Catalytic C-2 Allylation of Indoles by Electronic Modulation of the Indole Ring and its Application to the Synthesis of Functionalized Carbazoles

Palladium-Catalyzed Arylboration of Bicyclic Alkenes

(2016) Kai Yang et al.   JOURNAL OF ORGANIC CHEMISTRY

Synthesis of Carbazoles and Carbazole-Containing Heterocycles via Rhodium-Catalyzed Tandem Carbonylative Benzannulations

(2016) Wangze Song et al.   JOURNAL OF ORGANIC CHEMISTRY

One-pot synthesis of carbazoles via tandem C–C cross-coupling and reductive amination

(2016) Deuk-Young Goo et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Catalytic Cage Formation via Controlled Dimerization of Norbornadienes: An Entry to Functionalized HCTDs (Heptacyclo[6.6.0.02,6.03,13.04,11.05,9.010,14]tetradecanes)

(2016) Hee Nam Lim et al.   ORGANIC LETTERS

Achievement of regioselectivity in transition metal-catalyzed direct C–H (hetero)arylation reactions of heteroarenes with one heteroatom through the use of removable protecting/blocking substituents or traceless directing groups

(2016) Renzo Rossi et al.   TETRAHEDRON

Transition Metal-Catalyzed CH Activation of Indoles

(2015) Alexander H. Sandtorv   ADVANCED SYNTHESIS & CATALYSIS

Dehydrogenative Carbon-Carbon Bond Formation Using Alkynyloxy Moieties as Hydrogen-Accepting Directing Groups

(2015) Yasunori Minami et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

[Cu(NHC)]-Catalyzed C−H Allylation and Alkenylation of both Electron-Deficient and Electron-Rich (Hetero)arenes with Allyl Halides

(2015) Weilong Xie et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Dehydrative Direct CH Allylation with Allylic Alcohols under [Cp*CoIII] Catalysis

(2015) Yudai Suzuki et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cationic Iridium/S-Me-BIPAM-Catalyzed Direct Asymmetric Intermolecular Hydroarylation of Bicycloalkenes

(2015) Tomohiko Shirai et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium/norbornene chemistry: an unexpected route to methanocarbazole derivatives via three Csp3–Csp2/Csp3–N/Csp2–N bond formations in a single synthetic sequence

(2015) Farnaz Jafarpour et al.   CHEMICAL COMMUNICATIONS

Oxidative Coupling between Two Hydrocarbons: An Update of Recent C–H Functionalizations

(2015) Chao Liu et al.   CHEMICAL REVIEWS

Pd(II)-Catalyzed CH Activation of Styrylindoles: Short, Efficient, and Regioselective Synthesis of Functionalized Carbazoles

(2015) Rakesh K. Saunthwal et al.   CHEMISTRY-A EUROPEAN JOURNAL

Evolution of C–H Bond Functionalization from Methane to Methodology

(2015) John F. Hartwig   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper(I)–Taniaphos Catalyzed Enantiodivergent Hydroboration of Bicyclic Alkenes

(2015) Hyesu Lee et al.   ORGANIC LETTERS

Palladium-Catalyzed Triple Successive C–H Functionalization: Direct Synthesis of Functionalized Carbazoles from Indoles

(2015) Akhilesh K. Verma et al.   ORGANIC LETTERS

Direct Synthesis of N-H Carbazoles via Iridium(III)-Catalyzed Intramolecular C–H Amination

(2015) Chiharu Suzuki et al.   ORGANIC LETTERS

Rh-catalyzed C-C bond cleavage by transfer hydroformylation

(2015) S. K. Murphy et al.   SCIENCE

Synthesis of Carbazoles by a Merged Visible Light Photoredox and Palladium-Catalyzed Process

(2015) Sungkyu Choi et al.   ACS Catalysis

Electronically Matching C−H Alkylation Strategies for the Synthesis of α-Heteroaryl Acetic Acid Derivatives

(2015) Ha-Lim Jang et al.   Asian Journal of Organic Chemistry

Palladium-Catalyzed Intermolecular C-2 Alkenylation of Indoles Using Oxygen as the Oxidant

(2014) Zhao-Lei Yan et al.   ADVANCED SYNTHESIS & CATALYSIS

Rhodium(III)-Catalyzed Direct C-2 Olefination of Unactivated Indoles Utilizing OH/NH2as Directing Group

