Article
Chemistry, Physical
Hui Liu, Peng Cai, Kevin J. McHugh, Collin F. Perkinson, Laishuo Li, Shuna Wang, Wei Wang, Mingxia Jiao, Xiliang Luo, Lihong Jing
Summary: Aqueous synthesis is developed to prepare Zn-Cu-In-Se quantum dots with tunable emission through a simple approach, and the effects of composition on the optical properties are decoupled from the impact of particle size. The absolute photoluminescence quantum yield is enhanced by overcoating a ZnS shell. Based on these bright and biocompatible quantum dots, nanoprobes with targeting capability are constructed for simultaneous detection of multiple tumor markers in the cytoplasm and cell membrane.
Article
Chemistry, Multidisciplinary
Alexander M. Saeboe, Alexey Y. Nikiforov, Reyhaneh Toufanian, Joshua C. Kays, Margaret Chern, J. Paolo Casas, Keyi Han, Andrei Piryatinski, Dennis Jones, Allison M. Dennis
Summary: This report showcases the reddest emitting indium phosphide quantum dots to date, demonstrating tunable near-infrared photoluminescence and PL multiplexing in the first optical tissue window while avoiding toxic constituents. By utilizing an inverted QD heterostructure, the synthesis overcomes the growth bottleneck and extends the emission peak of the nanoparticles into the deeper optical tissue window.
Article
Materials Science, Multidisciplinary
Wenxu Yin, Xiaoyu Zhang, Xuyong Yang, Andrey L. Rogach, Weitao Zheng
Summary: This article summarizes the recent progress in the development of near-infrared quantum dot LEDs, focusing on how their device structure and emitter properties facilitate improvement of device performance. The challenges and opportunities associated with these LEDs are also discussed.
Article
Chemistry, Multidisciplinary
Xiaofei Zhao, Li Jun Lim, Shun Sheng Ang, Zhi-Kuang Tan
Summary: Short-wave infrared (SWIR) light emission is important for various modern applications. However, there are limited semiconductors that can efficiently emit SWIR light. This study presents a highly efficient SWIR LED based on heavy-metal-free indium arsenide (InAs) core-shell colloidal quantum dots (CQDs), achieving high external quantum efficiencies through the implementation of a poly(vinylcarbazole) layer.
ADVANCED MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Zong-Liang Tseng, Lung-Chien Chen, Li-Wei Chao, Meng-Ju Tsai, Dian Luo, Nurul Ridho Al Amin, Shun-Wei Liu, Ken-Tsung Wong
Summary: In recent years, the performance and efficiency of perovskite quantum dots and QD-based light-emitting diodes have greatly improved, but the development of near-infrared QLEDs lags behind. In this study, new near-infrared-emissive perovskite quantum dots were developed through post-treatment, achieving high photoluminescence quantum yield and preparing high-quality films suitable for highly efficient near-infrared QLED applications.
ADVANCED MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Ting Meng, Zifei Wang, Ting Yuan, Xiaohong Li, Yunchao Li, Yang Zhang, Louzhen Fan
Summary: This study presents a gram-scale synthesis of red/green/blue solid-state fluorescent carbon quantum rings with high quantum yields, offering a potential alternative to REE-free phosphor-converted white LEDs. These R/G/B-SBF-CQRs-based LEDs emit warm white light with low CCT, high CRI, and high luminous efficiency, comparable to REE-phosphor-based LEDs.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2021)
Article
Chemistry, Multidisciplinary
Yuan Jiang, Haibao Shao, Hangning Xu, Jiahao Yang, Yi Wang, Haonan Xiong, Pengyao Wang, Xilin Wang
Summary: An ultrafast and facile aqueous synthetic approach for CdTe/CdS core/shell quantum dots with emission from the green to near-infrared window has been reported. The CdTe/CdS QDs with emission wavelengths at 700 and 800 nm can be obtained within 20-45 minutes under optimized conditions, and the resulting QDs are highly luminescent without postsynthesis treatment. The influences of various experimental factors on the synthesis rate and luminescent properties of the CdTe/CdS QDs have been considered.
MATERIALS TODAY CHEMISTRY
(2021)
Article
Optics
Bingbing Guo, Runchen Lai, Sijie Jiang, Linming Zhou, Zhixiang Ren, Yaxiao Lian, Puyang Li, Xuhui Cao, Shiyu Xing, Yaxin Wang, Weiwei Li, Chen Zou, Mengyu Chen, Zijian Hong, Cheng Li, Baodan Zhao, Dawei Di
Summary: This study demonstrates ultrastable and efficient perovskite light-emitting diodes for near-infrared light source. The introduction of a dipolar molecular stabilizer enhances the stability by preventing phase transformation and decomposition of the perovskite.
