4.7 Article

Preparation of large-size Al2O3/GdAlO3/ZrO2 ternary eutectic ceramic rod by laser directed energy deposition and its microstructure homogenization mechanism

期刊

JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
卷 85, 期 -, 页码 218-223

出版社

JOURNAL MATER SCI TECHNOL
DOI: 10.1016/j.jmst.2021.01.025

关键词

Oxide eutectic ceramic; Laser 3D printing; Melt growth; Heat treatment; Microstructure homogenization

资金

  1. National Key R&D Program of China [2018YFB1106600, 2017YFB1103500]
  2. Science, Technology and Innovation Commission of Shenzhen Municipality [JCYJ20180306171121424]
  3. National Natural Science Foundation of China [51822405, 51472200]
  4. Aeronautics Power Foundation [6141B09050337]
  5. Key R&D Program of Shaan Xi Province [2018ZDCXL-GY-09-04]
  6. Joint Research Funds of the Department of Science &Technology of Shaanxi Province and NPU [2020GXLH-Z-024]
  7. Research Fund of the State Key Laboratory of Solidification Processing (NPU) [2019QZ-02]

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This study successfully fabricated large-scale Al2O3/GdAlO3/ZrO2 ternary eutectic ceramic materials using laser 3D printing technology, with heat treatment applied to eliminate microstructure heterogeneity and reveal the microstructure homogenization mechanism. The results showed that the eutectic spacing linearly increased with heat treatment time, following the Graham-Kraft model.
Laser 3D printing based on melt growth has great potential in rapid preparation of Al2O3-based eutectic ceramics. In this work, large-scale Al2O3/GdAlO3/ZrO2 ternary eutectic ceramic rod with diameter of 4-5 mm and height higher than 250 mm was additively manufactured by laser directed energy deposition. Especially, heat treatment was applied to eliminate the microstructure heterogeneity in the as-deposited eutectic ceramic, and the microstructure homogenization mechanism was studied in depth. The results indicate that colonies and banded structures completely disappear after the heat treatment, producing a homogeneous network eutectic structure. The microstructure homogenization is revealed to experience three stages of discontinuous coarsening, continuous coarsening and microstructure coalescence. Additionally, it is found that the eutectic spacing linearly increases with the heat treatment time, meaning that the coarsening behavior of the laser 3D-printed Al2O3/GdAlO3/ZrO2 eutectic ceramic satisfies well with the Graham-Kraft model. (C) 2021 Published by Elsevier Ltd on behalf of The editorial office of Journal of Materials Science & Technology.

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