(2014) Chen-Yu Tang et al.   ADVANCED SYNTHESIS & CATALYSIS

Rhodium(III)-Catalyzed Regioselective Direct C-2 Alkenylation of Indoles Assisted by the Removable N-(2-Pyrimidyl) Group

(2014) Binwei Gong et al.   ADVANCED SYNTHESIS & CATALYSIS

An Efficient Rhodium/Oxygen Catalytic System for Oxidative Heck Reaction of Indoles and AlkenesviaCH Functionalization

(2014) Lei Yang et al.   ADVANCED SYNTHESIS & CATALYSIS

Studies on Palladium-Catalyzed Synthesis of Dihydrocycloocta- [b]indoles and their Thermal Reactivities with Maleimide or Maleic Anhydride

(2014) Can Zhu et al.   ADVANCED SYNTHESIS & CATALYSIS

Rapid Synthesis of Fused N-Heterocycles by Transition-Metal-Free Electrophilic Amination of Arene CH Bonds

(2014) Hongyin Gao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct allylation of aromatic and α,β-unsaturated carboxamides under ruthenium catalysis

(2014) Mirim Kim et al.   CHEMICAL COMMUNICATIONS

Hydrogen-Bond-Assisted Activation of Allylic Alcohols for Palladium-Catalyzed Coupling Reactions

(2014) Yasemin Gumrukcu et al.   ChemSusChem

Catalytic C–H Allylation and Benzylation of Pyrazoles

(2014) Seri Bae et al.   JOURNAL OF ORGANIC CHEMISTRY

Palau’chlor: A Practical and Reactive Chlorinating Reagent

(2014) Rodrigo A. Rodriguez et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Dearomative Trimethylenemethane Cycloaddition Reactions

(2014) Barry M. Trost et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Efficient Carbazole Synthesis via Pd/Cu-Cocatalyzed Cross-Coupling/Isomerization of 2-Allyl-3-iodoindoles and Terminal Alkynes

(2014) Can Zhu et al.   ORGANIC LETTERS

Palladium(II)-Catalyzed Efficient C-3 Functionalization of Indoles with Benzylic and Allylic Alcohols under Co-Catalyst, Acid, Base, Additive and External Ligand-Free Conditions

(2013) Debjit Das et al.   ADVANCED SYNTHESIS & CATALYSIS

Palladium(II)/Polyoxometalate-Catalyzed Direct C-3 Alkenylation of Indoles using Dioxygen as the Terminal Oxidant

(2013) Qiufeng Huang et al.   ADVANCED SYNTHESIS & CATALYSIS

Mild Rhodium(III)-Catalyzed Direct CH Allylation of Arenes with Allyl Carbonates

(2013) Honggen Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Aerobic Ru-catalyzed direct C2-olefination of N-heteroarenes with alkenes directed by a removable N-dimethylcarbamoyl group

(2013) Luo-Qiang Zhang et al.   CHEMICAL COMMUNICATIONS

Regioselective C2 Oxidative Olefination of Indoles and Pyrroles through Cationic Rhodium(III)-Catalyzed CH Bond Activation

(2013) Bin Li et al.   CHEMISTRY-A EUROPEAN JOURNAL

Ruthenium-Catalyzed Regioselective C2 Alkenylation of Indoles and Pyrroles via C–H Bond Functionalization

(2013) Bin Li et al.   JOURNAL OF ORGANIC CHEMISTRY

Developing Ligands for Palladium(II)-Catalyzed C–H Functionalization: Intimate Dialogue between Ligand and Substrate

(2013) Keary M. Engle et al.   JOURNAL OF ORGANIC CHEMISTRY

C–H bond activation enables the rapid construction and late-stage diversification of functional molecules

(2013) Joanna Wencel-Delord et al.   Nature Chemistry

A novel neutral organic electron donor with record half-wave potential

(2013) Hardeep S. Farwaha et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Synthesis and C2-functionalization of indoles with allylic acetates under rhodium catalysis

(2013) Mirim Kim et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Highly Regioselective C2-Alkenylation of Indoles Using the N-Benzoyl Directing Group: An Efficient Ru-Catalyzed Coupling Reaction