Article
Chemistry, Multidisciplinary
Bin Xu, Jie Li, Jing Zhang, Huiying Ning, Xiaoqi Fang, Jian Shen, Heng Zhou, Tianlong Jiang, Zhenhua Gao, Xiangeng Meng, Zifei Wang
Summary: A novel structure engineering strategy is developed to achieve solid-state fluorescence-emitted carbon dots with extended wavelength emissions. The quantum yields of these carbon dots are significantly improved up to 67.7%, which is the highest value for solid-state carbon dots. This work provides high-quality solid-state carbon dot-based phosphors for LED lighting sources required for diverse optoelectronic applications.
Article
Chemistry, Analytical
Yong Cui, Liangliang Zhang, Bingfang Shi, Shengyu Chen, Shulin Zhao
Summary: A high-sensitivity fluorescent sensor based on the inner filter effect was developed to monitor levels of gamma-glutamyl transpeptidase (GGT). Biomass quantum dots (BQDs) prepared from cauliflower were used as a raw material and exhibited strong near-infrared emissions for sensitive detection of GGT abundance. The sensor showed success in monitoring GGT levels in serum samples, imaging GGT in live cells, and evaluating GGT inhibitors.
SENSORS AND ACTUATORS B-CHEMICAL
(2021)
Article
Nanoscience & Nanotechnology
Nagarjuna Naik Mude, Yeasin Khan, Truong Thi Thuy, Bright Walker, Jang Hyuk Kwon
Summary: This study reports the development of high-efficiency and long-lifetime inverted green cadmium-free quantum dot light-emitting diodes (QLEDs) using a stable ZnO/ZnS cascaded electron transport layer (ETL). The use of ZnO/ZnS cascaded ETL allows for reduced electron injection, improving charge balance and suppressing exciton quenching in the QD layer. The optimized devices achieved significantly improved efficiency and long lifetime compared to reference devices.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Article
Chemistry, Analytical
Bo Zhang, Wan-Sheng Tang, Shou-Nian Ding
Summary: In this study, a simple simulation strategy based on a multicolor fluorescence model was used to predict the influence of microbead size distribution on barcode signals, simplifying the experimental iteration process and achieving good agreement between experimental clusters of fluorescent microbeads and simulated barcodes. When applied for high-throughput ultrasensitive detection of tumor markers, these barcodes exhibit superior detection performance, meeting the sensitivity criteria of tumor marker analysis.
Article
Nanoscience & Nanotechnology
Hai Huang, Renfu Li, Shilin Jin, Zhifang Li, Ping Huang, Jinquan Hong, Shaowu Du, Wei Zheng, Xueyuan Chen, Daqin Chen
Summary: The study introduces a new hot-injection route to fabricate Yb3+-doped CsPbCl3 perovskite nanocrystals with high photoluminescence quantum yields. In the CsPbCl3 host, intrinsic shallow trap states play a key role in facilitating picosecond nonradiative energy transfer from nanocrystals to Yb3+ dopants. The optimized quantum cutters exhibit high NIR output irradiance and stable performance, showing great potential as invisible night-vision light sources.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Article
Multidisciplinary Sciences
Yuqi Sun, Lishuang Ge, Linjie Dai, Changsoon Cho, Jordi Ferrer Orri, Kangyu Ji, Szymon J. Zelewski, Yun Liu, Alessandro J. Mirabelli, Youcheng Zhang, Jun-Yu Huang, Yusong Wang, Ke Gong, May Ching Lai, Lu Zhang, Dan Yang, Jiudong Lin, Elizabeth M. Tennyson, Caterina Ducati, Samuel D. Stranks, Lin-Song Cui, Neil C. Greenham
Summary: Perovskite LEDs with exceptional performance at high brightness have been achieved by introducing a multifunctional molecule that removes non-radiative regions and suppresses luminescence quenching at the interface. These LEDs show a peak EQE of 23.8% at 33 mA cm(-2) and retain EQEs more than 10% at high current densities of up to 1,000 mA cm(-2). An operational half-lifetime of 32 h at high brightness has been achieved, representing the best stability for perovskite LEDs.
Article
Chemistry, Applied
Nini Liang, Xuetao Hu, Wenting Li, Yueying Wang, Ziang Guo, Xiaowei Huang, Zhihua Li, Xinai Zhang, Jiukai Zhang, Jianbo Xiao, Xiaobo Zou, Jiyong Shi
Summary: A dual-signal fluorescent sensor was developed for the detection of tetracycline in milk, showing excellent reproducibility and stability. The sensor utilized two types of quantum dots, MoS2 QDs and CdTe QDs, to achieve two fluorescence emission peaks at 433 nm and 573 nm. The sensor demonstrated strong application potential with accurate detection of TET concentration in milk samples.