013) Zhuangzhi Shi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

General and Efficient Synthesis of Indoles through Triazene-Directed C-H Annulation

(2013) Chengming Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A General Method to Diverse Cinnolines and Cinnolinium Salts

(2013) Dongbing Zhao et al.   CHEMISTRY-A EUROPEAN JOURNAL

A Tunable Class of Chiral Cp Ligands for Enantioselective Rhodium(III)-Catalyzed C–H Allylations of Benzamides

(2013) Baihua Ye et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Diverse Reactivity in a Rhodium(III)-Catalyzed Oxidative Coupling ofN-Allyl Arenesulfonamides with Alkynes

(2012) Dongqi Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium(III)-Catalyzed Intramolecular Annulation through CH Activation: Total Synthesis of (±)-Antofine, (±)-Septicine, (±)-Tylophorine, and Rosettacin

(2012) Xianxiu Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium/Copper-Catalyzed Annulation of Benzimides with Internal Alkynes: Indenone Synthesis through Sequential CH and CN Cleavage

(2012) Bi-Jie Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mild Rhodium(III)-Catalyzed CH Activation and Intermolecular Annulation with Allenes

(2012) Honggen Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Access to Sultams by Rhodium(III)-Catalyzed Directed CH Activation

(2012) Manh V. Pham et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium(III)-Catalyzed CH Activation of Arenes Using a Versatile and Removable Triazene Directing Group

(2012) Chengming Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium(III)-Catalyzed Oxidative CH Coupling ofN-Methoxybenzamides with Aryl Boronic Acids: One-Pot Synthesis of Phenanthridinones

(2012) Jaganathan Karthikeyan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

C–C, C–O and C–N bond formation via rhodium(iii)-catalyzed oxidative C–H activation

(2012) Guoyong Song et al.   CHEMICAL SOCIETY REVIEWS

Ruthenium-Catalyzed Hydroarylation of Methylenecyclopropanes through CH Bond Cleavage: Scope and Mechanism

(2012) Lutz Ackermann et al.   CHEMISTRY-A EUROPEAN JOURNAL

Amide-Directed Tandem CC/CN Bond Formation through CH Activation

(2012) Chen Zhu et al.   Chemistry-An Asian Journal

Bromine Radical-Mediated Sequential Radical Rearrangement and Addition Reaction of Alkylidenecyclopropanes

(2012) Takashi Kippo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Selective Mild Stepwise Allylation of N-Methoxybenzamides with Allenes

(2012) Rong Zeng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed Intermolecular Amidation of Arenes with Sulfonyl Azides via Chelation-Assisted C–H Bond Activation

(2012) Ji Young Kim et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereoselective Rhodium-Catalyzed [3 + 2 + 1] Carbocyclization of Alkenylidenecyclopropanes with Carbon Monoxide: Theoretical Evidence for a Trimethylenemethane Metallacycle Intermediate

(2012) Shivnath Mazumder et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh-Catalyzed Intermolecular Carbenoid Functionalization of Aromatic C–H Bonds by α-Diazomalonates

(2012) Wai-Wing Chan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mild Rh(III)-Catalyzed C–H Activation and Annulation with Alkyne MIDA Boronates: Short, Efficient Synthesis of Heterocyclic Boronic Acid Derivatives

(2012) Honggen Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed Cascade Oxidative Annulation Leading to Substituted Naphtho[1,8-bc]pyrans by Sequential Cleavage of C(sp2)–H/C(sp3)–H and C(sp2)–H/O–H Bonds

(2012) Xing Tan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ruthenium-catalyzed C–H/O–H and C–H/N–H bond functionalizations: oxidative annulations of cyclopropyl-substituted alkynes

(2012) Monica Deponti et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Direct Synthesis of Methylene-1,2-dichalcogenolanes via Radical [3 + 2] Cycloaddition of Methylenecyclopropanes with Elemental Chalcogens

(2012) Lei Yu et al.   ORGANIC LETTERS

Biotinylated Rh(III) Complexes in Engineered Streptavidin for Accelerated Asymmetric C-H Activation

(2012) T. K. Hyster et al.   SCIENCE

Chiral Cyclopentadienyl Ligands as Stereocontrolling Element in Asymmetric C-H Functionalization

(2012) B. Ye et al.   SCIENCE

Rapid Generation of Molecular Complexity in the Lewis or Brønsted Acid-Mediated Reactions of Methylenecyclopropanes

(2011) Min Shi et al.   ACCOUNTS OF CHEMICAL RESEARCH

Palladium-Catalyzed Tunable Functionalization of Allylic Imidates: Regioselective Aminodiacetoxylation and Aziridination

(2011) Sunliang Cui et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Isoquinolines from α-Aryl Vinyl Azides and Internal Alkynes by Rh-Cu Bimetallic Cooperation

(2011) Yi-Feng Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Carboxylate-Assisted Transition-Metal-Catalyzed C−H Bond Functionalizations: Mechanism and Scope

(2011) Lutz Ackermann   CHEMICAL REVIEWS

Enantioselective methodologies for the synthesis of spiro compounds

(2011) Ramon Rios   CHEMICAL SOCIETY REVIEWS

Strained small rings in gold-catalyzed rapid chemical transformations

(2011) Bei-Li Lu et al.   CHEMICAL SOCIETY REVIEWS

Computational Elucidation of the Internal Oxidant-Controlled Reaction Pathways in Rh(III)-Catalyzed Aromatic C–H Functionalization

