4.6 Article

Synthesis of N-CuMe2Pc nanorods/graphene oxide nanocomposite for symmetric supercapacitor electrode with excellent cyclic stability

期刊

ELECTROCHIMICA ACTA
卷 298, 期 -, 页码 770-777

出版社

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2018.12.163

关键词

Phthalocyanine; Nanocomposite; Graphene oxide; Specific capacitance; Cyclic stability

资金

  1. Special Funds for the Development of Strategic Emerging Industries in Shenzhen [JCYJ20170412154240645]
  2. National Natural Science Foundation of China [51505209]
  3. Shenzhen Science and Technology Innovation Committee [JCYJ20170412154426330]
  4. Guangdong Natural Science Funds for Distinguished Young Scholar [2016A030306042]
  5. Guangdong Special Support Program [2015TQ01X555]

向作者/读者索取更多资源

Recent progress in the construction of non-peripheral octamethyl-substituted copper(II) phthalocyanine (N-CuMe2Pc) has opened up new strategies for energy storage applications. Since metal phthalocyanines can deliver excellent redox activities, we have prepared composite based on different ratios of NCuMe2Pc and graphene oxide (GO) through a simple ultrasound process and evaluated their electrochemical performance for supercapacitor applications. As-prepared composites exhibit superior electrochemical activities as the results of the synergistic effect. A maximum specific capacitance of 291.6 F g(-1) is achieved for the G10P2 electrode (Graphene oxide 10 mg and N-CuMe2Pc 2 mg) at 0.5 A g(-1) which two times higher than their individual components. Further, the fabricated symmetric device shows that the excellent cyclic stability of about 100.1% over 5000 cycles. The experimental findings ensure the potential application of copper-phthalocyanine/ GO composite as an electrode material for the next-generation supercapacitor applications. (c) 2018 Elsevier Ltd. All rights reserved.

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