Enantioselective Aluminum-Free Alkene Hydroarylations through C−H Activation by a Chiral Nickel/JoSPOphos Manifold

Inert C–H Bond Transformations Enabled by Organometallic Manganese Catalysis

(2018) Yuanyuan Hu et al.   ACCOUNTS OF CHEMICAL RESEARCH

Late-Stage Peptide Diversification by Position-Selective C-H Activation

(2018) Wei Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Ni–Al Bimetallic Catalyzed exo-Selective C–H Cyclization of Imidazoles with Alkenes

(2018) Yin-Xia Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Enantioselective Pyridone C–H Functionalizations Enabled by a Bulky N-Heterocyclic Carbene Ligand

(2018) Johannes Diesel et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chemo-, Regio-, and Enantioselective Rhodium-Catalyzed Allylation of Triazoles with Internal Alkynes and Terminal Allenes

(2018) Dino Berthold et al.   ORGANIC LETTERS

sp3 C–H activation via exo-type directing groups

(2018) Yan Xu et al.   Chemical Science

Transient Directing Groups for Transformative C–H Activation by Synergistic Metal Catalysis

(2018) Parthasarathy Gandeepan et al.   Chem

Enantioselective Cobalt(III)-Catalyzed C−H Activation Enabled by Chiral Carboxylic Acid Cooperation

(2018) Fabio Pesciaioli et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The mechanism and regioselectivities of (NHC)nickel(ii)hydride-catalyzed cycloisomerization of dienes: a computational study

(2017) Yuan Gao et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Aromatic C–H σ-Bond Activation by Ni0, Pd0, and Pt0 Alkene Complexes: Concerted Oxidative Addition to Metal vs Ligand-to-Ligand H Transfer Mechanism

(2017) Shuwei Tang et al.   ORGANOMETALLICS

Entrances, Traps, and Rate-Controlling Factors for Nickel-Catalyzed C–H Functionalization

(2017) Alex J. Nett et al.   ACS Catalysis

A General Strategy for the Nickel-Catalyzed C−H Alkylation of Anilines

(2016) Zhixiong Ruan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Transformations of Alkyl C–H Bonds

(2016) Jian He et al.   CHEMICAL REVIEWS

Regioconvergent and Enantioselective Rhodium-Catalyzed Hydroamination of Internal and Terminal Alkynes: A Highly Flexible Access to Chiral Pyrazoles

(2016) Alexander M. Haydl et al.   CHEMISTRY-A EUROPEAN JOURNAL

Recent Development of Benzimidazole-Containing Antibacterial Agents

(2016) Di Song et al.   ChemMedChem

Rhodium-Catalysed Enantioselective C-H Functionalization in Asymmetric Synthesis

(2016) Somayeh Motevalli et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Theoretical Study of Nickel-Catalyzed Selective Alkenylation of Pyridine: Reaction Mechanism and Crucial Roles of Lewis Acid and Ligands in Determining the Selectivity

(2016) Vijay Singh et al.   JOURNAL OF ORGANIC CHEMISTRY

Diastereodivergent Construction of Bicyclic γ-Lactones via Enantioselective Ketone Hydroacylation

(2016) Xuesong Wu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Hydroacylation of Styrenes with Simple Aldehydes: Reaction Development and Mechanistic Insights

(2016) Li-Jun Xiao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed C–H Alkynylation of Anilines: Expedient Access to Functionalized Indoles and Purine Nucleobases

(2016) Zhixiong Ruan et al.   ACS Catalysis

Manganese-Catalyzed C–H Activation

(2016) Weiping Liu et al.   ACS Catalysis

Chiral Cyclopentadienyls: Enabling Ligands for Asymmetric Rh(III)-Catalyzed C–H Functionalizations

(2015) Baihua Ye et al.   ACCOUNTS OF CHEMICAL RESEARCH

Regio- and Enantioselective Synthesis of N-Substituted Pyrazoles by Rhodium-Catalyzed Asymmetric Addition to Allenes

(2015) Alexander M. Haydl et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickel-catalysed para-CH activation of pyridine with switchable regioselective hydroheteroarylation of allylarenes

(2015) Wei-Chih Lee et al.   CHEMICAL COMMUNICATIONS

Recent Advances in Copper-mediated Direct Biaryl Coupling

(2015) Koji Hirano et al.   CHEMISTRY LETTERS

Single-Component Phosphinous Acid Ruthenium(II) Catalysts for Versatile C−H Activation by Metal-Ligand Cooperation

(2015) Daniel Zell et al.   CHEMISTRY-A EUROPEAN JOURNAL

Highly Active Nickel Catalysts for C–H Functionalization Identified through Analysis of Off-Cycle Intermediates

(2015) Alex J. Nett et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Anti-Markovnikov Hydroheteroarylation of Unactivated Alkenes with Indoles, Pyrroles, Benzofurans, and Furans Catalyzed by a Nickel–N-Heterocyclic Carbene System

