4.7 Article

Microstructure control, competitive growth and precipitation rule in faceted Al2O3/Er3Al5O12 eutectic in situ composite ceramics prepared by laser floating zone melting

期刊

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
卷 39, 期 5, 页码 1900-1908

出版社

ELSEVIER SCI LTD
DOI: 10.1016/j.jeurceramsoc.2019.01.015

关键词

Directional solidification; Oxide ceramic; Microstructure control; Competitive growth; Precipitation rule

资金

  1. National Natural Science Foundation of China [51822405, 51472200, 51272211, 51690163]
  2. National Key R&D Program of China [2018YFB1106600, 2017YFB1103500]
  3. Research Fund of Equipment Development Department [6140759040116HK03001, 61409230402]
  4. Key R&D Program of ShaanXi Province [2018ZDCXL-GY-09-04]
  5. Program of Xi'an Science and Technology [2017-1-14-D1]
  6. Shenzhen Science and Technology Innovation Committee Fund [201803063000257]

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Microstructure control and competitive growth of Al2O3/Er3Al5O12 eutectic/off-eutectics are explored over wide ranges of solidification rates and compositions. Gradual transformation phenomenon of microstructure morphology from complete eutectic to eutectic + coarse Er3Al5O12 phase and to eutectic + Er3Al5O12 dendrite is observed and the corresponding influence factors are evaluated. Competitive growth between single-phase A1203 (or Er3Al5O12) dendrite and eutectic is analyzed and coupled growth zone is mapped through comparing interface temperatures of different patterns of microstructures. The complete eutectic microstructure could be obtained at Al2O3/Er3Al5O12 hypoeutectic (Al2O3-17.5 mol% Er2O3) under fast solidification rate and the onset growth rate 00.94 x 104 m/s) estimated from the measured eutectic spacing [150 nm) fits well with the result calculated on the basis of competitive growth [1.27 x 104 pm/s). Transformation of microstructure from irregular eutectic to regular eutectic and probable adjustment mechanism of eutectic spacings are discussed when the eutectic spacings refined from micron-scale ( < 10 pm) to nano-scale [20 nm).

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