期刊
CHEMISTRY-AN ASIAN JOURNAL
卷 13, 期 21, 页码 3169-3172出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/asia.201801235
关键词
click chemistry; metal-ligand interactions; orthogonality; self-assembly; supramolecular polymers
资金
- National Natural Science Foundation of China [21704075, 21522405, 51503142]
- Thousand Youth Talents Plan
- Natural Science Foundation of Tianjin [15JCYBJC52900, 17JCJQJC44200]
Supramolecular polymers with multiple functionalities and hierarchical structures have received considerable attention and become a hot research topic over the past years. Herein, a main-chain supramolecular polymer has been successfully fabricated by using metal-ligand interactions and a thiol-ene click reaction. H-1 NMR, UV/Vis, DOSY, and viscosity measurements were carried out to investigate the molecular recognition and the process of supramolecular polymerization. From the study, the orthogonality between thiol-ene click reactions and the terpyridine-metal ions complexation behavior was testified, and supramolecular polymeric assemblies could be constructed by a one pot method. In the meantime, due to the incorporation of metal-ligand interactions, the supramolecular polymer shows stimuli-responsive properties toward chemical stimuli. Hence, this work could provide a methodology for developing supramolecular polymers as smart materials.
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