(2015) York Schramm et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Computational Exploration of Mechanism and Selectivities of (NHC)Nickel(II)hydride-Catalyzed Hydroalkenylations of Styrene with α-Olefins

(2015) Xin Hong et al.   ACS Catalysis

Low-Valent Cobalt Catalysis: New Opportunities for C–H Functionalization

(2014) Ke Gao et al.   ACCOUNTS OF CHEMICAL RESEARCH

Unlocking theN2 Selectivity of Benzotriazoles: Regiodivergent and Highly Selective Coupling of Benzotriazoles with Allenes

(2014) Kun Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickel-Catalyzed CH Alkylations: Direct Secondary Alkylations and Trifluoroethylations of Arenes

(2014) Weifeng Song et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Linear-Selective Hydroarylation of Unactivated Terminal and Internal Olefins with Trifluoromethyl-Substituted Arenes

(2014) Joseph S. Bair et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cobalt-Catalyzed Enantioselective Intramolecular Hydroacylation of Ketones and Olefins

(2014) Junfeng Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cobalt-Catalyzed Enantioselective Directed C–H Alkylation of Indole with Styrenes

(2014) Pin-Sheng Lee et al.   ORGANIC LETTERS

Catalytic Functionalization of C(sp2)H and C(sp3)H Bonds by Using Bidentate Directing Groups

(2013) Guy Rouquet et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Diaminophosphine Oxide Ligand Enabled Asymmetric Nickel-Catalyzed Hydrocarbamoylations of Alkenes

(2013) Pavel A. Donets et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent development of direct asymmetric functionalization of inert C–H bonds

(2013) Chao Zheng et al.   RSC Advances

Alkylation of Pyridone Derivatives By Nickel/Lewis Acid Catalysis

(2012) Ryuichi Tamura et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mechanistic Origin of Regioselectivity in Nickel-Catalyzed Olefin Hydroheteroarylation through C–H Activation

(2012) Yuan-Ye Jiang et al.   ORGANOMETALLICS

Rhodium Catalyzed Chelation-Assisted C–H Bond Functionalization Reactions

(2011) Denise A. Colby et al.   ACCOUNTS OF CHEMICAL RESEARCH

Hydroarylation of alkynes catalyzed by nickel

(2011) Yoshiaki Nakao   CHEMICAL RECORD

Carboxylate-Assisted Transition-Metal-Catalyzed C−H Bond Functionalizations: Mechanism and Scope

(2011) Lutz Ackermann   CHEMICAL REVIEWS

Hydrofluoroarylation of Alkynes with Ni Catalysts. C–H Activation via Ligand-to-Ligand Hydrogen Transfer, an Alternative to Oxidative Addition

(2011) Julie Guihaumé et al.   ORGANOMETALLICS

Nickel-Catalyzed Hydroheteroarylation of Vinylarenes

(2010) Yoshiaki Nakao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chiral Mixed Secondary Phosphine-Oxide-Phosphines: High-Performing and Easily Accessible Ligands for Asymmetric Hydrogenation

(2010) Heidi Landert et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Oxidative Coupling of Aromatic Substrates with Alkynes and Alkenes under Rhodium Catalysis

(2010) Tetsuya Satoh et al.   CHEMISTRY-A EUROPEAN JOURNAL

Bimetallic Nickel Aluminun MediatedPara-Selective Alkenylation of Pyridine: Direct Observation of η2,η1-Pyridine Ni(0)−Al(III) Intermediates Prior to C−H Bond Activation

(2010) Chung-Chih Tsai et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Transition-Metal-Catalyzed Direct Arylation of (Hetero)Arenes by CH Bond Cleavage

(2009) Lutz Ackermann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nonlinear Effects in Asymmetric Catalysis

(2009) Tummanapalli Satyanarayana et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium catalyzed enantioselective cyclization of substituted imidazoles via C–H bond activation

(2009) Andy S. Tsai et al.   CHEMICAL COMMUNICATIONS

Rhodium-Catalyzed C−C Bond Formation via Heteroatom-Directed C−H Bond Activation

(2009) Denise A. Colby et al.   CHEMICAL REVIEWS

Direct Alkenylation and Alkylation of Pyridone Derivatives by Ni/AlMe3Catalysis

(2009) Yoshiaki Nakao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct Functionalization of Nitrogen Heterocycles via Rh-Catalyzed C−H Bond Activation

(2008) Jared C. Lewis et al.   ACCOUNTS OF CHEMICAL RESEARCH

Catalytic C–H functionalization by metal carbenoid and nitrenoid insertion

(2008) Huw M. L. Davies et al.   NATURE

Catalytic Annulation of Heterocycles via a Novel Redox Process Involving the Imidazolium Salt N-Heterocyclic Carbene Couple

(2008) Adrien T. Normand et al.   ORGANOMETALLICS