(2011) Liang Xu et al.   JOURNAL OF ORGANIC CHEMISTRY

Rhodium(III)-Catalyzed Arylation of Boc-Imines via C−H Bond Functionalization

(2011) Andy S. Tsai et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh(III)-Catalyzed Directed C−H Olefination Using an Oxidizing Directing Group: Mild, Efficient, and Versatile

(2011) Souvik Rakshit et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium(III)-Catalyzed Heterocycle Synthesis Using an Internal Oxidant: Improved Reactivity and Mechanistic Studies

(2011) Nicolas Guimond et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cellular Localization of Debromohymenialdisine and Hymenialdisine in the Marine Sponge Axinella sp. Using a Newly Developed Cell Purification Protocol

(2011) Yue-Fan Song et al.   MARINE BIOTECHNOLOGY

Pd-Catalyzed C4-Olefination of Oxazoles via C–H Bond Activation: Divergent Synthesis of Functionalized Amino Alcohol and Amino Acid Derivatives

(2011) Sunliang Cui et al.   ORGANIC LETTERS

Transition-Metal-Catalyzed Rearrangements of Small Cycloalkanes: Regioselectivity Trends in β-Carbon Elimination Reactions

(2011) Christophe Aïssa   SYNTHESIS-STUTTGART

An improved catalyst architecture for rhodium(iii) catalyzed C–H activation and its application to pyridone synthesis

(2011) Todd K. Hyster et al.   Chemical Science

Synthesis of Nine-Membered Carbocycles by the [4+3+2] Cycloaddition Reaction of Ethyl Cyclopropylideneacetate and Dienynes

(2010) Shinichi Saito et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Vinyl Moiety as a Handle for Regiocontrol in the Preparation of Unsymmetrical 2,3-Aliphatic-Substituted Indoles and Pyrroles

(2010) Malcolm P. Huestis et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chemistry of Vinylidenecyclopropanes

(2010) Min Shi et al.   CHEMICAL REVIEWS

Selectivity in Metal-Catalyzed CarbonCarbon Bond Cleavage of Alkylidenecyclopropanes

(2010) Ahmad Masarwa et al.   CHEMISTRY-A EUROPEAN JOURNAL

Palladium-Catalyzed Arylation Reactions: A Mechanistic Perspective

(2010) Madeleine Livendahl et al.   ISRAEL JOURNAL OF CHEMISTRY

Targeting the Polyamine Transport System with Benzazepine- and Azepine-Polyamine Conjugates†

(2010) Sophie Tomasi et al.   JOURNAL OF MEDICINAL CHEMISTRY

Rhodium(III)-Catalyzed Isoquinolone Synthesis: The N−O Bond as a Handle for C−N Bond Formation and Catalyst Turnover

(2010) Nicolas Guimond et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed Oxidative Cycloaddition of Benzamides and Alkynes via C−H/N−H Activation

(2010) Todd K. Hyster et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Transition-Metal-Catalyzed Regioselective Arylation and Vinylation of Carboxylic Acids

(2010) Tetsuya Satoh et al.   SYNTHESIS-STUTTGART

Recent developments in the reactivity of methylene- and alkylidenecyclopropane derivatives

(2010) Hélène Pellissier   TETRAHEDRON

Combined Rhodium-Catalyzed Carbon-Hydrogen Activation and β-Carbon Elimination to access Eight-Membered Rings

(2009) Damien Crépin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

CID755673 enhances mitogenic signaling by phorbol esters, bombesin and EGF through a protein kinase D-independent pathway

(2009) Eugenia Torres-Marquez et al.   BIOCHEMICAL AND BIOPHYSICAL RESEARCH COMMUNICATIONS

Structure−Activity Relationship Analysis of Novel Derivatives of Narciclasine (anAmaryllidaceaeIsocarbostyril Derivative) as Potential Anticancer Agents

(2009) Laurent Ingrassia et al.   JOURNAL OF MEDICINAL CHEMISTRY

Synthesis of Indoles via Domino Reaction ofN-Aryl Amides and Ethyl Diazoacetate

(2008) Sun-Liang Cui et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An Efficient Low-Temperature Route to Polycyclic Isoquinoline Salt Synthesis via C−H Activation with [Cp*MCl2]2(M = Rh, Ir)

(2008) Ling Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Indole Synthesis via Rhodium Catalyzed Oxidative Coupling of Acetanilides and Internal Alkynes

(2008) David R. Stuart et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ruthenium-Catalyzed Hydroarylations of Methylenecyclopropanes: Mild C−H Bond Functionalizations with Conservation of Cyclopropane Rings

(2008) Sergei I. Kozhushkov et al.   ORGANIC LETTERS

Rhodium- and iridium-catalyzed oxidative coupling of benzoic acids with alkynes and alkenes

(2008) Tetsuya Satoh et al.   PURE AND APPLIED CHEMISTRY

Design, Synthesis, and Biological Evaluation of Caprolactam-Modified Bengamide Analogues

(2007) Gang Liu et al.   ChemMedChem