Palladium(II)-Catalyzed Enantioselective Aminotrifluoromethoxylation of Unactivated Alkenes using CsOCF3 as a Trifluoromethoxide Source

Catalytic C−H Trifluoromethoxylation of Arenes and Heteroarenes

(2018) Weijia Zheng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Radical Trifluoromethoxylation of Arenes Triggered by a Visible-Light-Mediated N-O Redox Fragmentation

(2018) Antonio Togni et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric synthesis of α-trifluoromethoxy ketones with a tetrasubstituted α-stereogenic centre via the palladium-catalyzed decarboxylative allylic alkylation of allyl enol carbonates

(2018) Hiroya Kondo et al.   CHEMICAL COMMUNICATIONS

Fluorine and Fluorinated Motifs in the Design and Application of Bioisosteres for Drug Design

(2018) Nicholas A. Meanwell   JOURNAL OF MEDICINAL CHEMISTRY

Trifluoromethyl Benzoate: A Versatile Trifluoromethoxylation Reagent

(2018) Min Zhou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Intermolecular Ditrifluoromethoxylation of Unactivated Alkenes: CF3O-Palladation Initiated by Pd(IV)

(2018) Chaohuang Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Pd(II)-Catalyzed Intramolecular Oxidative 6-endo Aminoacetoxylation of Unactivated Alkenes

(2018) Xiaoxu Qi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Controlling Pd(iv) reductive elimination pathways enables Pd(ii)-catalysed enantioselective C(sp3)−H fluorination

(2018) Hojoon Park et al.   Nature Chemistry

Redox-Active Reagents for Photocatalytic Generation of the OCF3 Radical and (Hetero)Aryl C−H Trifluoromethoxylation

(2018) Weijia Zheng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric silver-catalysed intermolecular bromotrifluoromethoxylation of alkenes with a new trifluoromethoxylation reagent

(2017) Shuo Guo et al.   Nature Chemistry

Palladium(II)-Catalyzed Oxidative Difunctionalization of Alkenes: Bond Forming at a High-Valent Palladium Center

(2016) Guoyin Yin et al.   ACCOUNTS OF CHEMICAL RESEARCH

Synthetic Approaches to Trifluoromethoxy-Substituted Compounds

(2016) Anis Tlili et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

18F-Labeling of Arenes and Heteroarenes for Applications in Positron Emission Tomography

(2016) Sean Preshlock et al.   CHEMICAL REVIEWS

The unique fluorine effects in organic reactions: recent facts and insights into fluoroalkylations

(2016) Chuanfa Ni et al.   CHEMICAL SOCIETY REVIEWS

New entries toward the synthesis of OCF3-containing molecules

(2016) Tatiana Besset et al.   Organic Chemistry Frontiers

Carbon Trifluoromethylation Reactions of Hydrocarbon Derivatives and Heteroarenes

(2015) Concepción Alonso et al.   CHEMICAL REVIEWS

Aryl-BIAN-ligated silver(i) trifluoromethoxide complex

(2015) Shouxiong Chen et al.   DALTON TRANSACTIONS

Applications of Fluorine in Medicinal Chemistry

(2015) Eric P. Gillis et al.   JOURNAL OF MEDICINAL CHEMISTRY

Palladium-Catalyzed Enantioselective 1,1-Fluoroarylation of Aminoalkenes

(2015) Ying He et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Intramolecular Aminotrifluoromethoxylation of Alkenes

(2015) Chaohuang Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Trifluoromethoxylation of Arenes: Synthesis ofortho-Trifluoromethoxylated Aniline Derivatives by OCF3Migration

(2014) Katarzyna N. Hojczyk et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Modern Carbon–Fluorine Bond Forming Reactions for Aryl Fluoride Synthesis

(2014) Michael G. Campbell et al.   CHEMICAL REVIEWS

Advances in Catalytic Enantioselective Fluorination, Mono-, Di-, and Trifluoromethylation, and Trifluoromethylthiolation Reactions

(2014) Xiaoyu Yang et al.   CHEMICAL REVIEWS

Trifluoromethyltrimethylsilane: Nucleophilic Trifluoromethylation and Beyond

(2014) Xiao Liu et al.   CHEMICAL REVIEWS

Asymmetric Palladium-Catalyzed Directed Intermolecular Fluoroarylation of Styrenes

(2014) Eric P. A. Talbot et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-mediated/-catalyzed fluorination reactions: new routes to aryl fluorides

(2014) Xin Mu et al.   Organic Chemistry Frontiers

Fluorine in Pharmaceutical Industry: Fluorine-Containing Drugs Introduced to the Market in the Last Decade (2001–2011)

(2013) Jiang Wang et al.   CHEMICAL REVIEWS

Catalytic Enantioselective Cyclization and C3-Fluorination of Polyenes

(2013) Nikki A. Cochrane et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent Advances in Transition-Metal-Catalyzed Trifluoromethylation and Related Transformations

(2013) Guosheng Liu et al.   SYNTHESIS-STUTTGART

Oxygen-Bound Trifluoromethoxide Complexes of Copper and Gold

(2012) Cheng-Pan Zhang et al.   ORGANOMETALLICS

Transition metal catalysis and nucleophilic fluorination

(2011) Charlotte Hollingworth et al.   CHEMICAL COMMUNICATIONS

Silver-Mediated Trifluoromethoxylation of Aryl Stannanes and Arylboronic Acids

(2011) Chenghong Huang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A New and Direct Trifluoromethoxylation of Aliphatic Substrates with 2,4-Dinitro(trifluoromethoxy)benzene

(2010) Olivier Marrec et al.   ADVANCED SYNTHESIS & CATALYSIS

The Organometallic Fluorine Chemistry of Palladium and Rhodium: Studies toward Aromatic Fluorination

(2009) Vladimir V. Grushin   ACCOUNTS OF CHEMICAL RESEARCH

A deeper insight into direct trifluoromethoxylation with trifluoromethyl triflate

(2009) Olivier Marrec et al.   JOURNAL OF FLUORINE CHEMISTRY

Update 1 of: Asymmetric Fluorination, Trifluoromethylation, and Perfluoroalkylation Reactions

(2008) Jun-An Ma et al.   CHEMICAL REVIEWS