(2013) Veeranjaneyulu Lanke et al.   ORGANIC LETTERS

One-shot indole-to-carbazole π-extension by a Pd–Cu–Ag trimetallic system

(2013) Kyohei Ozaki et al.   Chemical Science

Synthesis of Pyrroles, Indoles, and Carbazoles through Transition-Metal-Catalyzed CH Functionalization

(2013) Naohiko Yoshikai et al.   Asian Journal of Organic Chemistry

One-Pot Approach to Installing Eight-Membered Rings onto Indoles

(2012) Can Zhu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Regio- and Stereocontrolled Introduction of Secondary Alkyl Groups to Electron-Deficient Arenes through Copper-Catalyzed Allylic Alkylation

(2012) Yusuke Makida et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Occurrence, Biogenesis, and Synthesis of Biologically Active Carbazole Alkaloids

(2012) Arndt W. Schmidt et al.   CHEMICAL REVIEWS

Copper- and Phosphine-Ligand-Free Palladium-Catalyzed Direct Allylation of Electron-Deficient Polyfluoroarenes with Allylic Chlorides

(2012) Yan-Bo Yu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Origins of regioselectivity of the palladium-catalyzed (aromatic)CH bond metalation–deprotonation

(2012) Serge I. Gorelsky   COORDINATION CHEMISTRY REVIEWS

Selective Cross-Coupling of Organic Halides with Allylic Acetates

(2012) Lukiana L. Anka-Lufford et al.   JOURNAL OF ORGANIC CHEMISTRY

Friedel–Crafts-Type Allylation of Nitrogen-Containing Aromatic Compounds with Allylic Alcohols Catalyzed by a [Mo3S4Pd(η3-allyl)] Cluster

(2012) Yinsong Tao et al.   JOURNAL OF ORGANIC CHEMISTRY

Palladium-Catalyzed Intermolecular C3 Alkenylation of Indoles Using Oxygen as the Oxidant

(2012) Wen-Liang Chen et al.   ORGANIC LETTERS

Recent trends in the synthesis of carbazoles: an update

(2012) Joyeeta Roy et al.   TETRAHEDRON

Palladium-catalyzed cascade reactions of 3-iodochromones with aryl iodides and norbornadiene leading to annulated xanthones

(2012) Ming Cheng et al.   Chemical Science

Stereospecific Copper-Catalyzed CH Allylation of Electron-Deficient Arenes with Allyl Phosphates

(2011) Tomoyuki Yao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct Palladium-Catalyzed Intermolecular Allylation of Highly Electron-Deficient Polyfluoroarenes

(2011) Shilu Fan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Reaction of Aryl Iodides with ortho-Bromoanilines and Norbornene/Norbornadiene: Unexpected Formation of Dibenzoazepine Derivatives

(2011) Nicola Della Ca' et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

PdCl2-catalyzed efficient allylation and benzylation of heteroarenes under ligand, base/acid, and additive-free conditions

(2011) Feng-Quan Yuan et al.   CHEMICAL COMMUNICATIONS

Update 1 of: Synthesis and Functionalization of Indoles Through Palladium-Catalyzed Reactions

(2011) Sandro Cacchi et al.   CHEMICAL REVIEWS

Analysis of the Palladium-Catalyzed (Aromatic)C–H Bond Metalation–Deprotonation Mechanism Spanning the Entire Spectrum of Arenes

(2011) Serge I. Gorelsky et al.   JOURNAL OF ORGANIC CHEMISTRY

Intramolecular Oxidative C−H Coupling for Medium-Ring Synthesis

(2011) Didier G. Pintori et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Intramolecular Oxidative C−N Bond Formation for the Synthesis of Carbazoles: Comparison of Reactivity between the Copper-Catalyzed and Metal-Free Conditions

(2011) Seung Hwan Cho et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Straightforward Synthetic Entry to Cleavamine-Type Indole Alkaloids by a Ring-Closing Metathesis−Vinyl Halide Heck Cyclization Strategy

(2011) M.-Lluïsa Bennasar et al.   ORGANIC LETTERS

Ruthenium(IV) Complexes Featuring P,O-Chelating Ligands: Regioselective Substitution Directly from Allylic Alcohols

(2010) Basker Sundararaju et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Concise Total Syntheses of Variecolortides A and B through an Unusual Hetero-Diels-Alder Reaction

(2010) Christian A. Kuttruff et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Total Synthesis of Tryprostatins A and B

(2010) Takayuki Yamakawa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

PdII-Catalysed CH Functionalisation of Indoles and Pyrroles Assisted by the Removable N-(2-Pyridyl)sulfonyl Group: C2-Alkenylation and Dehydrogenative Homocoupling

(2010) Alfonso García-Rubia et al.   CHEMISTRY-A EUROPEAN JOURNAL

Non-Natural Macrocyclic Inhibitors of Histone Deacetylases: Design, Synthesis, and Activity

(2010) Luciana Auzzas et al.   JOURNAL OF MEDICINAL CHEMISTRY

Modulating Reactivity and Diverting Selectivity in Palladium-Catalyzed Heteroaromatic Direct Arylation Through the Use of a Chloride Activating/Blocking Group

(2010) Benoît Liégault et al.   JOURNAL OF ORGANIC CHEMISTRY

Rhodium(III)-Catalyzed Intermolecular Hydroarylation of Alkynes

(2010) Derek J. Schipper et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium(II)-Catalyzed Regioselective Direct C2 Alkenylation of Indoles and Pyrroles Assisted by theN-(2-Pyridyl)sulfonyl Protecting Group

(2009) Alfonso García-Rubia et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Functionalization of Indoles in a New Dimension

(2009) Marco Bandini et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The synthesis of 2- and 3-aryl indoles and 1,3,4,5-tetrahydropyrano[4,3-b]indoles and their antibacterial and antifungal activity

(2009) Tlabo C. Leboho et al.   BIOORGANIC & MEDICINAL CHEMISTRY LETTERS

Anti Human Immunodeficiency Virus-1 (HIV-1) Agents 3. Synthesis and in Vitro Anti-HIV-1 Activity of Some N-Arylsulfonylindoles

(2009) Ling-Ling Fan et al.   CHEMICAL & PHARMACEUTICAL BULLETIN

Fluorescent Diarylindoles by Palladium-Catalyzed Direct and Decarboxylative Arylations of Carboxyindoles

(2009) Mitsuru Miyasaka et al.   CHEMISTRY-A EUROPEAN JOURNAL

Acid-Free Synthesis of Carbazoles and Carbazolequinones by Intramolecular Pd-Catalyzed, Microwave-Assisted Oxidative Biaryl Coupling Reactions - Efficient Syntheses of Murrayafoline A, 2-Methoxy-3-methylcarbazole, and Glycozolidine

(2009) Vellaisamy Sridharan et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Palladium-Catalyzed Annulation of Haloanilines and Halobenzamides Using Norbornadiene as an Acetylene Synthon: A Route to Functionalized Indolines, Isoquinolinones, and Indoles

(2009) Praew Thansandote et al.   JOURNAL OF ORGANIC CHEMISTRY

Stereoselective Synthesis of (+)-Aspidofractinine

(2009) David Gagnon et al.   JOURNAL OF ORGANIC CHEMISTRY

Direct Prenylation of Aromatic and α,β-Unsaturated Carboxamides via Iridium-Catalyzed C−H Oxidative Addition−Allene Insertion

(2009) Yong Jian Zhang et al.   ORGANIC LETTERS

Ligand-Free Pd-Catalyzed Highly Selective Arylation of Allylic Esters with Retention of the Traditional Leaving Group

(2008) Delin Pan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Fast and Highly Regioselective Allylation of Indole and Pyrrole Compounds by Allyl Alcohols Using Ru-Sulfonate Catalysts

(2008) Alexey B. Zaitsev et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ir-Catalyzed Regio- and Enantioselective Friedel–Crafts-Type Allylic Alkylation of Indoles

(2008) Wen-Bo Liu et al.   ORGANIC LETTERS

Regioselective C−H Functionalization Directed by a Removable Carboxyl Group:  Palladium-Catalyzed Vinylation at the Unusual Position of Indole and Related Heteroaromatic Rings

(2008) Atsushi Maehara et al.   ORGANIC LETTERS

Allylation ofN-Heterocycles with Allylic Alcohols Employing Self-Assembling Palladium Phosphane Catalysts

(2008) Ippei Usui et al.   ORGANIC LETTERS